Surface Modification of Co3O4 Nanosheets to Promote Peroxymonosulfate Activation for Degradation of Atrazine

Catalysis Letters - This study proposed a new facile route to rational creating oxygen-vacancy (Vo)-rich surface of Co3O4 nanosheets by acetic acid leaching. The acid leached Co3O4 nanosheets was...     

多堆厂址始发事件分析探讨

多堆厂址一级概率安全评价（PSA）研究中，机组数目的增加使得建模工作量剧增，给整个核电厂的风险评估带来困难。结合已有基础，本文研究了多堆厂址始发事件分析的筛选方法，提出利用堆芯损伤频率（CDF）上下限值评估方法，分析厂址内不同机组数对厂址CDF的影响。结果表明，双机组厂址适合优先进行具体分析。针对双机组核电站，对多堆厂址内各始发事件进行筛选。结果表明，丧失厂外电、丧失热阱等事件适合建模分析，并对其他筛选结果给出后续分析建议，为多堆厂址一级PSA后续事故序列建模工作提供了重要基础。     

某工业园区污水处理厂升级改造工程案例分析

以河北某园区污水处理厂提标改造工程为研究对象,通过对污水厂来水组成调研、取样、化验分析、试验,确定水解酸化+MBR+臭氧催化氧化组合工艺为主要设计方案.根据调试及运行结果,MBR组合工艺系统运行稳定,出水达到《地表水环境质量标准》(GB 3838—2002)地表水Ⅳ类标准(除TN外),根据长期实际运行效果,出水CODCr≤30 mg/L、氨氮≤1 mg/L、TN≤10 mg/L、TP≤10 mg/L,SS≤0.7 mg/L,出水回用于当地景观水体.本项目的设计与实施为类似工业园区污水处理厂尤其是存在较高难降解有机物、TN去除率要求高的污水厂提标改造提供了参考经验.     

Failure mechanism of gently inclined shallow landslides along the soil-bedrock interface on ring shear tests

Bulletin of Engineering Geology and the Environment - There were many gently inclined shallow landslides along the soil-bedrock interface at a depth of 3–5 m in Nanjiang County, Sichuan...     

Comparison of γ-aminobutyric acid accumulation capability in different mung bean (Vigna radiata L.) varieties under heat and relative humidity treatment,and its correlation with endogenous amino acids and polyamines

In this study, the accumulation of GABA and its inherent factors across different varieties of mung bean (Vigna radiata L.) in response to heat and relative humidity (HRH) were investigated. Results showed the average GABA content in mung bean varieties was increased 7.52 times following HRH treatment, and the black mung bean variety (A8) exhibited the highest GABA accumulation capability (1.76–84.57 mg per 100 g DW). From the perspective of GABA shunt metabolites, the free glutamic acid content of mung beans significantly decreased (P < 0.05) after HRH treatment and presented a significant correlation (P < 0.05) with GABA content. In polyamine degradation pathway, although the average levels of spermine and spermidine of mung bean varieties significantly decreased (P < 0.05) after HRH treatment, no significant correlation with GABA content was identified. Hence, the GABA accumulation was predominantly attributed to GABA shunt. Besides, free amino acids including glutamic acid, serine, ornithine, arginine and glycine in mung beans showed a significant positive correlation (P < 0.05) with GABA content and increment following HRH treatment, which suggested that mung beans enriched in these free amino acids might accumulate higher amounts of GABA after HRH treatment and be useful for industrial applications.     

Application of kinetics and computational fluid dynamics in pinene isomerization

A reliable kinetic model to describe the effects of various factors on the reaction rate and selectivity of pinene isomerization is developed. Furthermore, computational fluid dynamics(CFD) is applied to simulate the solid–liquid dispersion in reactor. The catalyst Ti M is obtained by improving the composition and structure of hydrated titanium dioxide. The kinetic equation of pinene isomerization is deduced based on reaction mechanism and catalyst deactivation model. The kinetic equation of pinene isomerization reaction is fitted, and the results show that the fitted equation is correlated with the experimental data. The rate and selectivity of pinene isomerization reaction are affected by the amount of catalyst, deactivation of catalyst, structure of catalyst, reaction temperature and water content of catalyst. The solid–liquid distribution of the reactor is calculated by computational fluid dynamics numerical simulation, and the solid–liquid dispersion in commercial scale reactor is more uniform than that in lab-scale reactor.     

基于梯度范数的暂态稳定评估模型的不平衡修正方法

为了解决电力系统中样本数量和质量不平衡造成的暂态稳定评估偏差问题,从评估模型的训练过程出发,通过预训练模型获得样本对模型参数修正的梯度范数,引入梯度范数均值比量化样本的不平衡程度,相较于先验信息,梯度范数均值比综合考虑了样本数量与样本质量的不平衡,并提出基于代价敏感法的不平衡修正方法,利用该方法改善模型的评估倾向性,以实现较好的修正效果。IEEE 39节点系统和华东电网系统的仿真结果验证了所提方法的有效性。     

西藏高海拔地区建筑物防雷接地环境研究

西藏高海拔地区建筑物雷击灾害严重,为弄清其防雷接地环境,探索出合适的防雷接地降阻措施,从建筑场地取回岩石样本,利用岩石取芯机钻取圆柱岩样,在岩样两端面用导电胶外粘金属电极片,在直流伏安电阻测试系统中采用二极法测试不同环境温度下岩石的电阻率,分析岩性和环境温度对岩石电阻率的影响。结果表明：受成岩矿物的影响,相同条件下,花岗岩电阻率高于砂岩电阻率;岩石电阻率随温度降低而升高,正温对岩石电阻率影响较小,而负温对岩石电阻率影响较大,-30℃时花岗岩的电阻率比10℃时的电阻率大11倍。总的来说,对于以花岗岩为主要岩石类型、雷击发生于冬季且集中于夜里的高海拔地区建筑物,其防雷接地环境是十分恶劣的。     

Deep ocean bubble transport model coupled with multiple hydrate behavior characteristics

Submarine gas seepage is a widely observed process. In this study, a unified mechanistic model of bubble transport both inside and outside the gas hydrate stability zone (GHSZ) was developed. Multiple hydrate-related behaviors were considered, including hydrate nucleation, hydrate film lateral spread, hydrate shell dynamic growth, hydrate dissolution and decomposition, and collapse and fracture deformation of hydrate-coated bubbles. Using the proposed model, a series of simulation studies about bubble dissolution and rising fate were conducted. The results indicate that the formation of solid hydrates in the deep-sea environment can provide a fairly effective barrier for the dissolution and shrinkage of bubbles, and the deeper the initial release water depth, the smaller the critical size of the bubble required for arriving at the water surface. Furthermore, the majority of gases released from the seafloor would be absorbed by the shallow oceanic layer, but larger bubbles could still pass through the water column to the atmosphere.     

在建工程旁埋地天然气管道沉降监测实验

对在建上海中心工程项目周边的天然气埋地管道进行了沉降监测,发现在监测期间,最大的正变形量为10mm,最大的负变形量-8mm;对监测结果进行了数值拟合和误差分析。