An economical synthesis of the major sex attractant of the oak leaf roller—cis-10-tetradecenyl acetate

The major sex attractant of the oak leaf roller (Archips semiferanus Walker),cis-10-tetradecenyl acetate (I), was synthesized in 55–62% overall yield by a highly economical route from inexpensive azelaic acid (II).Authorized as Paper No. 4779 in the Journal Series of the Pennsylvania Agricultural Experiment Station.     

Randomized mutual exclusion on a multiple access channel

In this paper we consider the mutual exclusion problem on a multiple access channel. Mutual exclusion is one of the fundamental problems in distributed computing. In the classic version of this problem, n processes execute a concurrent program that occasionally triggers some of them to use shared resources, such as memory, communication channel, device, etc. The goal is to design a distributed algorithm to control entries and exits to/from the shared resource (also called a critical section), in such a way that at any time, there is at most one process accessing it. In our considerations, the shared resource is the shared communication channel itself (multiple access channel), and the main challenge arises because the channel is also the only mean of communication between these processes. We consider both the classic and a slightly weaker version of mutual exclusion, called \(\varepsilon \)-mutual-exclusion, where for each period of a process staying in the critical section the probability that there is some other process in the critical section is at most \(\varepsilon \). We show that there are channel settings, where the classic mutual exclusion is not feasible even for randomized algorithms, while the \(\varepsilon \)-mutual-exclusion is. In more relaxed channel settings, we prove an exponential gap between the makespan complexity of the classic mutual exclusion problem and its weaker \(\varepsilon \)-exclusion version. We also show how to guarantee fairness of mutual exclusion algorithms, i.e., that each process that wants to enter the critical section will eventually succeed.     

Analysis of the effect of structural defects on the fatigue strength of RFSSW joints using C‐scan scanning acoustic microscopy and SEM

Solid‐state refill friction stir spot welding (RFSSW) technology offers significant benefits in the fabrication of aluminium structures in the transport and aerospace industries. In this paper, the joining of 1.6‐mm‐thick Alclad 7075‐T6 aluminium alloy sheets is investigated. High‐cycle fatigue strength tests of single‐lap welded joints were carried out on an Instron E10000 testing machine with a limited number of cycles equal to 2 × 10⁶. The welding of overlap fatigue specimens was conducted using an RPS100 spot welder by Harms & Wende GmbH & Co KG. C‐mode scanning acoustic microscopy (C‐SAM) and scanning electron microscopy (SEM) were utilised to evaluate the joint quality and characterise the microstructure. The paper discusses the effect of the maximum load force and defects (voids, hook, kissing bond, bonding ligament, etc) associated with the material flow in the weld on the failure mechanism. Insufficient plasticisation of sheet material and mixing of the material in the weld area are crucial defects that influence the number of destructive cycles. The weld defects in the joint structure are a source of a decrease in the fatigue life compared with the fatigue life of defect‐free welds. It was also found that RFSSW joint defects can be effectively detected by the nondestructive C‐SAM method.     

Endfire tapered slot antennas on dielectric substrates

Endfire tapered slot antennas are suitable for many integrated circuit applications, imaging and phased arrays. We report on an investigation of single elements of such antennas, including slots which are exponentially tapered (Vivaldi), linearly tapered (LTSA) and constant width (CWSA). For antennas of all types, a good general agreement is obtained for curves of beamwidth versus length, normalized to wavelength, when one compares the data with that for traveling-wave antennas published by Zucker. An important condition for this agreement is that the effective dielectric thickness, defined in the text, is in a certain optimum range. This condition is qualitatively explained in terms of the theory for traveling-wave antennas.     

Sources, fate and transport of perfluorocarboxylates

This review describes the sources, fate, and transport of perfluorocarboxylates (PFCAs) in the environment, with a specific focus on perfluorooctanoate (PFO). The global historical industry-wide emissions of total PFCAs from direct (manufacture, use, consumer products) and indirect (PFCA impurities and/or precursors) sources were estimated to be 3200-7300 tonnes. It was estimated that the majority (approximately 80%) of PFCAs have been released to the environment from fluoropolymer manufacture and use. Although indirect sources were estimated to be much less importantthan direct sources, there were larger uncertainties associated with the calculations for indirect sources. The physical-chemical properties of PFO (negligible vapor pressure, high solubility in water, and moderate sorption to solids) suggested that PFO would accumulate in surface waters. Estimated mass inventories of PFO in various environmental compartments confirmed that surface waters, especially oceans, contain the majority of PFO. The only environmental sinks for PFO were identified to be sediment burial and transport to the deep oceans, implying a long environmental residence time. Transport pathways for PFCAs in the environment were reviewed, and it was concluded that, in addition to atmospheric transport/degradation of precursors, atmospheric and ocean water transport of the PFCAs themselves could significantly contribute to their long-range transport. It was estimated that 2-12 tonnes/ year of PFO are transported to the Artic by oceanic transport, which is greater than the amount estimated to result from atmospheric transport/degradation of precursors.     

Plants—the origin of kairomones utilized by parasitoids of phytophagous insects?

Chemicals previously identified as kairomones utilized by parasitoids have been found in significant quantities in food plants of host insects. Different plant species contain varying concentrations and ratios of these chemicals. Feeding studies with chemically labeled kairomones indicate that these cues are concentrated and released unaltered by the host insect. In this report, a theoretical framework consistent with these findings is considered.     

Rekonstruktion des Baudenkmals “Das grüne Tor” in Danzig nach einem Teil einsturz

Rehabilitation of the structure of the “Green Gate” in Gdansk. The Green Gate is a historical building dating back to the 16th century. Its support‐based design consists of brick walls and pillars that are based on a timber beam grillage foundation supported by wooden piles. Out of the five over‐ground storeys, three are accommodated under a steep roof of timber and reinforced concrete structure and covered with tiles. Through the centuries of its existence the building was frequently rebuilt and redeveloped. The state of affairs before the incident of January 2002 dated back to the 50's of the 20th century. It was then that the building was rebuild after the damages it had suffered during the 2^nd World War. The incident resulted in a damage to the internal independent stone pillar along with the brick vault that it supported. The article mentions the reasons behind the incident that took place and the way the damaged part of the building was rebuilt. The study also offers general outline of the reconstruction concept for the whole building, with particular stress on the supporting structure of the vaults and the ceilings of the roof and of individual storeys.     

High-resolution atmospheric modeling of fluorotelomer alcohols and perfluorocarboxylic acids in the North American troposphere

A high spatial and temporal resolution atmospheric model is used to evaluate the potential contribution of fluorotelomer alcohol (FTOH) and perfluorocarboxylate (PFCA) emissions associated with the manufacture, use, and disposal of DuPont fluorotelomer-based products in North America to air concentrations of FTOH, perfluorooctanoic acid (PFOA), and perfluorononanoic acid (PFNA) in North America and the Canadian Arctic. A bottom-up emission inventory for PFCAs and FTOHs was developed from sales and product composition data. A detailed FTOH atmospheric degradation mechanism was developed to simulate FTOH degradation to PFCAs and model atmospheric transport of PFCAs and FTOHs. Modeled PFCA yields from FTOH degradation agree with experimental smog-chamber results supporting the degradation mechanism used. Estimated PFCA and FTOH air concentrations and PFCA deposition fluxes are compared to monitoring data and previous global modeling. Predicted FTOH air concentrations are generally in agreement with available monitoring data. Overall emissions from the global fluorotelomer industry are estimated to contribute approximately 1-2% of the PFCAs in North American rainfall, consistent with previous global emissions estimates. Emission calculations and modeling results indicate that atmospheric inputs of PFCAs in North America from fluorotelomer-based products will decline by an order of magnitude in the near future as a result of current industry commitments to reduce manufacturing emissions and lower the residual fluorotelomer alcohol raw material and trace PFCA product content.     

In vitro antibiotic susceptibility of salmonellae

In vitro antibiotic susceptibilities were determined for 101 strains of salmonellae. Resistance to chloramphenicol and ampicillin was low. Cefamandole was active against the majority of strains and deserves further evaluation.