排序方式: 共有5条查询结果,搜索用时 15 毫秒
1
1.
Muoz-Lpez Cesar Nadem Daz-Silvestre Sergio Telles-Padilla J. Guadalupe Rivera-Vallejo Claudia St Thomas Claude Jimnez-Regalado Enrique 《Polymer Bulletin》2020,77(5):2539-2555
Polymer Bulletin - Preparation of associating multiblock copolymer electrolytes mediated by radical addition–fragmentation chain transfer (RAFT) technique has been evaluated and reported in... 相似文献
2.
Synthesis,characterization and rheological properties of three different associative polymers obtained by micellar polymerization 总被引:1,自引:0,他引:1
Ana C. Lara-Ceniceros Claudia Rivera-Vallejo Enrique J. Jiménez-Regalado 《Polymer Bulletin》2007,58(2):425-433
Summary We report the synthesis, characterization and rheological properties in aqueous solutions of three different water-soluble
associative polymers (AP’s) (telechelic, multisticker and combined). Polymer chains consisting of water-soluble polyacrylamides,
hydrophobically modified with low amounts of N,N-dihexylacrylamide and a linear hydrophobic initiator. These have been prepared
via free radical micellar polymerization. We compare the properties of these different polymers, with respect to the localization
of the hydrophobic groups, using steady-flow experiments. In the semidiluted regime we clearly differentiate two different
zero-shear viscosity (η0) -vs- concentration (C) behaviors; a first semidiluted regime unentangled, where the viscosity increases strongly and directly
with c and a second regime entangled, where the viscosity increases proportionally to C4, independently of the localization of the hydrophobic group. 相似文献
3.
Sergio?E.?Díaz-Silvestre Claude?St Thomas Claudia?Rivera-Vallejo Gregorio?Cadenas-Pliego Marissa?Pérez-Alvarez Ramón?Díaz?de?León-Gómez Enrique?J.?Jiménez-RegaladoEmail author 《Polymer Bulletin》2017,74(10):4009-4021
In this work, we described the preparation of hydrosolubles thermosensitive copolymers obtained via free radical polymerization in aqueous media. The reactions were carried out under different molar ratio of acrylamide and N-isopropylacrylamide (NIPAM) and are considered [80]/[20], [60]/[40], [50]/[50], [40]/[60] and [20]/[80], respectively. The initial concentration of monomer mixture was kept at 3% (weight) based on the water volume. The polymerizations were performed at 70 °C under mechanical agitation during 7 h and the molar ratio between monomer and initiator (4,4′-azobis cyano pentanoic acid) was kept at 0.07%. The copolymers were characterized and results demonstrated that the monomer concentrations were closed to previously feed to the reaction. The turbidity point rises according to the quantity of poly(acrylamide), PAM, incorporated into the copolymers (composition value). Also, it was observed that the molecular weight of each copolymer decreases when the amount of NIPAM increases. On the other hand, the viscosity of all copolymers growth compared to the increase in the temperature from 25 to 70 °C is observed. Notwithstanding, in the case of copolymer with highest NIPAM concentration (CP5), the viscosity decreases in the temperature range from 60 to 70 °C. 相似文献
4.
Ana C. Lara-Ceniceros Claudia Rivera-Vallejo Enrique J. Jiménez-Regalado 《Polymer Bulletin》2007,59(4):499-508
Summary The synthesis, characterization and rheological properties in aqueous solution of two telechelic polymers of different structures
and size are reported: they are water soluble polyacrylamides, hydrophobically modified with linear and di-substituted hydrophobic
initiators. The polymers were prepared via free radical micellar polymerization. The results of static light scattering (SLS),
showed similar weight-average molecular weights (Mw) in all of the synthesized polymers. No signal corresponding to the presence of the hydrophobic group of the initiator could
be observed by 1H NMR; however, the presence of these hydrophobic groups was demonstrated using rheological measurements. 相似文献
5.
César Muñoz-López Claude St Thomas Luis Alfonso García-Cerda Claudia Rivera-Vallejo Enrique Jiménez-Regalado 《应用聚合物科学杂志》2021,138(43):51270
The impact of additives on the rheological behavior of four associating water-soluble multiblock polyelectrolytes previously synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization was described. These polyelectrolytes contained different number of blocks ranged from 1 to 7 divided into hydrophilic and hydrophobic. The rheological analyses of polymers were performed at 25°C at a given concentration (0.1–15 wt%) in the presence of sodium chloride (NaCl) 0.1–0.5 M, sodium dodecyl sulfate (SDS) 2–10 mM or a mixture of both. Data demonstrated an increase in the viscosity of macroRAFT (ɳ = 0.002–9 Pa·s) and triblock copolymer-TBC (ɳ = 0.003–0.04 Pa·s) versus the concentration of NaCl. Meanwhile, the viscosity of penta and heptablock copolymer exhibited a diminution whatever the (NaCl) used. Results from the rheological analyses of the associative polyelectrolytes at different (SDS) revealed that the viscosity of macroRAFT and triblock copolymer was kept constant in spite of the increment of the (SDS) while the viscosity of PBC and HBC displayed a pronounced diminution at the lower (SDS). Finally, the results from the rheological analyses of these polyelectrolytes versus a mixture of NaCl-SDS showed a diminution in the viscosity of these solutions at any concentration of additives. 相似文献
1