Current trends in structural development and modification strategies for metal-organic frameworks (MOFs) towards photocatalytic H2 production: A review

Photocatalytic H₂ generation using semiconductor photocatalysts is considered as a cost-effective and eco-friendly technology for solar to energy conversion; however, the present photocatalysts have been recognized to depict low efficiency. Currently, porous coordination polymers known as metal-organic frameworks (MOFs) constituting flexible and modifiable porous structure and having excess active sites are considered to be appropriate for photocatalytic H₂ production. This review highlights current progress in structural development of MOF materials along with modification strategies for enhanced photoactivity. Initially, the review discusses the photocatalytic H₂ production mechanism with the concepts of thermodynamics and mass transfer with particular focus on MOFs. Elaboration of the structural categories of MOFs into Type I, Type II, Type III and classification of MOFs for H₂ generation into transition metal based, post-transition metal based, noble-metal based and hetero-metal based has been systematically discussed. The review also critically deliberate various modification approaches of band engineering, improvement of charge separation, efficient irradiation utilization and overall efficiency of MOFs including metal modification, heterojunction formation, Z-scheme formation, by introducing electron mediator, and dye based composites. Also, the MOF synthesized derivatives for photocatalytic H₂ generation are elaborated. Finally, future perspectives of MOFs for H₂ generation and approaches for efficiency improvement have been suggested.     

Iron pyrite films prepared by sulfur vapor transport

Iron films deposited via thermal evaporation, with a thickness between 100 and 250 nm, were converted into FeS₂ by open sulfur transport using nitrogen as a gas vector. The films thus obtained constituted a single pyrite phase and were optically highly absorbing. The sulfurization process was optimized. As a result, sample temperature and conversion time were found to be the major determining parameters. The films were characterized using several methods. The crystallinity and phase identification were determined by X-ray diffractometry. Scanning electron microscopy showed a homogeneous surface of both iron and pyrite layers. Optical transmission measurements confirmed the highly absorbing character of FeS₂ and allowed the determination of direct (1.35 eV) and indirect (0.82 eV) transitions.     

Solar cookers for outdoors and indoors

The solar cooking process has been investigated to develop safe, simple, portable, and reliable solar cookers. The concept of insulated and vapor-tight pots has been introduced and applied to oven, point-focus and heat-pipe cookers. A new, flat-plate cooker with heat pipes has been developed. It requires no tracking and allows cooking to be done in the shade or indoors. Also, a novel-portable cooker, the Mina Oven, featuring a vapor-tight pot and an integral collector with reflector flaps, has been constructed and tested. A second portable cooker that has been developed is the Arafa Cooker, which comprises a parabolic dish focused at a glazed and insulated receiver. Experiments indicated that all cookers yielded satisfactory performance, with cooking times of 25–45 min per kg of food per m² of solar collection area while operating from 10 a.m. to 4 p.m.     

Air impingement and intermittent drying: Application to apple and to mango

An original drying process combining air impingement and intermittent drying was studied on apple slices and mango cubes. The influence of four operating parameters (air velocity, drying/tempering periods, upper height, and air temperature) on the drying time and on the drying rate was evaluated. Continuous and intermittent drying were compared. The intermittency α = 1/7 (τ_on = 10 seconds and τ_off = 60 seconds) gave the best results. A time savings of 54% for apple and 67% for mango was reached. In continuous drying, a time savings of 4620 seconds was observed by increasing the air velocity from 6 to 40 m s^?1 for apple. Air temperatures of 328 K for apple and of 328 K or 338 K for mango were determined as optimum to prevent case‐hardening. Experimental results were fitted with the analytical solution of Fick's second law and the modified Page equation (average values R² = 0.985 and 0.961, for apple and mango, respectively). For both products, the apparent moisture diffusivity D_app, the drying constant k, the drying coefficient n, and the activation energy E_a, were identified. Activation energies calculated from the analytical solution were 30.3 and 36.8 kJ mol^?1 and were 25.4 and 30.0 kJ mol^?1 using the modified Page equation for apple and mango, respectively. Mango has an increased temperature sensitivity and thus will need less energy for drying than apple.     

Investigations on mode-division multiplexed free-space optical transmission for inter-satellite communication link

Wireless Networks - Inter-satellite data transmission links are very crucial for providing global inter-connectivity. We report designing and investigations on high date rate inter-satellite...     

Evaluation of rutting potential for asphalt concrete mixes containing copper slag

Copper slag (CS) is a by-product of the copper extraction process, which can be used as coarse and/or fine aggregate in hot mix asphalt (HMA) pavements. This study used CS as a replacement of the fine aggregate with a percentage of up to 40% by total aggregate weight. The objective of this study was to evaluate the effect of CS on the rutting potential of the asphalt concrete mix using two methods. One method is based on the Dynamic modulus |E*| testing result. Actual pavement temperature data from a test section were used with the developed |E*| master curves. EverStressFE finite element program was used to perform a linear elastic load-deformation analysis for a pavement section and to determine the vertical resilient strain in a 40-mm HMA surface layer. The M-E PDG permanent deformation model was used with and Excel Visual Basic for Applications code to predict the accumulated rutting for different CS mixes for 10 million ESALs. The other method used the data from the flow number (FN) test. Based on the |E*| approach, the results indicated that adding 5% CS in the mix increased the predicted rutting from 0.59 to 0.98 mm at 10 million ESALs (increase by 68%). When 40% CS was used, rutting increased by more than 700% compared with the control mix. After analysing the FN results with the Francken model, the results indicated a decrease in FN as CS content is increased, indicating higher rutting potential. The decrease in FN ranged from 9% for 5% CS to 95% for 40% CS. The mixes containing up to 10% CS satisfied the minimum FN criteria for rutting. A calibration process for the M-E PDG distress prediction models that allows the use of waste and by-product materials such as CS should be considered in the future.     

Flow and crystallization of saturated fatty acid methyl esters and their binary mixtures

Demand for biodiesel has increased due to being a more environmentally-friendly fuel. Cold weather operation of biodiesel is challenging due to fatty acid methyl ester (FAME) content in biodiesel. Saturated FAMEs crystallize at relatively high temperatures, increase the viscosity of biodiesel, and can clog fuel lines. Here, several factors altered crystallization temperature (CT) of FAMEs, including composition, shear rate, and cooling rate. The crystallization of pure and binary mixtures of methyl palmitate, methyl myristate, and methyl stearate were studied under shear flow and static conditions. Static phase CTs of pure methyl palmitate, methyl myristate, and methyl stearate were 26, 14, and 35°C, respectively. In binary mixtures, CTs were depressed up to 7°C, which agreed with freezing point depression theory. Increasing shear rate up to 100 s⁻¹ decreased CT by 2°C compared to static conditions. Decreasing cooling rate from 1 to 0.1°C/min increased CT less than 2°C. Overall, FAME composition altered CT more than shear flow or cooling rate for pure and binary mixtures of three FAMEs.