Hardness and Fracture Toughness of Solid Solutions of Mg2Si and Mg2Sn

Semiconductors - Thermoelectric material development typically aims at maximizing produced electrical power and efficiency of energy conversion, even though sometimes, this means adding expensive...     

Surfactant Sputtering: Theory of a new method of surface nanostructuring by ion beams

We present a new Monte Carlo model and a new continuum theory of surface pattern formation due to “surfactant sputtering”, i.e. erosion by ion beam sputtering including a submonolayer coverage of additional, co-sputtered surfactant atoms. This setup, which has been realized in recent experiments in a controlled way leads to a number of interesting possibilities to modify pattern forming processing conditions. We will present three simple scenarios, which illustrate some potential applications of the method. In all three cases, simple Bradley–Harper type ripples appear in the absence of surfactant, whereas new, interesting structures emerge during surfactant sputtering.     

The influence of beam divergence on ion-beam induced surface patterns

We present a continuum theory and a Monte Carlo model of self-organized surface pattern formation by ion-beam sputtering including effects of beam profiles. Recently, it has turned out that such secondary ion-beam parameters may have a strong influence on the types of emerging patterns. We first discuss several cases, for which beam profiles lead to random parameters in the theory of pattern formation. Subsequently we study the evolution of the averaged height profile in continuum theory and find that the typical Bradley–Harper scenario of dependence of ripple patterns on the angle of incidence can be changed qualitatively. Beam profiles are implemented in Monte Carlo simulations, where we find generic effects on pattern formation. Finally, we demonstrate that realistic beam profiles, taken from experiments, may lead to qualitative changes of surface patterns.     

Effect of nanoimprinted surface relief on Si and Ge nucleation and ordering

Surface relief formed by nanoimprinting and etching into a thermally grown SiO₂ layer on Si was used to position the initial nuclei formed by chemically vapor deposited Si and Ge. By controlling the deposition conditions, the surface diffusion length was adjusted to be comparable to or larger than the spacing between features, thus favoring nucleation adjacent to steps, rather than random nucleation. Random nucleation was further suppressed by a two-stage deposition process. Ge nucleation on oxide by chemical vapor deposition was enhanced by coating the oxide surface with an organic self-assembled monolayer (SAM) and by the nanoimprinted surface relief. The nanoimprinted surface relief also provides long-range order in the SAM.     

Lake responses following lanthanum-modified bentonite clay (Phoslock) application: An analysis of water column lanthanum data from 16 case study lakes

Phoslock^® is a lanthanum (La) modified bentonite clay that is being increasingly used as a geo-engineering tool for the control of legacy phosphorus (P) release from lake bed sediments to overlying waters. This study investigates the potential for negative ecological impacts from elevated La concentrations associated with the use of Phoslock^® across 16 case study lakes. Impact-recovery trajectories associated with total lanthanum (TLa) and filterable La (FLa) concentrations in surface and bottom waters were quantified over a period of up to 60 months following Phoslock^® application. Both surface and bottom water TLa and FLa concentrations were <0.001 mg L⁻¹ in all lakes prior to the application of Phoslock^®. The effects of Phoslock^® application were evident in the post-application maximum TLa and FLa concentrations reported for surface waters between 0.026 mg L⁻¹–2.30 mg L⁻¹ and 0.002 mg L⁻¹ to 0.14 mg L⁻¹, respectively. Results of generalised additive modelling indicated that recovery trajectories for TLa and FLa in surface and bottom waters in lakes were represented by 2nd order decay relationships, with time, and that recovery reached an end-point between 3 and 12 months post-application. Recovery in bottom water was slower (11–12 months) than surface waters (3–8 months), most probably as a result of variation in physicochemical conditions of the receiving waters and associated effects on product settling rates and processes relating to the disturbance of bed sediments. CHEAQS PRO modelling was also undertaken on 11 of the treated lakes in order to predict concentrations of La³⁺ ions and the potential for negative ecological impacts. This modelling indicated that the concentrations of La³⁺ ions will be very low (<0.0004 mg L⁻¹) in lakes of moderately low to high alkalinity (>0.8 mEq L⁻¹), but higher (up to 0.12 mg L⁻¹) in lakes characterised by very low alkalinity. The effects of elevated La³⁺ concentrations following Phoslock^® applications in lakes of very low alkalinity requires further evaluation. The implications for the use of Phoslock^® in eutrophication management are discussed.     

Silver nanocrystal-modified silicon nanowires as substrates for surface-enhanced Raman and hyper-Raman scattering

Metal catalyzed, CVD-grown silicon nanowires decorated by chemical assembly of closely spaced Ag nanocrystals were modified with the well-known "silver mirror" reaction and investigated as substrates for surface-enhanced Raman (SERS) and hyper-Raman (SEHRS) spectroscopy. Four chromophores were examined: Rhodamine 6G, crystal violet, a cyanine dye, and a cationic donor-acceptor substituted stilbene. After soaking the substrates overnight in 10(-4) M aqueous chromophore solutions, all four chromophores gave good-quality SERS spectra in < or =60 s using <1 microW of 458-nm cw laser power, and SEHRS spectra are obtained in < or =120 s using <1 mW of mode-locked 916-nm laser power. Results from this substrate are compared with those on colloidal silver nanoparticles deposited as a film, as well as surfaces grown by the silver mirror reaction.     

Optimal design of slabs on a plastic foundation

This paper discusses the absolute minimum reinforcement design of a transversely loaded, rigid-plastic fibre-reinforced slab resting on a perfectly plastic foundation. The condition of minimum reinforcement and a model of a perfectly plastic supporting medium are reviewed. With the use of these results, solutions are found for minimum reinforcement of circular slabs under a point load at the centre.     

A Monte Carlo study of surface sputtering by dual and rotated ion beams

Several, recently proposed methods of surface manufacturing based on ion beam sputtering, which involve dual beam setups, sequential application of ion beams from different directions, or sample rotation, are studied with the method of kinetic Monte Carlo simulation of ion-beam erosion and surface diffusion. In this work, we only consider erosion dominated situations. The results are discussed by comparing them to a number of theoretical propositions and to experimental findings. Two ion-beams aligned opposite to each other produce stationary, symmetric ripples. Two ion beams crossing at right angle will produce square patterns only, if they are exactly balanced. In all other cases of crossed beams, ripple patterns are created, and their orientations are shown to be predictable from linear continuum theory. In sequential ion-beam sputtering we find a very rapid destruction of structures created from the previous beam direction after a rotation step, which leads to a transient decrease of overall roughness. Superpositions of patterns from several rotation steps are difficult to obtain, as they exist only in very short time windows. In setups with a single beam directed towards a rotating sample, we find a non-monotonic dependence of roughness on rotation frequency, with a very pronounced minimum appearing at the frequency scale set by the relaxation of prestructures observed in sequential ion-beam setups. Furthermore we find that the logarithm of the height of structures decreases proportional to the inverse frequency.