Profiling hot isostatically pressed canister–wasteform interaction for Pu-bearing zirconolite-rich wasteforms

Zirconolite-rich full ceramic wasteforms designed to immobilize Pu-bearing wastes were produced via hot isostatic pressing (HIP) using stainless steel (SS) and nickel (Ni) HIP canisters. A detailed profiling of the elemental compositions of the major and minor phases over the canister–wasteform interaction zone was performed using scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDS) characterization. Bulk sample analyses from regions near the center of the HIP canister were also conducted for both samples using X-ray diffraction and SEM-EDS. The sample with the Ni HIP canister showed almost no interaction zone with only minor diffusion of Ni from the inner wall of the canister into the near-surface region of the wasteform. The sample with the SS HIP canister showed ∼100–120 μm of interaction zone dominated by high-temperature Cr diffusion from canister materials to the wasteform with the Cr predominantly incorporated into the durable zirconolite phase. We also examined, for the first time, changes to the HIP canister wall thickness caused by HIPing and demonstrated that no canister wall thinning occurred. Instead, in the areas examined, the canister wall thickness was observed to increase (up to ∼20%) due to the compression occurring during the HIP cycle. Further, only sparse formation of (Cr, Mn)-rich oxide particles were noted within the HIP canister inner wall area immediately adjacent to the ceramic material, with no evidence for reverse diffusion of ceramic materials. Though the HIP canister–wasteform interaction extends to ∼120 μm when using an SS HIP canister for the system investigated, this translates to <<1 vol.% for an industrial scale HIPed wasteform. Importantly, the HIP canister–wasteform interactions did not produce any obviously less durable phases in the wasteform or had any detrimental impact on the HIP canister properties.     

Hydroxyl Group Separation Distances in Anti-Freeze Compounds and Their Effects on Ice Nucleation

Since the discovery of biological antifreeze glycoproteins (AFGPs), which can inhibit ice nucleation, there has been considerable interest in understanding their mechanisms and mimicking them in synthetic polymers. In this study, we used molecular dynamics simulations of modified polyvinyl alcohol (PVA) compounds to show that the hydroxyl (OH) group distance is a key factor in whether certain compounds promote or inhibit ice nucleation. A hydroxyl distance smaller than ~2.8 Å but greater than ~7.1 Å in modified PVA (MPVA) compounds was associated with the promotion of ice nucleation, while a hydroxyl group separation distance of approximately ~5.0 Å was correlated with a delay in ice nucleation, owing to changes in the energy of the system. Thus, these results may help explain some of the mechanisms of current known anti-freeze compounds and may have implications for designing new anti-freeze compounds in the future.     

Conceptualizing the pedestrian mall in post-war North America and understanding its transatlantic transfer through the work and influence of Victor Gruen

Pedestrianization was an established concept among modernist architects and planners long before the first post-war pedestrian malls were built in North American downtowns. Post-war pedestrian-oriented suburban shopping malls, such as Northland near Detroit, MI and Northgate in Seattle, WA, linked retail success to the pedestrian shopping experience. This propelled the existing but then-untested assumption that planning downtowns to mimic suburban shopping centres by pedestrianizing main streets would revitalize downtown retail districts. Despite the modern origins of the pedestrianization concept, the rhetorical cues of post-war architects and planners in North America mask its modern roots and employ nostalgic imagery of pre-industrial European urbanism, implying European origin of the concept. Although imagery of European charm became a means of packaging modernist ideas of pedestrianization, the design proposals rarely referenced or replicated actual European precedents. Furthermore, while much research implies a linear transfer of pedestrianization ideas from Europe to North America, professionals in Europe also looked to North American shopping malls and pedestrian streets for guidance in addressing their own challenges with accommodating automobiles in downtowns.     

Overheating in care settings: magnitude,causes, preparedness and remedies

ABSTRACT

Research in UK and elsewhere has highlighted that older people are particularly vulnerable to negative health effects of overheating. This paper examines the magnitude, causes, preparedness and remedies for addressing the risk of summertime overheating in four case study residential care and extra-care settings across the UK, spanning different building types, construction and age. An interdisciplinary approach is adopted, drawing from building science and social science methods, including temperature monitoring, building surveys, and interviews with design and management teams. The findings suggest that overheating is a current and prevalent risk in the case study schemes, yet currently little awareness or preparedness exists to implement suitable and long-term adaptation strategies (e.g., external shading). There was a perception from designers to managers, that cold represents a bigger threat to older occupants’ health than excessive heat. A lack of effective heat management was found across the case studies that included unwanted heat gains from the heating system, confusion in terms of responsibilities to manage indoor temperatures, and conflicts between window opening and occupant safety. Given that care settings should provide protection against risks from cold and hot weather, design, management and care practices need to become better focused towards this goal.     

Gardening cyberspace—social media and hybrid spaces in the creation of food citizenship in the Bristol city-region,UK

Abstract

This paper conducts a detailed analysis of urban food and online networks in Bristol, UK. In particular, it examines social media postings of grass-roots food networks. Qualitative research identifies and analyses five core themes, from which two dominant discourses emerge. Analysis reinforces the multifunctional nature of city food but moves beyond dominant scholarly pre-occupations with nutrition and physical resources. Instead, the paper positions social and symbolic aspects as equal components within the convening power of food. To date, social media has been neglected in urban food research, although this is a space as well-tended and structured as the physical spaces it augments. The paper finds a relationship of limited collaboration between the grass-roots networks and the city council. While the former are dynamic and networked, the council adheres to a linear policy process that limits the scope of citizenship. The relationships examined here indicate implications for urban planning processes.     

Phosphorous limitation in an arctic river biofilm—A whole ecosystem experiment

A fourth-order arctic river was experimentally enriched with phosphate (7.7 ± 7.0 μ g 1⁻¹) to determine the effect of such a loading (equivalent to a community of 10,000 people) upon the trophically important biofilm. The effect upon a light-grown biofilm (an autotrophic/heterotrophic assemblage) and a dark-grown biofilm (predominantly heterotrophic assemblage) was determined after 28 days of colonization. Seven attributes of the biofilms were monitored, 2 autotrophic indices, chlorophyll , [¹⁴C]HCO₃ incorporation into lipids and 5 heterotrophic indices; [¹⁴C]acetate incorporation into lipids, metabolic heat output, turn-over times of microbially labile glucose and glutamate and mineralization of microbially recalcitrant ring-labelled [¹⁴C]hydroxybenzoic acid. The findings showed that the addition of phosphorus resulted in a substantial stimulation of both autotrophic and heterotrophic processes suggesting that arctic rivers of this type would be liable to cultural eutrophication.     

A pathway for net-zero energy buildings: creating a case for zero cost increase

To have market relevance and gain widespread market adoption, zero energy buildings (ZEBs) will need to be designed and constructed cost-effectively, and preferably without additional costs. An approach was developed to create low-energy buildings without additional construction costs such that it yielded innovation in building technology and integration by the market. A case study of the implementation of this method is presented to provide a data point that ZEBs can be built with zero cost increase. Documenting cost-control best practices and packaging those strategies for adoption by the commercial building sector will help make the business case for ZEBs for mainstream construction and promote market uptake of the innovative technologies and design approaches needed. The holistic implementation of cost-control strategies will enable ZEBs to be designed and constructed on a typical budget. The current state of ZEB economics is evaluated and a path forward is proposed for greater market penetration of ZEBs. By demonstrating how to combine ZEB technologies and design approaches into an overall efficiency package that can be implemented at minimal (zero, in certain cases) incremental capital cost, the domain of ZEB design and construction can be expanded from a niche market to the commercial construction mainstream.     

On-road experiment to assess drivers’ detection of roadside targets as a function of headlight system,target placement,and target reflectance

Adaptive headlights swivel with steering input to keep the beams on the roadway as drivers negotiate curves. To assess the effects of this feature on driver’s visual performance, a field experiment was conducted at night on a rural, unlit, and unlined two-lane road during which 20 adult participant drivers searched a set of 60 targets. High- (n = 30) and low- (n = 30) reflectance targets were evenly distributed on straight road sections and on the inside or outside of curves. Participants completed three target detection trials: once with adaptive high-intensity discharge (HID) headlights, once with fixed HID headlights, and once with fixed halogen headlights. Results indicated the adaptive HID headlights helped drivers detect targets that were most difficult to see (low reflectance) at the points in curves found by other researchers to be most crucial for successful navigation (inside apex). For targets placed on straight stretches of road or on the outside of curves, the adaptive feature provided no significant improvement in target detection. However, the pattern of results indicate that HID lamps whether fixed or adaptive improved target detection somewhat, suggesting that part of the real world crash reduction measured for this adaptive system (Highway Loss Data Institute (HLDI), 2012a) may be due to the differences in the light source (HID vs. halogen). Depending on the scenario, the estimated benefits to driver response time associated with the tested adaptive (swiveling HID) headlights ranged from 200 to 380 ms compared with the fixed headlight systems tested.     

Performative technologies for heritage site regeneration

Heritage sites are an important part of understanding our role in history. They have the potential to teach us important lessons, such as where we came from and subsequently, the people it has made us today. As members of a large, heritage-led, regeneration project, we are working with the Hafod–Morfa Copperworks, a heritage site in the Lower Swansea Valley where there is not much to see or hear. The few ruins at the site make it difficult to imagine what the site would have been like back in its heyday. Our goal at the site is to draw people together, not to view a finished piece of curated heritage, but rather, to start conversations about their memories and the significance of the site to them and to discover what they would like to see at the site in the future. The technology we are producing is about engaging with the local community and stakeholders as groups to provoke discussion. This contrasts with previous uses of mobile guides which only attempt to be tourist aids. In this article, we report on two prototype technologies we have developed to help accomplish this task. Throughout the article, we discuss how and why designing performative technologies could help encourage people to visit, socialise and communicate within the area. Our early results suggest that expressive performative technologies are good at gaining spectators’ attention and encouraging an active engagement between performer and spectator.