Microstructural and microwave dielectric properties of LZT (Li2ZnTi3O8) ceramics sintered in presence of bismuth borate glass for LTCC applications

In the present research, the Li₂ZnTi₃O₈(LZT) ceramics were synthesized throughout solid-state ceramic processing, then mixed with bismuth borate (BiBO) glass prepared based on conventional melt quenching method. Wetting behavior of BiBO glass on the LZT ceramic substrate was monitored by hot stage microscopy. Afterward, dielectric LZT ceramics containing different amounts of BiBO glass (0.25–6 wt%) were sintered at various temperatures. X-ray diffraction and electron back scatter diffraction examinations revealed the presence of two crystalline phases of Li₂ZnTi₃O₈ and Bi₂Ti₂O₇. The maximum value of relative density (above 95%) was obtained in the case of specimens contained more than 5 wt% glass. The microwave dielectric properties of the finally sintered BiBO glass containing LZT ceramics were as follows: dielectric constant (ε_r) = 21.44–25.09, quality factor (Q × f) = 10839–54708 GHz and temperature coefficient of resonant frequency (τ_f) = (? 15.58) ? (? 12.86)ppm/°C.     

Laboruntersuchungen zur Freisetzung von Unat aus einem Gestein unter oxischen naturnahen Bedingungen

Kurzfassung Im Labor wurden verschiedene Größen (pH-Wert, HCO ₃ —Gehalt, Präsenz von Fe(OH) ₃ ) untersucht, von denen angenommen werden konnte, dass sie die umweltrelevante Freisetzung von Uran aus Gesteinen (z. B. Haufwerken, Halden, Tailings) im neutralen und schwach basischen pH-Bereich (6 bis 9) beeinflussen. Hierzu wurde der Austrag von U _nat aus einem schwach vererzten Urangestein (2,31 %) in Batchversuchen untersucht. Diese Versuche wurden mit 8, 10 oder 40 g/l Gestein und Leitungs- bzw. Mineralwasser durchgeführt. Zum Vergleich wurden parallele Standversuche in deionisiertem Wasser, 0,1 M Na ₂ CO ₃ und 0,1 M H ₂ SO ₄ durchgeführt. Die Ergebnisse zeigen eine Begünstigung der Uranfreisetzung in Anwesenheit von Carbonat (gelöst oder in situ durch Dolomitauflösung entstanden), während die Rolle des Pyrits auf die Freisetzung deutlich komplexer ist. Das Erreichen eines Gleichgewichtszustands kann unter Umständen durch sorptive Einflüsse verzögert werden.

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Investigations for the release of U_nat from ore bearing rock under natural near oxic conditions

Abstract The effects of carbonate concentration and the presence of iron hydroxide phases on uranium release into the environment were investigated under oxic conditions and in the pH range from 6 to 9. For this purpose not-shaken batch experiments were conducted with a constant amount (8, 10 or 40 g/l) of a uranium bearing rock and different types of water (deionised, tap and mineral water). For comparison parallel experiments were conducted with 0.1 M Na ₂ CO ₃ and 0.1 M H ₂ SO ₄ . The use of dolomite confirmed the favourable role of carbonate bearing minerals for U transport while the presence of pyrite on Uranium mobilisation was shown to be considerably more complex. This study shows that the approach of equilibrium conditions can be strongly delayed by sorption processes.

     

An Improved On-line Contingency Screening for Power System Transient Stability Assessment

This paper presents a contingency screening method and a framework for its on-line implementation. The proposed method carries out contingency screening and on-line stability assessment with respect to first-swing transient stability. For that purpose, it utilizes the single machine equivalent method and aims at improving the prior developed contingency screening approaches. In order to determine vulnerability of the system with respect to a particular contingency, only one time-domain simulation needs to be performed. An early stop criteria is proposed so that in a majority of the cases the simulation can be terminated after a few hundred milliseconds of simulated system response. The method’s outcome is an assessment of the system’s stability and a classification of each considered contingency. The contingencies are categorized by exploiting parameters of an equivalent one machine infinite bus system. A novel island detection approach, appropriate for an on-line application since it utilizes efficient algorithms from graph theory and enables stability assessment of individual islands, is also introduced. The New England and New York system as well as the large-scale model of the Continental-European interconnected system are used to test the proposed method with respect to assessment accuracy and computation time.     

Creep compliance mapping by atomic force microscopy

We present a method for mapping the spatial distribution of viscoelastic properties of heterogeneous samples using the atomic force microscope (AFM). By applying a force step load protocol to induce time dependent sample indentations we measured the local creep compliance of the sample. The creep compliance was quantified in terms of the standard linear solid model to give maps of the instant glassy modulus, the equilibrium rubbery modulus, and the retardation time. To reduce the influence of plastic deformations, the sample was preformed with an initial preload step. Different polymer samples with a homogeneous or a heterogeneous material composition on a microscopic scale were investigated.     

An approach to mechanistic event recognition applied on monitoring organic matter depletion in SBRs

A fundamental practice in process engineering is monitoring the state dynamics of a system. Unfortunately, observability of some states is related to high costs, time, and efforts. The mechanistic event recognition (MER) aims to detect an event (defined as a change of the system with specific significance to the operation of the process) that cannot be directly observed but has some predictable effect on the dynamics of the systems. MER attempts to apply fault diagnosis techniques using mechanistic “recognition” models to describe the process. A systematic method for building recognition models using optimal experimental design tools is presented. As proof of concept, the MER approach to detect organic matter depletion in sequencing batch reactors, measuring only ammonia, dissolved oxygen, and nitroxides is applied. The event, that is, consumption of organic matter to a level below 50 gCOD/m³, was successfully detected even though microbial activity is known to continue after organic matter depletion. © 2014 American Institute of Chemical Engineers AIChE J, 60: 3460–3472, 2014     

Rapid Determination of the Amino Acid Configuration of Xenotetrapeptide

An E. coli strain with deletions in five transaminases (ΔaspC ΔilvE ΔtyrB ΔavtA ΔybfQ) was constructed to be unable to degrade several amino acids. This strain was used as an expression host for the analysis of the amino acid configuration of nonribosomally synthesized peptides, including the novel peptide “xenotetrapeptide” from Xenorhabdus nematophila, by using a combination of labeling experiments and mass spectrometry. Additionally, the number of D ‐amino acids in the produced peptide was assigned following simple cultivation of the expression strain in D₂O.     

Probing first-order spatial coherence of a Bose-Einstein condensate

Abstract

We probe the spatial coherence properties of a magnetically trapped Bose gas. Two matter wave beams are extracted from two spatially separated regions of the trap and overlap outside the trapping region. The visibility of the resulting interference pattern measures the phase coherence between the regions of extraction. By varying the spatial separation between the two regions the first-order spatial correlation function of the trapped Bose gas can be measured. The location of the minima of the interference pattern is reproducible, which experimentally confirms that the trapped Bose-Einstein condensate is not fragmented into individual condensates.     

Anisotropy Effects in the Shape-Memory Performance of Polymer Foams

Isotropic and anisotropic shape-memory polymer foams are prepared by supercritical carbon dioxide foaming from a multiblock copolymer (PDLCL) consisting of poly(ω-pentadecalactone) and poly(ε-caprolactone) segments. Analysis by micro-computed tomography reveals for the anisotropic PDLCL foam cells a high shape anisotropy ratio of R = 1.72 ± 0.62 with a corresponding Young's compression moduli ratio between longitudinal and transversal direction of 4.3. The experimental compression data in the linear elastic range can be well described by the anisotropic open foam model of Gibson and Ashby. A micro-morphological analysis for single pores using scanning electron microscopy images permits the correlation between the macroscopic stress-compression behavior and microscale structural changes.