Optimization techniques for spectrum handoff in cognitive radio networks using cluster based cooperative spectrum sensing

Wireless Networks - Spectrum handoff has an undesirable effect in utilizing the space for Secondary user (SU) in the spectrum, which causes a handoff delay in cognitive radio network. The SU...     

2-Acetyl-1-pyrroline: A key aroma component of aromatic rice and other food products

2-Acetyl-1-pyrroline is an aroma compound that gives aromatic rice its characteristic flavor. This compound either is present naturally in various food sources or is generated during certain processing methods, as reported in a number of studies. This review focuses on several sources of 2-acetyl-1-pyrroline, including aromatic rice, and the factors, including chemical and genetic parameters, affecting the formation of 2-acetyl-1-pyrroline. Extensive work has been conducted on the agricultural parameters, postharvest processing, storage, and cooking methods, influencing the concentrations of 2-acetyl-1-pyrroline in different food commodities. This article is an attempt to emphasize the importance of this compound in the food industry as a major aroma compound.     

Influence of Mg concentration on structural,morphological and optical properties of nanoceria

Nano crystalline pure and Mg doped ceriaparticles were synthesized by simple chemical co-precipitation method using cerium nitrate hexahydrate as a source material and magnesium nitrate as doping precursor at room temperature. The effect of doping were investigated by X-ray diffraction pattern(XRD), FT-Raman,fourier transform infrared spectroscopy(FTIR), Ultraviolet spectroscopy(UV), photoluminescence spectroscopy(PL), field emission scanning electron microscope(FESEM) and high resolution transmission electron microscopy with energy dispersive spectroscopy (HRTEM &EDS). The X-ray diffraction pattern and FT-Raman studies showed that the prepared samples were nano particulates with cubic fluorite structure. The XRD pattern analysis showed that the size of the particles ranged from 13 to 20?nm, however 4?wt% Mg doping results in reduction of particle size compared with other doping concentrations. The effects of Mg concentration on various structural parameters of the prepared samples were also determined. The slight blue shift observed upon doping in UV–Vis absorption region around 330–360nmrecorded for reduction in particle size. The FTIR unveils the presence of Metal oxygen bonds below 700?cm^?1in the prepared samples. All samples showed a broad emission band at 430?nm with linearly increasing intensity with respect to dopant concentrations. The Spherical morphology with weak agglomeration was identified through FESEM and HRTEM analysis. The elemental analysis of Ce, O and Mg were confirmed through EDS analysis.     

Modeling and Optimization of Reactive Extraction of Gallic Acid Using RSM

Reactive extraction was experimentally investigated for recovery of gallic acid (GA) from the aqueous solution using tri-n-octylamine (TOA) as extractant in hexanol. All experiments were carried out according to statistical design in order to develop a regression model used to optimize the extraction of GA. Two independent variables were selected as: initial concentration of GA (C_GA0) in aqueous phase and concentration of TOA (C_TOA) in organic phase. The statistical analysis showed that both the independent variables had significant effect on response value, followed by the quadratic and interactive effect on response. A five-level central composite rotatable design (CCRD) was employed. Analysis of variance (ANOVA) showed a high coefficient of determination (R²?=?99.0%). The optimal extraction conditions of GA were determined as: C_GA0?=?2.01?g/L, C_TOA?=?6.8% v/v. At the optimum conditions, the experimental yield of GA was 91.9%, which was in close agreement with the predicted value of 93.2%.     

Physicochemical Characterization of Interaction of Ibuprofen by Solid-State Milling with Aluminum Hydroxide

This present study is a preliminary exploration of the affinity between a carboxylic model drug ibuprofen and aluminum hydroxide. Ibuprofen was comilled with aluminum hydroxide in different weight ratios in the solid state and was characterized by scanning electron microscopy (SEM), X-ray powder diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), and in vitro dissolution studies. XRD and SEM studies indicated complete interaction of ibuprofen with aluminum hydroxide and complete amorphization of aluminum hydroxide–ibuprofen complexed salt as well, on comilling with aluminum hydroxide at 1:2 ratio. FTIR data showed the disappearance of acid carbonyl peak with the appearance and the corresponding increase in absorbance of new signal at 1,682 cm^?1 in the 1:1 and 1:2 ibuprofen–aluminum hydroxide-comilled powder. The accompanied increase in the absorbance of carboxylate peak in the ibuprofen–aluminum hydroxide physical mixture, and 1:0.1, 1:0.5, 1:1, and 1:2 (IBA_pm, and IB₁A_0.1, IB₁A_0.5, IB₁A₁, and IB₁A₂, respectively) comilled powder indicated an acid–base reaction between ibuprofen and aluminum hydroxide. On storage at 40°C and 75% relative humidity (RH) for 10 weeks, XRD study showed the absence of reversion to the crystalline state and FTIR data revealed continued increase of new signal at 1,682 cm^?1 relative to carboxylic acid peak and no reappearance of carboxylic acid peak. In vitro dissolution studies revealed that the percent release of ibuprofen from the aluminum hydroxide-comilled powder is in the following order: IB₁A₂ < IB₁A₁ < ibuprofen crystal < ibuprofen milled alone < IB₁A_0.1 < IB₁A_0.5. Aluminum metal cation might have interacted to form a complex through the carboxyl and carbonyl groups of ibuprofen. Improved dissolution of drug associated with IB₁A_0.1 and IB₁A_0.5 is because of the absence of a new signal at 1,682 cm^?1 and improved amorphization of the drug to some extent. Dissolution of drug affected in IB₁A₂ and IB₁A₁ may be because of the insoluble stable complex formation.     

Existence and Global Asymptotic Stability of Fuzzy Cellular Neural Networks with Time Delay in the Leakage Term and Unbounded Distributed Delays

Fuzzy cellular neural network (FCNN) structures are based on the uncertainties in human cognitive processes and in modeling neural systems, and they provide an interface between a human expert and classical cellular neural networks (CNNs). In this paper, an existence and global asymptotic stability analysis of the equilibrium point of FCNNs with time delay in the leakage term and unbounded distributed delays is investigated. Based on the Lyapunov-Krasovskii functional with free-weighting matrix, and using the homeomorphism mapping principle and linear matrix inequalities (LMIs), a new set of stability criteria for FCNNs is obtained with time delay in the leakage term, time-varying delays and unbounded distributed delays. The proposed results can be easily checked via the LMI Control Toolbox in MATLAB. Moreover, it is well known that the stability behavior of FCNNs is very sensitive to the time delay in the leakage term. In the absence of the leakage term, a new stability criterion is also derived by employing a Lyapunov-Krasovskii functional using an LMI approach. Numerical examples are provided to illustrate the effectiveness and reduced conservativeness of the developed techniques.     

Synthesis and characterization of niobium doped hexagonal tungsten bronze in the systems,Cs<Subscript>x</Subscript>Nb<Subscript>y</Subscript>W<Subscript>1−y</Subscript>O<Subscript>3</Subscript>

Samples of nominal compositions, Cs_0.25Nb _y W_1−y O₃ and Cs_0.3Nb _y W_1−y O₃ with 0.0 ≤ y ≤ 0.25 and 0.0 ≤ y ≤ 0.3 were synthesized using appropriate amounts of Cs₂WO₄, WO₃ and WO₂ in evacuated and closed silica glass tubes at 800 °C. The polycrystalline products contain hexagonal shaped crystals of up to 15 μm diameter as long as y ≤ 0.15. X-ray powder patterns of the samples reveal the formation of hexagonal tungsten bronze (HTB-I) type phase with y < 0.1. A mixture of HTB-I and an analogous less reduced hexagonal tungsten bronze (HTB-II) type phase is seen when y ≥ 0.1. HTB-II content increases with increasing y, revealing close similarity to bronzoid type phases when y = x. Results of SEM/EDX analysis also support a partial substitution of tungsten by niobium in the HTB-I type phase. Infrared absorption and optical reflectivity data shows the effect of increasing amount of non-metallic phase for y > 0.1 and the effect of counterdoping by Nb⁵⁺/W⁵⁺ substitution in the metallic HTB-I type phase for y ≤ 0.1, respectively. Reinvestigations in the system Rb_0.3Nb _y W_1−y O₃ (0.0 ≤ y ≤ 0.175) show similar results with increasing content of HTB-II type phase related with y.