Tuning the Stability of Graphene Layers by Phthalocyanine‐Based oPPV Oligomers Towards Photo‐ and Redoxactive Materials

In contrast to pristine zinc phthalocyanine (1), zinc phthalocyanine based oPPV‐oligomers (2–4) of different chain lengths interact tightly and reversibly with graphite, affording stable and finely dispersed suspensions of mono‐ to few‐layer graphene—nanographene (NG)—that are photoactive. The p‐type character of the oPPV backbones and the increasing length of the oPPV backbones facilitate the overall π–π interactions with the graphene layers. In NG/2, NG/3, and NG/4 hybrids, strong electronic coupling between the individual components gives rise to charge transfer from the photoexcited zinc phthalocyanines to NG to form hundreds of picoseconds lived charge transfer states. The resulting features, namely photo‐ and redoxactivity, serve as incentives to construct and to test novel solar cells. Solar cells made out of NG/4 feature stable and repeatable photocurrent generation during several ‘on‐off’ cycles of illumination with monochromatic IPCE values of around 1%.     

All year power supply with off-grid photovoltaic system and clean seasonal power storage

The objective of the project is an all-year secure supply of alternating current based on a solar energy island grid consisting of serial components and seasonal energy storage. Photovoltaic modules, inverters, electrolysers, batteries, hydrogen stores and fuel cells form the basis of the independent power supply system. For this, selected load profiles were analysed and evaluated in theory and practice.The analysis is based on the results of the test runs of the system and the simulations, in which the combined hydrogen-battery-system is compared to the battery system.It was revealed that it is sensible to complement an island grid operating on lead batteries for shortterm energy supply with hydrogen as a long-term store. This ensures a year-round supply security based on solar energy and the extension of the life span of the batteries required for hydrogen-based power stores. The systems based purely on batteries can not provide perfect supply security during long periods of low solar radiation since they do not possess energy stores which allow long-term energy storage.Hence a seasonal energy store, such as hydrogen, is required to guarantee reliable power supply for every day of the year.Autonomous power supply systems with long-term energy stores operate independently from the public grid system and can be implemented without elaborate intelligent energy management. For this, however, the costs of the serial components must be reduced and the efficiency of the system must be improved.     

Swelling of PMMA-structures in aqueous solutions and room temperature Ni-electroforming

 LIGA-structures are known to have a lateral dimensional precision of 1 μm and below. These specifications strongly depend on the process parameters. Fabrication of 400 μm tall nickel LIGA-structures by electroplating of X-ray patterned (DXRL) resist structures revealed much higher distortions. These are caused on the one hand by thermal expansion of the structured resist since the electroforming is usually performed at 52 °C, but on the other hand to a higher degree by swelling of the resist in the aqueous electroplating bath. Reducing the electrolyte temperature not only eliminates the thermal expansion but also particularly reduces the swelling. At room temperature the latter is reduced by a factor of 3 in comparison to the usual 52 °C-bath leading to an overall reduction of the deformation of up to 80%. In this paper the experimental data are presented and the results are explained. Furthermore first microstructures electroplated at room temperature with optimized precision are shown.