Synthesis and photovoltaic properties of mono-substituted quaterthiophenes bearing strong electron-withdrawing group

We report here on the synthesis and properties of a monosubstituted quaterthiophene derivative asymmetrically functionalized by an electron-withdrawing group using the palladium-catalyzed Stille's coupling reaction. The UV–vis absorption spectrum evidences a strong intramolecular charge transfer transition. Thus oligothiophenes act as electron donors and substituent group as acceptor. The diodes in which monosubstituted quaterthiophenes behave as organic semiconductors, exhibit a rectifying behavior. Photovoltaic measurements show moderate power conversion efficiency.     

Organization and management in construction: a new approach

Operational management theory is considered and the traditional organizational problems experienced in construction and similar organizations, created by the matrix structure of management traditionally used at head office and project levels, are discussed. A new concept that is based on the formation of small but fully- independent functional companies with contractual relationships with the parent organization is introduced. The feasibility of a management structure of this type is considered. It is concluded that the new system is potentially capable of improving the productivity of resource and service groups and creating a rational basis for sharing of professional services nationwide, while at the same time improving such matters as staff motivation, job satisfaction, personal development, unity of command, ease of communication and flexibility in organization.     

Criticism of CPM for Project Planning Analysis

Published criticism in recent years concerning the inadequacy of Critical Path Method (CPM) as a project planning tool is identified and grouped under six major headings with reference to the publications in which the criticism were contained. These are answered from the writer's field experience and from experiences published by other authors. The object of the analysis is to see whether or not CPM as a project planning tool can meet the required functions of planning in construction, including consideration of legal and contractual framework and the complex and interdisciplinary nature of the project environment. The analysis reveals that, despite numerous criticism, project and construction planning should be done using CPM scheduling. Main factors affecting successful planning are realistic estimation of the productivity of crews in the context of expected job‐management efficiency conditions, and inclusion of sufficient time buffers between dissimilar trades. CPM is found to be equally useful as a planning tool for linear or repetitive projects. The limitations of this technique are identified in terms of the defined planning functions in the engineering phase of capital projects. A broad model for management of the engineering phase in revenue‐generating projects is suggested.     

Construction management know-how for transnational projects

Characteristics of transnational projects are outlined and their environment reviewed with a view to highlighting those external variables that affect managerial functions in such projects. Reference is made to the published experiences on some macroprojects executed in various parts of the world. It is concluded that the know-how in this field is at best sketchy and unrelated to the actual managerial needs. Many of the present techniques and associated infrastructures are inadequate for handling transnational projects. Specifically, the techniques for the estimation of resources and costs, for the handling of information requirements and for financial transactions are substantially underdeveloped and unreliable.     

Preparation,Characterization, and Mucoadhesive Properties of Chitosan-Coated Microspheres Encapsulated with Cyclosporine A

The aim of this study was to prepare and characterize chitosan-coated microspheres containing cyclosporine A (CyA). Microspheres encapsulated with CyA were prepared by solvent evaporation-emulsification methods. Microspheres were immersed in chitosan solution (0.5% w/w) to be coated. Morphology, mean size, and encapsulation efficiency of chitosan-coated microspheres were evaluated. To assess the mucoadhesive properties of this drug delivery system, the percent of mucin adsorption to the surface of coated microspheres was determined. Microspheres were spherical in shape. Encapsulation efficiency of different microsphere formulations varied from 78% to 92%. According to the mucin adsorption results, this particulate system showed suitable mucoadhesive properties. It can be concluded that surface modification of microspheres by chitosan coating would increase the prospects of their usefulness as oral drug delivery systems for CyA.     

VIRCON: Interactive System for Teaching Construction Management

The focus in this paper is on a system, developed by the writers, called VIRCON (short for VIRtual CONstruction), in which the traditional construction planning is combined with 3D∕4D models of the project. To facilitate current best practices with 3D∕4D models of the project, VIRCON has been implemented using object-oriented programming, client/server configuration, database management information, and CAD systems. The real innovation in the design of VIRCON is associated with the unique scheduling and simulation engine developed to integrate cost planning and scheduling and accommodate integrated cross-impact analysis. VIRCON has been validated by means of student group projects on a course where many of the project management techniques are being taught. The teaching approach conducted with the utilization of VIRCON has shown the way forward in creating a dynamic and interactive learning atmosphere. This paper also outlines the experience gained from teaching construction planning fundamentals by means of the VIRCON system.     

Fabrication of Biogenic Silica Nanostructures from Sorghum bicolor Leaves for Food Industry Applications

Silicon - Due to the large production of sorghum, the generation of associated agricultural residues, which contain high contents of silica, is inevitable. Also, these agricultural residues are not...     

A study of Cr(VI) and NH4+adsorption using greensand (glauconite) as a low‐cost adsorbent from aqueous solutions

This paper investigates the removal of Cr(VI) and NH⁴⁺ from aqueous solutions using greensand (glauconite). The effects of adsorbent dosage, contact time, initial Cr(VI) and NH⁴⁺ concentrations, and pH were investigated in batch experiments. The results show that these parameters influenced Cr(VI) and NH⁴⁺ removal using glauconite considerably. Pseudo‐first‐order, pseudo‐second‐order and intraparticle diffusion kinetic models were applied to explain the kinetic data, and the pseudo‐second‐order model achieved good agreement. The equilibrium isotherm data are coordinated with the Freundlich, Langmuir models, Temkin and Dubinin–Radushkevich; the Freundlich model proved most best suitable. The removal efficiency of Cr(VI) and NH₄⁺ were 12.21 mg/g (54% at pH 3) and 19.24 mg/g (77.08% at pH 7). All in all, the results showed that the adsorption process on glauconite could be used as an effective method for removing Cr(VI) and NH⁴⁺ from aqueous solutions.     

A Simulation Model for Life Cycle Project Management

This paper puts forward a simulation model specifically designed for holistic evaluation of project functionality within a life cycle project management framework. The authors describe a methodology for development of the aforementioned tool, referred to as a dynamic simulation modeling system (DSMS). The DSMS is geared toward modeling of service and manufacturing processes with hierarchical and modular modeling methodology; however, the underlying philosophy can be adopted for modeling any generic system. The enhanced modeling features and logical division of large systems into small process components and their internal linkage are the key contributions of this work. The aim of this development is to apply the simulation technique in order to evaluate the overall project functionalities from the dynamic business perspective. A set of business objective functions (i.e., life cycle objective function [LCOF]) has been employed as a basis for decision making throughout the project's life. Object-oriented programming language with the object-oriented database technology facilitates the necessary model capability. A brief case study has been used to demonstrate and discuss the model capability.     

J. Cosmet. Sci., 59, 385–398 (September/October 2008)Evaluation of liposomal and conventional formulations of octyl methoxycinnamate on human percutaneous absorption using the stripping method

The objective of this study was to determine the influence of vehicles on the penetration of octyl methoxycinnamate (OMC), as a UV absorber, to the stratum corneum by the stripping method. The experimental formulations consisted of a conventional o/w emulsion and multilamellar and small unilamellar liposomes (MLVs and SUVs) containing OMC. MLVs containing OMC were prepared by the fusion method and then converted to SUVs by probe sonication. Various formulations were then applied onto the midvolar forearms of six volunteers at a dose of 2 mg cm^-2. After determined timepoints, the stripping method was conducted whereby 22 tape strips were applied and subsequently divided into different stripping groups. The sunscreen agent was assessed by HPLC while the SPF (sun protection factor) of the formulations was determined in human volunteers in accordance with the Australian standard. Overall the results indicate that skin accumulation of OMC in MLVs was significantly greater than in the o/w emulsion and SUVs. Furthermore, SUV's penetration into the deeper skin layers was significantly greater than MLV's and that of a conventional o/w emulsion. Also, higher amounts of OMC were recovered from the upper layers of the stratum corneum than from the deeper layers in all the formulations tested. Finally, the SPF of the liposomes containing OMC was slightly greater than that of the control lotions at a similar concentration of OMC. In conclusion, the result of this study indicates that an MLV prepared by the fusion method could be a better vehicle for OMC as a sunscreen since it has a slightly better SPF compared to a conventional formulation and more remains in the stratum corneum, reducing its penetration to the deeper layers.
Address all correspondence to M. R. Jaafari.