Thallium diagenesis in lacustrine sediments

Dated sediment cores and porewaters from two Canadian Shield lakes, located 40 km from Québec City (L. Tantaré) and 25 km downwind from an important smelter in northwestern Québec (L. Vose), were analyzed for thallium and other geochemical variables. Atmospheric deposition is the only source of anthropogenic Tl to these lakes. The porewater Tl concentration profiles in L. Tantaré display a peak below the sediment-water interface that suggests post-depositional Tl remobilization and transport to the overlying water and deeper sediments; such a dissolved Tl peak occurs just above the sediment-water interface in L. Vose. Modeling the porewater Tl profiles with a diagenetic reaction-transport equation reveals a zone of dissolved Tl production lying above a zone of Tl consumption in L. Tantaré sediments. In contrast, in L. Vose, Tl diffuses across the sediment-water interface from the anoxic hypolimnion and is fixed to the surficial sediments. The localization of the consumption zones, the shape of the dissolved Tl, sulfide and iron profiles, as well as calculations of saturation states are all consistent with the removal of Tl from porewater by co-precipitation with and/or adsorption to Fe sulfides. The concentrations of Tl removed from or added to sediments after their deposition (i.e., diagenetic Tl) amount to up to 36% of measured sediment Tl concentrations. Comparison of the reconstructed historical Tl records with those of polycyclic aromatic hydrocarbons (PAHs) and of Pb originating from coal burning or from smelting activities indicate that coal combustion is the major source of atmospheric Tl to L. Tantaré and that an additional important Tl source to L. Vose is the nearby smelter.     

Impoverishment of recent floodplain forest mollusc fauna in the lower Ohře River (Czech Republic) as a result of prehistoric human impact

Analyses of fossil mollusc successions have rarely been used to study the development of floodplain forests during the Holocene. The Oh?e River, located in a prehistorically settled chernozem area in the Czech Republic, is partly situated in Cretaceous marlstones, yielding sediments suitable for fossilization directly in floodplain deposits. We analysed five fossil mollusc successions situated in the lower stretch of the Oh?e River and compared the results with recent mollusc assemblages studied along the entire 256 km of the river. Fossil samples were composed mostly of open‐country species throughout the Holocene or the whole preserved succession. Only some samples also contained woodland assemblages, but these were always greatly impoverished, with a very low frequency of strictly woodland species. Although the natural‐looking appearance of the present‐day floodplain forests of the lower river stretch has resulted in its being declared a nature reserve, modern floodplain forest mollusc assemblages there are also impoverished. This reduction in the distribution of strictly woodland species compared with modern assemblages in the upper stretch of the river seems to be the result of an ancient human settlement and continuous disturbances of the floodplain forest development since the Neolithic. Thus, fully developed floodplain forest assemblages occur recently only in the upper non‐impacted stretch of the river. Based on the studied fossil successions we can conclude that the lower Oh?e River floodplain was probably a mosaic of open and disturbed forest habitats throughout the Holocene. This area is part of a central European landscape island, where forests probably never fully developed and open patches from the early Holocene continually developed into an agricultural landscape.     

Temperature and precipitation trends in Canada during the 20th century

Abstract

Trends in Canadian temperature and precipitation during the 20th century are analyzed using recently updated and adjusted station data. Six elements, maximum, minimum and mean temperatures along with diurnal temperature range (DTR), precipitation totals and ratio of snowfall to total precipitation are investigated. Anomalies from the 1961–1990 reference period were first obtained at individual stations, and were then used to generate gridded datasets for subsequent trend analyses. Trends were computed for 1900–1998 for southern Canada (south of 60°N), and separately for 1950–1998 for the entire country, due to insufficient data in the high arctic prior to the 1950s.

From 1900–1998, the annual mean temperature has increased between 0.5 and 1.5°C in the south. The warming is greater in minimum temperature than in maximum temperature in the first half of the century, resulting in a decrease of DTR. The greatest warming occurred in the west, with statistically significant increases mostly seen during spring and summer periods. Annual precipitation has also increased from 5% to 35% in southern Canada over the same period. In general, the ratio of snowfall to total precipitation has been increasing due mostly to the increase in winter precipitation which generally falls as snow and an increase of ratio in autumn. Negative trends were identified in some southern regions during spring. From 1950–1998, the pattern of temperature change is distinct: warming in the south and west and cooling in the northeast, with similar magnitudes in both maximum and minimum temperatures. This pattern is mostly evident in winter and spring. Across Canada, precipitation has increased by 5% to 35%, with significant negative trends found in southern regions during winter. Overall, the ratio of snowfall to total precipitation has increased, with significant negative trends occurring mostly in southern Canada during spring.

Indices of abnormal climate conditions are also examined. These indices were defined as areas of Canada for 1950–1998, or southern Canada for 1900–1998, with temperature or precipitation anomalies above the 66th or below the 34th percentiles in their relevant time series. These confirmed the above findings and showed that climate has been becoming gradually wetter and warmer in southern Canada throughout the entire century, and in all of Canada during the latter half of the century.     

On the Integrability of Limited-Area Numerical Weather Prediction Model ALADIN over Extended Time Periods

This note summarizes results of the first integration of regional numerical weather prediction model ALADIN in a climate mode. The ALADIN model, developed in an international cooperation led by Météo France, is operationally used for weather prediction. The grid step of the model is 12 km; the integration domain covers a major part of Europe. A one-month-long run has been performed with this model on observed boundary conditions (represented by assimilations by the global model ARPEGE). It is demonstrated that no excessive error is generated and accumulated in the model during the integration; hence the model is integrable for extended time periods and may serve a basis for a development towards a regional climate model.     

A GCM Simulation of Heat Waves, Dry Spells, and Their Relationships to Circulation

Heat waves and dry spells are analyzed (i) at eightstations in south Moravia (Czech Republic), (ii) inthe control ECHAM3 GCM run at the gridpoint closest tothe study area, and (iii) in the ECHAM3 GCM run fordoubled CO₂ concentrations (scenario A) at thesame gridpoint (heat waves only). The GCM outputs arevalidated both against individual station data andareally representative values. In the control run, theheat waves are too long, appear later in the year,peak at higher temperatures and their numbers areunder- (over-) estimated in June and July (in August).The simulated dry spells are too long, and the annualcycle of their occurrence is distorted.Mid-tropospheric circulation, and heat waves and dryspells are linked much less tightly in the controlclimate than in the observed. Since mid-troposphericcirculation is simulated fairly successfully, wesuggest the hypothesis that either the air-masstransformation and local processes are too strong inthe model or the simulated advection is too weak. Inthe scenario A climate, the heat waves become a commonphenomenon: warming of 4.5 °C in summer(difference between scenario A and control climates)induces a five-fold increase in the frequency oftropical days and an immense enhancement of extremityof heat waves. The results of the study underline theneed for (i) a proper validation of the GCM outputbefore a climate impact study is conducted and (ii)translation of large-scale information from GCMs intolocal scales using downscaling and stochasticmodelling techniques in order to reduce GCMs' biases.     

An Overview of the Second Generation Adjusted Daily Precipitation Dataset for Trend Analysis in Canada

A second generation adjusted precipitation daily dataset has been prepared for trend analysis in Canada. Daily rainfall and snowfall amounts have been adjusted for 464 stations for known measurement issues such as wind undercatch, evaporation and wetting losses for each type of rain-gauge, snow water equivalent from ruler measurements, trace observations and accumulated amounts from several days. Observations from nearby stations were sometimes combined to create time series that are longer; hence, making them more useful for trend studies. In this new version, daily adjustments are an improvement over the previous version because they are derived from an extended dataset and enhanced metadata knowledge. Datasets were updated to cover recent years, including 2009. The impact of the adjustments on rainfall and snowfall total amounts and trends was examined in detail. As a result of adjustments, total rainfall amounts have increased by 5 to 10% in southern Canada and by more than 20% in the Canadian Arctic, compared to the original observations, while the effect of the adjustments on snowfall were larger and more variable throughout the country. The slope of the rain trend lines decreased as a result of the larger correction applied to the older rain-gauges while the slope of the snow trend lines increased, mainly along the west coast and in the Arctic. Finally, annual and seasonal rainfall and snowfall trends based on the adjusted series were computed for 1950–2009 and 1900–2009. Overall, rainfall has increased across the country while a mix of non-significant increasing and decreasing trends was found during the summer in the Canadian Prairies. Snowfall has increased mainly in the north while a significant decrease was observed in the southwestern part of the country for 1950–2009.

     

Did humans and natural forests coexist in close proximity? A case study of the Lateglacial and Holocene Mollusca in the Moravian Karst,Czech Republic

Prehistoric settlements are usually perceived as being in opposition to the natural development of the landscape. Indeed, for woodland snail assemblages in anthropogenic landscapes in central Europe, considerable impoverishment is typical. However, it remains unclear whether this has been caused by humans only or also by climate effects. From an archaeological point of view, the Moravian Karst is one of the classic prehistorical locations in central Europe, but with a more humid climate than the previously studied anthropogenic areas. To learn more about coexistence of humans and natural forests during the Lateglacial and Holocene, we analysed 11 mollusc successions covering this entire area, a unique data set for such a relatively small area. These mollusc successions show several specific features compared to the standard development known from other mid‐European areas. One is that although the Moravian Karst is not far from the Western Carpathians, Carpathian species appeared relatively late, only during the second half of the Holocene climatic optimum. Similarly, some western European and Alpine elements appeared later than expected. In contrast to this, however, a number of forest species with central European range appeared relatively early during the Lateglacial or Early Holocene. Two even survived the Last Glacial Maximum in the Moravian Karst. This would suggest an early occurrence of forest patches in a mosaic landscape. Humans have apparently inhabited this area since the Lateglacial amongst islands of forests, which later changed during the Boreal and then the climatic optimum into humid canopy forests. Thus, a mosaic of anthropogenic and natural habitats persisting in close vicinity was possible in rugged and humid landscapes practically until the Industrial Revolution.