Dry Fractionation Approach in Concentrating Tocopherols and Tocotrienols from Palm Fatty Acid Distillate: A Green Pretreatment Process for Vitamin E Extraction

Palm fatty acid distillate (PFAD) is a rich source of vitamin E. As compared to other vegetable oil, PFAD has higher tocotrienol (70–80%) over tocopherol content, which makes it a valuable source for vitamin E extraction. Current vitamin E extraction methods are not sustainable due to the intensive usage of chemical and high operational cost. Hence, the present study investigated for the first time using dry fractionation process as a green and economical pretreatment method for separating solid fraction (stearin) and liquid fraction (olein) in order to concentrate vitamin E from PFAD in olein fraction. We examined the dry fractionation conditions: crystallization ending temperature (36–44 °C), cooling rate (0.3 and 1.5°C min⁻¹), stirring speed (20–125 rpm), and holding time (0–60 min) on the composition of unsaturated and saturated fatty acids as well as vitamin E content in liquid fraction (olein) and solid fraction (stearin) using gas chromatography and high performance liquid chromatography, respectively. In most of these conditions, vitamin E was ultimately higher in olein fraction as compared to stearin fraction, which is correlated with the high degree of unsaturation. Under a cooling rate of 0.3°C min⁻¹, 90 rpm stirring speed, and ending crystallization of 38 °C, the highest vitamin E rich olein fraction was attained with 1479 ± 10.51 ppm in 50 g olein fraction as compared to 1366 ± 7.94 ppm in 500 g of unfractionated PFAD.     

Grouting of large karstic caverns in dobrogea Coalfield,Bulgaria

The paper describes the results of an experimental grouting programme carried out by the Spetstamponazhgeologia association at the Dobrogea coalfield in Bulgaria. The anticipated water inflow into a shaft at this deposit totals 8 m³/s at a pressure of 12 MPa, from a cavity size equal or exceeding 3 metres. Grouting operations made it possible to cut down water inflow by a factor of more than one thousand. The success of this investigation has enabled the author to design an exprrimental shaft sinking project through the valange formation at Dobrogea mine.     

Biochemical effects of administering shock loads of sucrose to a laboratory-scale anaerobic (UASB) effluent treatment plant

An experimental study was undertaken to determine the effects of administering shock loads of sucrose to a laboratory-scale anaerobic effluent treatment plant (UASB reactor) treating diluted landfill leachate. Administration of shock loads of 10 g l⁻ sucrose caused accumulations of up to 7 g l⁻¹ of l-lactate and the resultant acidity caused the pH value of the reactor effluent to drop from 7.2 to 4.7 which inhibited methanogenesis.Major disturbances in the composition of the biogas also occurred and, under the severest conditions, the biogas contained up to 30% (v/v) hydrogen.     

Legislation and the motor car

Vehicle legislation for safety and emission control is led by the USA where half the world's cars and one‐third of the world's road deaths are found. The 1975/6 standards will cause confrontations between industry and government in the U.S.A. and have costly implications for the American people. The rest of the world is affected by what happens in the U.S.A. but for language and other reasons fragmented laws are normal with conflicting requirements for manufacturers who supply the many markets. The greatest force for harmonization of legislation may be the enlarged Common Market including, as it does, the four major European Car manufacturing countries. The Common Market Commission may displace WP 29 of the United Nations as the leading law‐making body. Type approval is the compliance system used in Europe, but the growth in scope of safety and other legislation is bringing into focus a weakness of the system which is reducing production efficiency to an alarming degree. American style self‐certification is not acceptable to European governments.     

Displacement bound of beam‐column with time‐dependent boundary constraints

Abstract

A simplified explicit formula for the displacement bounds of the beam‐column subjected to time‐dependent boundary constraints is proposed. The formula is derived by means of removing time dependence from the boundary conditions. The proposed bounds provide a quick estimation of the displacements for problems with complex loading conditions.     

Analytical performance of 3?m and 3?m +1 armchair graphene nanoribbons under uniaxial strain

The electronic band structure and carrier density of strained armchair graphene nanoribbons (AGNRs) with widths of n =3 m and n =3 m +1 were examined using tight-binding approximation. The current-voltage (I-V) model of uniaxial strained n =3 m AGNRs incorporating quantum confinement effects is also presented in this paper. The derivation originates from energy dispersion throughout the entire Brillouin zone of uniaxial strained AGNRs based on a tight-binding approximation. Our results reveal the modification of the energy bandgap, carrier density, and drain current upon strain. Unlike the two-dimensional graphene, whose bandgap remains near to zero even when a large strain is applied, the bandgap and carrier density of AGNRs are shown to be sensitive to the magnitude of uniaxial strain. Discrepancies between the classical calculation and quantum calculation were also measured. It has been found that as much as 19% of the drive current loss is due to the quantum confinement. These analytical models which agree well with the experimental and numerical results provide physical insights into the characterizations of uniaxial strained AGNRs.