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1.
Jeffrey Chiarenzelli Robin Lock Carol Cady Adria Bregani Benn Whitney 《Environmental Earth Sciences》2012,67(1):189-204
Water from four north-flowing rivers (Oswegatchie, Grasse, Raquette, and West Branch of the St. Regis) traversing three distinct geologic terranes (Adirondack Highlands, Adirondack Lowlands, St. Lawrence Valley), originating in the acidified northern Adirondack region, display rapid spatial changes in downriver multi-element chemistry and physical parameters. Downriver, most soluble elements increase (Ba, Ca, Cu, K, Mg, Na, Rb, S, and Sr) while statistically significant decreases in insoluble elements (Al, Ce, Dy, Er, Fe, Gd, La, Mn, Nd, Pr, and Y) also occur. Lithium, Si, and Zr did not show a consistent increasing or decreasing trend. Concentrations of most elements measured on June 5, 2008 were greater than 7?weeks later; however, greater discharge and lower pH enhanced Al concentrations occurred during the later sampling date. Elemental ratios track changes in lithology, anthropogenic influence, and pH. The Raquette River shows the least variation in elemental concentrations because of storage in numerous hydropower reservoirs and has non-detectable concentrations of some redox sensitive elements such as Co, Ni, and V. Oswegatchie tributaries display similar geochemical trends dependent upon their location and local bedrock and show geochemical trends along the trunks of major rivers that are also evident in smaller drainage basins. Comparison with analytical results from the Western Adirondack Stream Survey also indicates acidification is prevalent in the Adirondack Highlands, particularly in the Oswegatchie headwaters during periods of high flow, but acidity is rapidly buffered downriver due to interaction with marble in the Adirondack Lowlands. 相似文献
2.
The >1800 km long Coast Mountains–North Cascades orogen of the Canadian Cordillera and north-western US developed as a continental magmatic arc. Metamorphic rocks in the orogen contain widespread evidence for burial of supracrustal rocks to depths of c. 40 km, followed by nearly isothermal decompression to depths of <10 km. Near many shallowly-emplaced, mid-Cretaceous plutons, low-pressure contact metamorphic effects were overprinted by high-pressure regional metamorphic minerals and textures, as evidenced by kyanite±staurolite pseudomorphs after andalusite in metapelitic rocks. Therefore, near-pluton rocks record the loading history of the orogen. Metapelitic rocks not associated with plutons only preserve evidence for high-pressure conditions and/or high-temperature decompression, as indicated, for example, by sillimanite and cordierite after kyanite and garnet, respectively. Petrological evidence for burial and decompression is therefore recorded in different rocks. Various regions of the orogen differ in timing of metamorphism, the overall shape of P–T paths and the relative timing and regional extent of the high-pressure event, but most of these data and observations are consistent with thrusting and/or pure shear thickening as primary loading mechanisms throughout the orogen, as opposed to magma-dominated loading. This interpretation is further supported by comparison with thermal models, which demonstrate that the P–T paths are consistent with simultaneous thrusting and folding at a high initial geothermal gradient (35–40 °C km?1) in much of the orogen. A high geothermal gradient supports tectonic models invoking intra-arc contraction and suggests that magmatism played an important role in regional temperature-time paths. This tectonic-thermal history may be typical of other contractional orogens and illustrates the importance of large vertical displacement of crust in magmatic arcs. 相似文献
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R. T. Schilizzi W. Aldrich B. Anderson A. Bos R. M. Campbell J. Canaris R. Cappallo J. L. Casse A. Cattani J. Goodman H. J. van Langevelde A. Maccafferri R. Millenaar R. G. Noble F. Olnon S. M. Parsley C. Phillips S. V. Pogrebenko D. Smythe A. Szomoru H. Verkouter A. R. Whitney 《Experimental Astronomy》2001,12(1):49-67
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Quartz‐rich veins in metapelitic schists of the Sanandaj‐Sirjan belt, Hamadan region, Iran, commonly contain two Al2SiO5 polymorphs, and, more rarely, three coexisting Al2SiO5 polymorphs. In most andalusite and sillimanite schists, the types of polymorphs in veins correlate with Al2SiO5 polymorph(s) in the host rocks, although vein polymorphs are texturally and compositionally distinct from those in adjacent host rocks; e.g. vein andalusite is enriched in Fe2O3 relative to host rock andalusite. Low‐grade rocks contain andalusite + quartz veins, medium‐grade rocks contain andalusite + sillimanite + quartz ± plagioclase veins, and high‐grade rocks contain sillimanite + quartz + plagioclase veins/leucosomes. Although most andalusite and sillimanite‐bearing veins occur in host rocks that also contain Al2SiO5, kyanite‐quartz veins crosscut rocks that lack Al2SiO5 (e.g. staurolite schist, granite). A quartz vein containing andalusite + kyanite + sillimanite + staurolite + muscovite occurs in andalusite–sillimanite host rocks. Textural relationships in this vein indicate the crystallization sequence andalusite to kyanite to sillimanite. This crystallization sequence conflicts with the observation that kyanite‐quartz veins post‐date andalusite–sillimanite veins and at least one intrusive phase of a granite that produced a low‐pressure–high‐temperature contact aureole; these relationships imply a sequence of andalusite to sillimanite to kyanite. Varying crystallization sequences for rocks in a largely coherent metamorphic belt can be explained by P–T paths of different rocks passing near (slightly above, slightly below) the Al2SiO5 triple point, and by overprinting of multiple metamorphic events in a terrane that evolved from a continental arc to a collisional orogen. 相似文献
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Christopher Packham Keith L. Thompson Almudena Zurita Johan H. Knapen Ian Smail Robert Greimel Daniel F. M. Folha Chris Benn rew Humphrey Rene Rutten David Ciardi Matthieu Bec Richard Bingham Simon Craig Kevin Dee Derek Ives Paul Jolley Peter Moore Marti Pi i Puig Simon Rees Gordon Talbot Sue Worswick 《Monthly notices of the Royal Astronomical Society》2003,345(2):395-405
10.
The lowest addition of mercury (0.1 ug Hg 1−1) was used in CEEs for research on mercury flux, speciation and budget. The removal behavior of mercury by phytoplankton in
water columns of CEEs can be described by first order kinetic equations for total and particulate mercury in the CEE spiked
by mercury. The removal rate of mercury in water columns depends on the size and productivity of phytoplanton in a water column
to which mercuric ions were added. A 4.4 day half-life time and a 2.8 day half-life time for total and particulate mercury
respectively was obtained in diatom bloom. During microflagellate bloom a 30 day total mercury half-life time was estimated
with increase of particulate mercury in the water column. The 0.010 ug Hg cm−2y−1 mercury flux rate that was attained in the control bag agreed with the values from field measurements in Saanich Inlet where
the bags were launched.
The proportion of total mercury to dissolved and particulate mercury depended also on the size, productivity, and concentration
of mercury in a water column. A more or less constant distribution of mercury species in the control bag was observed as follows:
dissolved Hg 0.73, particulate Hg 0.27, inorganic Hg 0.42, dissolved organic Hg 0.31. After spiking with mercury, the particulate
mercury rose rapidly and reached to over 70% of the total mercury.
The concentration factor of mercury by phytoplankton in the CEEs in the order of 105 was consistent with the results from field measurements in Saanich Inlet.
The mercury recovery from the water column, sediment, water with sediment, and the CEE bag walls was only 52.3% of total mercury
spiked in the CEE. The losses of mercury by vaporization into the ambient air and diffusion through the wall of the enclosure
should be considered.
This paper was published in Chinese inOcean. Limn. Sinica,17(4):307–317, 1986. 相似文献