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排序方式: 共有111条查询结果,搜索用时 31 毫秒
1.
Gang Yang Aaron Zimmerman Nicole C. Hurtig Svetoslav V. Georgiev Vineet Goswami Judith L. Hannah Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242
Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices. 相似文献
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Evaluating a process‐based model for use in streambank stabilization: insights on the Bank Stability and Toe Erosion Model (BSTEM) 下载免费PDF全文
Kate Klavon Garey Fox Lucie Guertault Eddy Langendoen Holly Enlow Ron Miller Anish Khanal 《地球表面变化过程与地形》2017,42(1):191-213
Streambank retreat is a complex cyclical process involving subaerial processes, fluvial erosion, seepage erosion, and geotechnical failures and is driven by several soil properties that themselves are temporally and spatially variable. Therefore, it can be extremely challenging to predict and model the erosion and consequent retreat of streambanks. However, modeling streambank retreat has many important applications, including the design and assessment of mitigation strategies for stream revitalization and stabilization. In order to highlight the current complexities of modeling streambank retreat and to suggest future research areas, this paper reviewed one of the most comprehensive streambank retreat models available, the Bank Stability and Toe Erosion Model (BSTEM), which has recently been integrated with several popular hydrodynamic and sediment transport models including the Hydrologic Engineering Center's River Analysis System (HEC‐RAS). The objectives of this paper were to: (i) comprehensively review studies that have utilized BSTEM and report their findings, (ii) address the limitations of the model so that it can be applied appropriately in its current form, and (iii) suggest directions of research that will help make the model a more useful tool in future applications. The paper includes an extensive overview of peer reviewed studies to guide future users of BSTEM. The review demonstrated that the model needs further testing and evaluation outside of the central United States. Also, further development is needed in terms of accounting for spatial and temporal variability in geotechnical and fluvial erodibility parameters, incorporating subaerial processes, and accounting for the influence of riparian vegetation on streambank pore‐water pressure dynamics, applied shear stress, and erodibility parameters. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
5.
Amy E. Draut Patrick E. Hart Thomas D. Lorenson Holly F. Ryan Florence L. Wong Ray W. Sliter James E. Conrad 《Marine Geophysical Researches》2009,30(3):193-206
Small, steep, uplifting coastal watersheds are prolific sediment producers that contribute significantly to the global marine
sediment budget. This study illustrates how sedimentation evolves in one such system where the continental shelf is largely
sediment-starved, with most terrestrial sediment bypassing the shelf in favor of deposition in deeper basins. The Santa Barbara–Ventura
coast of southern California, USA, is considered a classic area for the study of active tectonics and of Tertiary and Quaternary
climatic evolution, interpretations of which depend upon an understanding of sedimentation patterns. High-resolution seismic-reflection
data over >570 km2 of this shelf show that sediment production is concentrated in a few drainage basins, with the Ventura and Santa Clara River
deltas containing most of the upper Pleistocene to Holocene sediment on the shelf. Away from those deltas, the major factor
controlling shelf sedimentation is the interaction of wave energy with coastline geometry. Depocenters containing sediment
5–20 m thick exist opposite broad coastal embayments, whereas relict material (bedrock below a regional unconformity) is exposed
at the sea floor in areas of the shelf opposite coastal headlands. Locally, natural hydrocarbon seeps interact with sediment
deposition either to produce elevated tar-and-sediment mounds or as gas plumes that hinder sediment settling. As much as 80%
of fluvial sediment delivered by the Ventura and Santa Clara Rivers is transported off the shelf (some into the Santa Barbara
Basin and some into the Santa Monica Basin via Hueneme Canyon), leaving a shelf with relatively little recent sediment accumulation.
Understanding factors that control large-scale sediment dispersal along a rapidly uplifting coast that produces substantial
quantities of sediment has implications for interpreting the ancient stratigraphic record of active and transform continental
margins, and for inferring the distribution of hydrocarbon resources in relict shelf deposits. 相似文献
6.
Andreas G. Mueller Gregory C. Hall Alexander A. Nemchin Holly J. Stein Robert A. Creaser Douglas R. Mason 《Mineralium Deposita》2008,43(3):337-362
The Granny Smith (37 t Au production) and Wallaby deposits (38 t out of a 180 t Au resource) are located northeast of Kalgoorlie,
in 2.7 Ga greenstones of the Eastern Goldfields Province, the youngest orogenic belt of the Yilgarn craton, Western Australia.
At Granny Smith, a zoned monzodiorite–granodiorite stock, dated by a concordant titanite–zircon U–Pb age of 2,665 ± 3 Ma,
cuts across east-dipping thrust faults. The stock is fractured but not displaced and sets a minimum age for large-scale (1 km)
thrust faulting (D2), regional folding (D1), and dynamothermal metamorphism in the mining district. The local gold–pyrite
mineralization, controlled by fractured fault zones, is younger than 2,665 ± 3 Ma. In augite–hornblende monzodiorite, alteration
progressed from a hematite-stained alkali feldspar–quartz–calcite assemblage and quartz–molybdenite–pyrite veins to a late
reduced sericite–dolomite–albite assemblage. Gold-related monazite and xenotime define a U–Pb age of 2,660 ± 5 Ma, and molybdenite
from veins a Re–Os isochron age of 2,661 ± 6 Ma, indicating that mineralization took place shortly after the emplacement of
the main stock, perhaps coincident with the intrusion of late alkali granite dikes. At Wallaby, a NE-trending swarm of porphyry
dikes comprising augite monzonite, monzodiorite, and minor kersantite intrudes folded and thrust-faulted molasse. The conglomerate
and the dikes are overprinted by barren (<0.01 g/t Au) anhydrite-bearing epidote–actinolite–calcite skarn, forming a 600-m-wide
and >1,600-m-long replacement pipe, which is intruded by a younger ring dike of syenite porphyry pervasively altered to muscovite
+ calcite + pyrite. Skarn and syenite are cut by pink biotite–calcite veins, containing magnetite + pyrite and subeconomic
gold–silver mineralization (Au/Ag = 0.2). The veins are associated with red biotite–sericite–calcite–albite alteration in
adjacent monzonite dikes. Structural relations and the concordant titanite U–Pb age of the skarn constrain intrusion-related
mineralization to 2,662 ± 3 Ma. The main-stage gold–pyrite ore (Au/Ag >10) forms hematite-stained sericite–dolomite–albite
lodes in stacked D2 reverse faults, which offset skarn, syenite, and the biotite–calcite veins by up to 25 m. The molybdenite
Re–Os age (2,661 ± 10 Ma) of the ore suggests a genetic link to intrusive activity but is in apparent conflict with a monazite–xenotime
U–Pb age (2,651 ± 6 Ma), which differs from that of the skarn at the 95% confidence level. The time relationships at both
gold deposits are inconsistent with orogenic models invoking a principal role for metamorphic fluids released during the main
phase of compression in the fold belt. Instead, mineralization is related in space and time to late-orogenic, magnetite-series,
high-Mg monzodiorite–syenite intrusions of mantle origin, characterized by Mg/(Mg + FeTOTAL) = 0.31–0.57, high Cr (34–96 ppm), Ni (22–63 ppm), Ba (1,056–2,321 ppm), Sr (1,268–2,457 ppm), Th (15–36 ppm), and rare earth
elements (total REE: 343–523 ppm). At Wallaby, shared Ca–K–CO2 metasomatism and Th-REE enrichment (in allanite) link Au–Ag mineralization in biotite–calcite veins to the formation of the
giant epidote skarn, implicating a Th + REE-rich syenite pluton at depth as the source of the oxidized hydrothermal fluid.
At Granny Smith, lead isotope data and the Rb–Th–U signature of early hematite-bearing wall-rock alteration point to fluid
released by the source pluton of the differentiated alkali granite dikes. 相似文献
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Nathan S. Hall R. Wayne Litaker Elizabeth Fensin Jason E. Adolf Holly A. Bowers Allen R. Place Hans W. Paerl 《Estuaries and Coasts》2008,31(2):402-418
A dense bloom of the ichthyotoxic dinoflagellate Karlodinium veneficum was discovered in the Neuse River Estuary, North Carolina, on 19 October 2006 and was associated with four subsequent fish
kills. Microscopic, photopigment, DNA, and toxicological techniques confirmed bloom identity and toxicity. High-resolution
spatio-temporal data from ship-board and fixed automated sampling stations provided a unique opportunity to investigate the
environmental conditions that initiated, maintained, and terminated the K. veneficum bloom. Bloom initiation and growth were favored by high nutrient availability and reduced dispersal during the period of
declining riverine discharge after Tropical Storm Ernesto. K. veneficum out-competed other co-occurring dinoflagellates, perhaps because of the production of karlotoxins that are known to act as
grazing deterrents and to facilitate mixotrophic feeding. Once the bloom was established, small-scale hydrodynamic processes,
coupled with vertical migration, concentrated cells along a frontal convergence to high densities (>200,000 cells per milliliter).
By 26 October 2006, wind mixing and possible nutrient stress disrupted the bloom. Release of cell-bound toxins during the
bloom collapse likely accounted for the associated fish kill events where fish were reported as exhibiting typical symptoms
of karlotoxin poisoning. The dynamics of this bloom underscore the tight control of harmful algal blooms by meteorological
forcing, hydrology, and sediment nutrient input in this shallow lagoonal estuary. 相似文献
9.
Suburban growth is a complex process attributable partly to decentralization and partly to deconcentration. Data on source of migrants and population density are used to operationalize these concepts in an empirical study of the Cleveland, Ohio SMSA for the period 1950 to 1970. Statistical analysis of census tract data for the suburban ring reveals a piling up of densities at the inner edge and suggests a complex pattern with respect to sources of the migrants contributing to suburban growth. 相似文献
10.
Organic micropollutants in marine plastics debris from the open ocean and remote and urban beaches 总被引:2,自引:0,他引:2
Hirai H Takada H Ogata Y Yamashita R Mizukawa K Saha M Kwan C Moore C Gray H Laursen D Zettler ER Farrington JW Reddy CM Peacock EE Ward MW 《Marine pollution bulletin》2011,62(8):1683-1692
To understand the spatial variation in concentrations and compositions of organic micropollutants in marine plastic debris and their sources, we analyzed plastic fragments (∼10 mm) from the open ocean and from remote and urban beaches. Polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), dichloro-diphenyl-trichloroethane and its metabolites (DDTs), polybrominated diphenyl ethers (PBDEs), alkylphenols and bisphenol A were detected in the fragments at concentrations from 1 to 10,000 ng/g. Concentrations showed large piece-to-piece variability. Hydrophobic organic compounds such as PCBs and PAHs were sorbed from seawater to the plastic fragments. PCBs are most probably derived from legacy pollution. PAHs showed a petrogenic signature, suggesting the sorption of PAHs from oil slicks. Nonylphenol, bisphenol A, and PBDEs came mainly from additives and were detected at high concentrations in some fragments both from remote and urban beaches and the open ocean. 相似文献