Performance Analysis of Linear and Hybrid Precoding on Massive MIMO System Using Truncated Polynomial Expansion

Wireless Personal Communications - In a communication system, ultra-wideband (UWB) is the most promising solution because of its high speed, high data rate, and short-range communication. However,...     

Layer‐by‐layer assembly of halogen‐free polymeric materials on nylon/cotton blend for flame retardant applications

Thin films of environmentally safe, halogen free, anionic sodium phosphate and cationic polysiloxanes were deposited on a Nyco (1:1 nylon/cotton blend) fabric via layer‐by‐layer (LbL) assembly to reduce the inherent flammability of Nyco fabric. In the coating process, we used three different polysiloxane materials containing different amine groups including, 35–45% (trimethylammoniummethylphenythyl)‐methyl siloxane‐55‐65% dimethyl siloxane copolymer chloride salt (QMS‐435), aminoethylaminopropyl silsesquioxane‐methylsilsesquioxane copolymer oligomer (WSA‐7021) and aminopropyl silesquioxane oligomers (WSA‐991), as a positive polyelectrolyte. Thermo‐gravimetric analysis showed that coated fabric has char yield around 40% at 600 °C whereas control fabric was completely consumed. The vertical flame test (VFT) on the LbL‐coated Nyco fabric was passed with after flame time, 2 s, and the char length of 3.81 cm. Volatile and nontoxic degradation products of flame retardant‐coated fabric were analyzed by pyrolysis gas chromatography mass spectroscopy (Py‐GCMS). Surface morphology of coated fabrics and burned fabric residues were studied by scanning electron microscopy. Copyright © 2014 John Wiley & Sons, Ltd.     

Synthesis and characterization of highly photoresponsive fullerenyl dyads with a close chromophore antenna-C(60) contact and effective photodynamic potential

We report the synthesis of a new class of photoresponsive C(60)-DCE-diphenylaminofluorene nanostructures and their intramolecular photoinduced energy and electron transfer phenomena. Structural modification was made by chemical conversion of the keto group in C(60)(>DPAF-C(n)) to a stronger electron-withdrawing 1,1-dicyanoethylenyl (DCE) unit leading to C(60)(>CPAF-C(n)) with an increased electronic polarization of the molecule. The modification also led to a large bathochromic shift of the major band in visible spectrum giving measureable absorption up to 600 nm and extended the photoresponsive capability of C(60)-DCE-DPAF nanostructures to longer red wavelengths than C(60)(>DPAF-C(n)). Accordingly, C(60)(>CPAF-C(n)) may allow 2γ-PDT using a light wavelength of 1000-1200 nm for enhanced tissue penetration depth. Production efficiency of singlet oxygen by closely related C(60)(>DPAF-C(2) (M)) was found to be comparable with that of tetraphenylporphyrin photosensitizer. Remarkably, the (1)O(2) quantum yield of C(60)(>CPAF-C(2) (M)) was found to be nearly 6-fold higher than that of C(60)(>DPAF-C(2) (M)), demonstrating the large light-harvesting enhancement of the CPAF-C(2) (M) moiety and leading to more efficient triplet state generation of the C(60)> cage moiety. This led to highly effective killing of HeLa cells by C(60)(>CPAF-C(2) (M)) via photodynamic therapy (200 J cm(-2) white light). We interpret the phenomena in terms of the contributions by the extended π-conjugation and stronger electron-withdrawing capability associated with the 1,1-dicyanoethylenyl group compared to that of the keto group.     

Mechanical properties of friction welded 6063 aluminum alloy and austenitic stainless steel

Friction welding of dissimilar metal combination of aluminum alloy and austenitic stainless steel was examined to investigate the effect of welding conditions on mechanical properties of the dissimilar metal combination. The welded joints were produced by varying forge pressure (F _g), friction pressure (F _r), and burn-off length (B). The joints were subjected to mechanical testing methods such as the tension, notch Charpy impact tests. The tensile strength and toughness decrease with an increase in friction pressure. The tensile strength decreases with an increase in burn-off length at a low forge pressure while tensile strength increases with an increase in burn-off length at a high forge pressure. The tensile failure of the welded joint occurred in aluminum alloy just away from interface in the thermo-mechanically affected zone indicates good joint strength at the condition of low friction pressure, high forge pressure, and high burn-off length. The maximum tensile strength was observed with low friction pressure and high forge pressure. The tensile strength of dissimilar joint is approximately equal to tensile strength of 6063 aluminum alloys at the condition of low friction pressure, high forge pressure, and high burn-off length. The tensile and impact failure of joints was examined under scanning electron microscope and failure modes were discussed.