Bioleaching of pyrrhotite by Sulfobacillus thermosulfidooxidans

The bioleaching of pyrrhotite was investigated using Sulfobacillus thermosulfidooxidans.The effects of pH,pulp concentration,inoculation amount,external addition of ferrous and ferric ions were examined.The pH is found to exert a profound effect on the leaching process for controlling the bacterial activity and precipitation of ferric ions mainly as jarosite.The results show that low pulp content increases the leaching rate of iron.The inoculation amount from 1×107 cell/mL to 1×108 cell/mL has positive effects on the leaching rate.The results also imply that addition of ferrous sulfate（1 g/L） is required for the bacteria to efficiently drive the extraction of iron,however,the leaching efficiency has no obvious enhancement when 2 g/L ferrous sulfate was added.Comparatively,addition of ferric sulfate（2 g/L） significantly inhibits the bioleaching process.At the end of bioleaching,jarosite and sulfur are observed on the surface of pyrrhotite residues by using XRD and SEM.With the passivation film formed by jarosite and sulfur,the continuous iron extraction is effectively blocked.     

Formation of passivation film during pyrrhotite bioleached by pure L. ferriphilum and mixed culture of L. ferriphilum and A. caldus

Bioleaching and electrochemical experiments were conducted to evaluate pyrrhotite dissolution in the presence of pure L.ferriphilum and mixed culture of L. ferriphilum and A. caldus. The results indicate that the pyrrhotite oxidation behavior is the preferential dissolution of iron accompanied with the massive formation of sulfur in the presence of L. ferriphilum, which significantly hinders the leaching efficiency. Comparatively, the leaching rate of pyrrhotite distinctly increases by 68% in the mixed culture of L. ferriphilum and A. caldus at the 3rd day. But, the accumulated ferric ions and high p H value produced by bioleaching process can give rise to the rapid formation of jarosite, which is the primary passivation film blocking continuous iron extraction during bioleaching by the mixed culture. The addition of A. caldus during leaching by L. ferriphilum can accelerate the oxidation rate of pyrrhotite, but not change the electrochemical oxidation mechanisms of pyrrhotite. XRD and SEM/EDS analyses as well as electrochemical study confirm the above conclusions.     

某国外EPC工程总承包项目物流仓储管理

随着国内市场竞争日益激烈,越来越多的工程技术公司大力拓展国际市场,EPC(设计、采购和施工)成为大型工程公司国际工程承包的主要方式。其中,物流管理在EPC项目中扮演重要的角色,包括设备材料的采购、运输、入库、保管、出库,每个环节的顺利进行是项目按期保质完成的先决条件,而仓储管理是物流管理的一个关键环节,包括设备材料的入库、保管、出库。以某国外EPC工程总承包项目为例,阐述了仓储管理的重要性,并着重介绍总承包项目仓储管理实施方案。