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排序方式: 共有154条查询结果,搜索用时 262 毫秒
1.
Alena Yarysheva Dmitry Strel'tsov Sergey Malakhov Olga Arzhakova Larisa Yarysheva Alexandr Volynskii 《Polymer International》2020,69(7):627-634
This work addresses the phenomenon of the development of a patterned surface relief on polymer films via different modes of environmental crazing. Commercial films of semicrystalline poly(tetrafluoroethylene) (PTFE) and amorphous glassy poly(ethylene terephthalate) (PET) were subjected to tensile drawing in the presence of physically active liquid environments (carbon tetrachloride or aliphatic alcohols). The structure parameters and wettability of the modified films were studied by AFM, SEM, profilometer measurements and contact angle measurements. Environmental intercrystallite crazing of PTFE is accompanied by the development of an unstable structure with a high free surface, which experiences marked strain recovery upon unloading. As a result of the relief formation, PTFE hydrophobicity is enhanced (the water contact angle increases by 25°). Classical environmental crazing of PET films is accompanied by the formation of an anisotropic surface relief which is an assembly of crazes oriented perpendicular to the direction of tensile drawing, thus leading to the phenomenon of anisotropic wetting. The proposed approach for structural surface modification makes it possible to use the advantages of surface instability and spontaneous self‐organization of the polymer towards the development of a unique surface microrelief. © 2020 Society of Chemical Industry 相似文献
2.
Pavel P. Fedorov Vera Y. Proydakova Sergey V. Kuznetsov Valery V. Voronov Alexandr A. Pynenkov Konstantin N. Nishchev 《Journal of the American Ceramic Society》2020,103(5):3390-3400
The thermal analysis and X-ray powder diffraction studies of the Li2SO4–Na2SO4 system, including the high-temperature X-ray diffraction technique, have elucidated four phases of variable composition: three solid solutions based on the α-Li2SO4, α-Na2SO4, and α-LiNaSO4 high-temperature polymorphs, and a low-temperature β-LiNaSO4 phase. α-Na2SO4-Base solid solution disintegrates into two phases via a monotectoid phase transformation. It is quite probable that the monotectoid process is related to the conversion of the second-order phase transition to the first-order phase transition. 相似文献
3.
Alexandr Valentinovich Vinogradov Vladimir Valentinovich Vinogradov 《Journal of the American Ceramic Society》2014,97(1):290-294
Nowadays, it is a great challenge to synthesize crystalline TiO2 nanostructures using low‐temperature methods without annealing stage. Such an approach allows to perform functional and structural modification in the formed crystalline phase by thermally unstable compounds, such as biomaterials, MOFs, dye sets in situ, which was previously considered impossible. In this work, we have developed and analyzed the effect of acidic peptization on formation of highly photoactive titania crystallites in an aqueous solution using titanium tetraisopropylate as a precursor. Acids with different dissociation degrees in water were used as peptizing mediators to determine the effect of protonation on sol formation. The dip‐coating films were obtained with consequent drying of the sols via evaporation of the solvent. The as‐prepared catalysts were characterized by X‐ray diffraction, AFM microscopy, UV–V is spectroscopy, Brunauer–Emmett–Teller surface area. The aggregate size of TiO2 in the colloidal suspension solution was measured by dynamic light scattering. Photocatalytic activity of films was studied by decomposition of Rhodamine B dye. It is found that the size of colloids in an aqueous solution is proportional to the protonation degree of the surface of particles and does not depend on the [Ti4+]/[H+] ratio, and peptization under weakly acidic conditions leads to anisotropic rod‐like nanoparticles. The highest photocatalytic activity was exhibited by the TiO2–HCl‐based coatings, ~3.5 times higher than that of the Acet.‐prepared sample. 相似文献
4.
Wenhao Xu Murong Wen Jingbo Yu Qihong Zhang Nikolay E. Polyakov Alexandr V. Dushkin 《Drug development and industrial pharmacy》2013,39(12):1924-1932
AbstractIn this study, complexes of kaempferol (KF) with polysaccharide arabinogalactan (AG) and disodium glycyrrhizinate (Na2GA) were prepared through mechanochemical technique to improve the solubility and bioavailability of KF. The physicochemical properties and the interactions of KF with AG/Na2GA were investigated through dissolution, SEM, XRD, and DSC studies. The reduction of particle sizes and destruction of crystal forms revealed the formation of solid dispersion which may have assisted the dissolution of the drug. The accelerated stability study showed higher stability for KF–Na2GA complex. In vivo pharmacokinetic study was performed to observe the plasma drug concentrations for KF complexes. Mechanochemical complexation of KF with AG/Na2GA improved the pharmacological activity as evident by the inhibitory potential of the complexes towards carbohydrate metabolic enzymes. In vivo studies were performed in STZ-induced diabetic mice, where the group treated with KF–AG complex showed better liver and kidney function and lower blood glucose levels than pure KF. Therefore, mechanochemical complexes of KF with polysaccharide or glycyrrhizate may serve as a promising formulation for the treatment of diabetes. 相似文献
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Oleg N. Grigoriev Boris A. Galanov Vladimir A. Lavrenko Alla D. Panasyuk Sergey M. Ivanov Alexandr V. Koroteev Klaus G. Nickel 《Journal of the European Ceramic Society》2010,30(11):2397-2405
The oxidation of ZrB2–SiC and ZrB2–SiC–ZrSi2 ceramics of different composition has been studied experimentally at 1500 °C in pure oxygen for up to 50 h. ZrB2–SiC–ZrSi2 ceramics proved to be the most oxidation-resistant at ZrSi2 contents of less then 4 wt%. These ceramics were more oxidation-resistant than ZrB2–SiC ceramics. An analytical model of growth kinetics for a multilayered scale based on an oxidation–diffusion balance was developed and tested. 相似文献
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Petr Jákl Mojmír Šerý Jan Ježek Alexandr Jonáš Miroslav Liška Pavel Zemánek 《Journal of Modern Optics》2013,60(10):1615-1625
Abstract The way in which reflection of the trapping beam from a dielectric interface influences the distance of the trapped sphere from the beam waist is studied theoretically and experimentally. The reflected wave interferes with the incident wave and they create a standing-wave component in the total axial intensity distribution. This component then modulates the trapping potential and creates several possible equilibrium positions for the trapped sphere. When the beam waist approaches the surface, the potential profile changes, which consequently causes jumps of the trapped probe from its current location to a deeper potential well. We suggested theoretically and proved experimentally that the magnitude of these unwanted jumps between the neighbouring equilibrium positions can be decreased by a suitable size of the sphere. 相似文献
10.
Changes in the composition of hop secondary metabolites induced by high hydrostatic pressure 下载免费PDF全文
Karel Krofta Milan Houška Alexandr Mikyška Pavel Čermák 《Journal of the Institute of Brewing》2018,124(2):158-172
Hops contain large amounts of secondary metabolites, many of which have notable bioactive and sensory characteristics. Many of these properties are affected by the processing of raw hops into products. We studied the influence of high‐pressure processing (HPP) on the content and composition of secondary metabolites in hop homogenates prepared from fresh green cones of several Czech hop varieties. Homogenates contained more hop oils (27% on average) compared to dried hops. The composition of essential oils in homogenates after HPP showed a decrease in fatty acid methyl and thioesters fractions (80 and 100% respectively). Conversely, the number of other bioactive compounds from the group of resins and prenylflavonoids that remained in HPP homogenates was retained to a greater extent than in the dried hops. Low temperatures and an oxygen‐free atmosphere were effective conditions for the preservation of raw hops and hop products. Copyright © 2018 The Institute of Brewing & Distilling 相似文献