Mehrstrom-Wärmeaustauscher als gelötete Aluminium-Plattenapparate – Stand des Wissens

Multi-flow heat exchangers as soldered aluminium plate equipment – State of the art. Soldered aluminium plate heat exchangers are the most frequently used pieces of equipment for heat exchange between clean fluids in cryogenic and low temperature processes. Equipment of this type combines high flexibility in the flow arrangement, high heating surface densities (up to 1400 m²/m³), low pressure drops, and low production costs. This article provides a survey of the present state of the art of their manufacture and thermal dimensioning. In conclusion, new developments are treated.     

Atom probe tomography and transmission electron microscopy characterisation of precipitation in an Al-Cu-Li-Mg-Ag alloy

State-of-the art atom probe tomography (APT) combined with transmission electron microscopy (TEM) were used to investigate the microstructure at different stages of the ageing process of an alloy of composition (at%) Al-1.68%Cu-4.62%Li-0.33%Mg-0.1%Ag. These alloys were shown to exhibit a complex microstructure of T₁ plates and several metastable phases, including θ′ and S. We will highlight the early stages of clustering, precipitate interactions and possible solute segregation at the matrix/precipitate interfaces and detail the chemical composition of the different phases.     

Optimisation of specimen temperature and pulse fraction in atom probe microscopy experiments on a microalloyed steel

This paper details the effects of systematic changes to the experimental parameters for atom probe microscopy of microalloyed steels. We have used assessments of the signal-to-noise ratio (SNR), compositional measurements and field desorption images to establish the optimal instrumental parameters. These corresponded to probing at the lowest possible temperature (down to 20 K) with the highest possible pulse fraction (up to 30%). A steel containing a fine dispersion of solute atom clusters was used as an archetype to demonstrate the importance of running the atom probe at optimum conditions.     

An electron tomography algorithm for reconstructing 3D morphology using surface tangents of projected scattering interfaces

Upon discerning the mere shape of an imaged object, as portrayed by projected perimeters, the full three-dimensional scattering density may not be of particular interest. In this situation considerable simplifications to the reconstruction problem are possible, allowing calculations based upon geometric principles. Here we describe and provide an algorithm which reconstructs the three-dimensional morphology of specimens from tilt series of images for application to electron tomography. Our algorithm uses a differential approach to infer the intersection of projected tangent lines with surfaces which define boundaries between regions of different scattering densities within and around the perimeters of specimens. Details of the algorithm implementation are given and explained using reconstruction calculations from simulations, which are built into the code. An experimental application of the algorithm to a nano-sized Aluminium tip is also presented to demonstrate practical analysis for a real specimen.

Program summary

Program title: STOMO version 1.0Catalogue identifier: AEFS_v1_0Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEFS_v1_0.htmlProgram obtainable from: CPC Program Library, Queen's University, Belfast, N. IrelandLicensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.htmlNo. of lines in distributed program, including test data, etc.: 2988No. of bytes in distributed program, including test data, etc.: 191 605Distribution format: tar.gzProgramming language: C/C++Computer: PCOperating system: Windows XPRAM: Depends upon the size of experimental data as input, ranging from 200 Mb to 1.5 GbSupplementary material: Sample output files, for the test run provided, are available.Classification: 7.4, 14External routines: Dev-C++ (http://www.bloodshed.net/devcpp.html)Nature of problem: Electron tomography of specimens for which conventional back projection may fail and/or data for which there is a limited angular range. The algorithm does not solve the tomographic back-projection problem but rather reconstructs the local 3D morphology of surfaces defined by varied scattering densities.Solution method: Reconstruction using differential geometry applied to image analysis computations.Restrictions: The code has only been tested with square images and has been developed for only single-axis tilting.Running time: For high quality reconstruction, 5-15 min     

Cognitive load and instructionally supported learning with provided and learner-generated visualizations

This study investigated, whether learning from science texts can be enhanced by providing learners with different forms of visualizations (pictures) in addition to text. One-hundred-two 9th and 10th graders read a computer-based text on chemical processes of washing and answered questions on cognitive load (mental effort, perceived difficulty) and comprehension (retention, transfer, drawing). Instruction varied according to a 2 × 2-factorial design with ‘learner-generated pictures’ (yes, no) and ‘provided pictures’ (yes, no) as factors. Results indicate positive main effects of provided pictures on all three comprehension measures and negative main effects on both cognitive load measures. Additional analyses revealed a mediation effect of perceived difficulty on retention and transfer, that is learning with provided pictures decreased cognitive load and enhanced comprehension. Furthermore, results show a positive main effect of learner-generated pictures on drawing and mental effort, but no mediation effect. Taken together, computer-based learning with provided pictures enhances comprehension as it seems to promote active processing while reducing extraneous cognitive processing. Learners, generating pictures, however, seem to have less cognitive resources available for essential and generative processing, resulting in reduced comprehension. These results are in line with cognitive load theory, cognitive theories of multimedia learning, and generative theories of learning.     

Nano-structured solid oxide fuel cell design with superior power output at high and intermediate operation temperatures

A solid oxide fuel cell (SOFC) with a thin-film yttria-stabilized zirconia (YSZ) electrolyte was developed and tested. This novel SOFC shows a similar multilayer set-up as other current anode-supported SOFCs and is composed of a Ni/8YSZ anode, a gas-tight 8YSZ electrolyte layer, a dense Sr-diffusion barrier layer and a LSCF cathode. To increase the power density and lower the SOFC operating temperature, the thickness of the electrolyte layer was reduced from around 10 μm in current cells to 1 μm, using a nanoparticle deposition method. By using the novel 1 μm electrolyte layer, the current density of our SOFC progressed to 2.7, 2.1 and 1.6 A/cm² at operation temperatures of 800, 700 and 650°C, respectively, and out-performs all similar cells reported to date in the literature. An important consideration is also that cost-effective dip-coating and spin-coating methods are applied for the fabrication of the thin-film electrolyte. Processing of 1 μm layers on the very porous anode substrate material was initially experienced as very difficult and therefore 8YSZ nanoparticle coatings were developed and optimized on porous 8YSZ model substrates and transferred afterwards to regular anode substrates. In this paper, the preparation of the novel SOFC is shown and its morphology is illustrated with high resolution SEM pictures. Further, the performance in a standard SOFC test is demonstrated.     

Nanobeam electron diffraction and high resolution imaging analysis of InN films grown on sapphire

A JEOL JEM-3000F field emission, analytical, high-resolution transmission electron microscope (HRTEM) was used to study InN films grown on sapphire substrates. It was found that, while the InN films maintained the hexagonal (wurtzite) structure, InN nanodomains with a cubic (zincblende) structure were also formed in the films. Nanobeam electron diffraction techniques were applied for identification of the cubic phase. The identification of the cubic InN was confirmed by HRTEM structural imaging. The cubic InN nanodomains are 3-10 nm in diameter, and are orientated in two different orientations with their [110](cubic) and [110](cubic) axes parallel to each other and their (111)(cubic) planes parallel to the (0001)(hex) plane of the hexagonal InN.     

Overcoming challenges in the study of nitrided microalloyed steels using atom probe

Nitrided steels are widely used in the engineering field due to their superior hardness and other attractive properties. Atom probe tomography (APT) was employed to study two Nb-microalloyed CASTRIP steels with different N contents. A major challenge of using APT to study this group of materials is the presence of tails after Fe peaks in the mass spectra, which overestimates the composition for alloying elements such as Nb and Cu in the steels. One important factor that contributes to the tails is believed to be delayed field evaporation from Fe²⁺. This artefact of the mass spectrum was observed to be the most severe when voltage pulsing was used. The application of laser pulses with energy ranging from 0.2 to 1.2 nJ successfully reduced the tails and lead to better compositional measurement accuracy. Spatial resolution in the z-direction (along the tip direction) was observed to be less affected by changing laser energy but deteriorates in x-y direction with increasing laser energy. This investigation suggests that pulsed-laser atom probe with ∼0.4 nJ laser energy can be used to study this group of materials with improved mass resolution while still maintaining high spatial resolution.     

Measuring learning styles with questionnaires versus direct observation of preferential choice behavior in authentic learning situations: the visualizer/verbalizer behavior observation scale (VV-BOS)

Research on learning styles and their assessment has been the focus of growing interest due to rapid advances in educational multimedia applications. As an alternative to conventional questionnaires, the VV-BOS, a computer-based instrument for direct observation of students' preference for visual or verbal learning material in an authentic learning situation, was developed. A study with 103 second language learners was conducted to assess the reliability and validity of the scale scores provided by this instrument. The visualizer/verbalizer scale scores were highly reliable. They correlated moderately with corresponding VVQ and ELSIE questionnaire scale scores. Students' learning outcome could successfully be predicted using the VV-BOS scale, but not using the questionnaire scales. The results indicate that the direct observation of students' preferential choice behavior is a promising alternative to conventional questionnaires for the assessment of individual differences in multimedia training and instruction.