Lignin from Annual Plants as Raw Material Source for Flavors and Basic Chemicals

The enzymatic conversion of lignins, possibly in combination with electrochemical oxidation, makes aromatics such as syringol, guaiacol, vanillin and catechol available in the qualities required by the fragrance industry. The lignins were obtained by soda digestion from wheat straw and Miscanthus, characterized and then converted with laccases. The overall yield amounted up to 9 wt % with a product spectrum confined to four substances. Catechol was the major product, with a fraction of ≈75 %. It can easily be isolated by extraction with acetone.     

Contribution of the Internal and External Oxygen to the Oxidation of Microencapsulated Fish Oil

Microencapsulation aims to protect polyunsaturated fatty acids against oxidation by embedding oil droplets in a solid matrix. In such a system the internal (dissolved and entrapped) and external (in the environment) oxygen can be differentiated. The study aims to quantify the impact of both oxygen sources on the oxidation of microencapsulated fish oil. The impact of the solubilized oxygen in bulk fish oil is investigated by saturating the oil with nitrogen, synthetic air, and pure oxygen. Even though more dissolved oxygen results in more oxidation products, the difference between the oxidation of the nitrogen and air saturated oil is significant but low. For encapsulated fish oil powders, the internal oxygen is modified by preparing oil‐in‐water emulsions under atmospheric and inert conditions. The feed is atomized and spray dried with either nitrogen or air. Powders are stored under vacuum and in vials and the hydroperoxides and anisidine value are determined in the total‐ and encapsulated oil. The internal oxygen has a minor impact, whereas the external oxygen is the main determinant for autoxidation. Apart from oxidizing the non‐encapsulated oil, the external O₂ penetrates into the particle and reacts with the encapsulated oil. Practical Applications: Comparing the contribution of the internal and external oxygen to the oxidative stability shows that the internal O₂ plays a minor role and can be neglected. This means that the emulsion preparation as well as the spray drying process can be conducted under ambient conditions. An inert production is not extending the shelf life significantly as long as the external O₂ determines oxidation. The focus should be on optimizing the diffusion barrier properties of the wall matrix to reduce the penetration of the external oxygen into the particle system. Alternatively, packaging solution reducing the external O₂ will extend the shelf life of the microencapsulated oil.     

A PROTOTYPE GRID FRAMEWORK FOR THE CHEMICAL PROCESS INDUSTRIES

This article presents a GRID framework for distributed computations in the chemical process industries. We advocate a generic agent-based GRID environment in which chemical processes can be represented, simulated, and optimized as a set of autonomous, collaborative software agents. The framework features numerous advantages in terms of scalability, software reuse, security, and distributed resource discovery and utilization. It is a novel example of how advanced distributed techniques and paradigms can be elegantly applied in the area of chemical engineering to support distributed computations and discovery functions in chemical process engineering. A prototype implementation of the proposed framework for chemical process design is presented to illustrate the concepts.     

Trams-a risk factor for pedestrians

In Gothenburg tram injuries were identified to be an important cause of traffic injuries and fatalities (48%) among pedestrians. During the summer middle-aged men, often under the influence of alcohol, were often severely injured and the injury rate was also high during the autumn. A majority (60%) of those fatally injured were under the influence of alcohol. Most injury events happened at or near a tram stop. The most serious injuries arose when the victim landed under a tram. In 1992, a runaway tram caused a major disaster, killing 10 pedestrians and injuring 30. The injury reducing measures the tram company has now started to introduce include safety railings at tram stops, side barriers on the tramcars to prevent people from falling under the tram and lower speeds near tram stops.     

Acceptability of genetically modified cheese presented as real product alternative

European consumers, in general, have negative attitudes towards the use of gene technology in food production. The objective of this study was to examine whether taste and health benefits influence the acceptability of genetically modified (gm) products when they are presented as real product alternatives. Consumers in Denmark, Finland, Norway and Sweden (n=738) assessed two cheeses: one was labelled as genetically modified (preferred in an earlier product test) and the other as conventional (neutral in an earlier product test). A smaller control group received two cheeses with blind codes. Labelling decreased consumers' intentions to buy the originally preferred gm-labelled cheese, but still the intentions were at the same level with the conventionally labelled option. Participants chose two gm cheeses out of five possible when given the option to take cheese home after tasting. Intentions to buy gm cheese could best be explained by respondents' attitudes towards gene technology and perceived taste benefits. General health interest was also a reinforcer of intentions for gm cheese with reduced fat content.     

Coherent lightwave transmission at 2 Gbit/s over 170 km of optical fibre using phase modulation

We report coherent lightwave transmission at a data rate of 2Gbit/s over 170 km of optical fibre. Phase modulation is employed, and a bit error rate lower than 10-9 is achieved. The receiver sensitivity of ?39.0 dBm 10-9 BER) is an improvement of 2.4 dB over the best previously published direct-detection result for non-return-to-zero transmission.     

Effect of Carbon Content on Variant Pairing in Bainitic Low Alloy Steel

Metallurgical and Materials Transactions A - Variant pairing in bainite was evaluated in four different commercial low alloy steels with medium to high carbon content. The steels investigated were...     

项目计划内在稳健性与其影响因素关系分析

针对资源约束项目计划的内在稳健性受多种因素影响的问题,本研究采用16种优先规则,对Kolisch的j30算例集中的480个算例分别制定项目计划,计算出各项目计划的最少关键序列总数、资源使用效率及项目计划工期比项目最短工期长出的百分比L,并通过仿真得到各项目计划的内在稳健性值;同时应用多元统计方法,建立项目计划内在稳健性与各影响因素之间的回归方程。统计检验结果表明,回归方程是显著有效的,最少关键序列数、资源使用效率与内在稳健性呈负相关,项目计划的工期比项目的最短工期长出的百分比L与内在稳健性呈正相关;交叉项检验结果表明,关键序列较多时,L的增大可以有效地提高项目计划的稳健性,这与实际状况一致。该研究可为具有稳健性项目计划的制定、预测和控制提供决策依据。