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1.
John T. Wilson James C. Mills IV Barbara H. Wilson Mark L. Ferrey David L. Freedman Dora Taggart 《Ground Water Monitoring & Remediation》2019,39(2):53-63
Monitored natural attenuation (MNA) is commonly used as a remedy for trichloroethene (TCE) in anaerobic groundwater; however, MNA has not been applied to TCE contamination in aerobic groundwater. Under aerobic conditions, bacteria initiate the degradation of many organic substances with oxygenase enzymes. Several of these enzymes are known to degrade TCE through a fortuitous reaction known as cometabolism. There are commercially available qPCR assays that can determine the number of gene copies of these enzymes. If the qPCR assay could be used to predict the first-order rate constant for cometabolism of TCE, the qPCR assay could be used to screen sites to determine whether MNA was a plausible remedy for TCE contamination. This study reevaluated data from water samples that were collected from 19 wells on five sites in Minnesota, New York, and Utah. Data had previously been published on the rate constant for cometabolism of TCE in the water samples as determined by a 14C-assay and the abundance of gene copies for five enzymes that cometabolize TCE as determined using a qPCR assay. The Michaelis-Menten (Haldane) kinetic parameters for cometabolism of TCE and the abundance of DNA for the five oxygenase enzymes were used to predict the rate constant for cometabolism of TCE. The predicted rate constants were evaluated and validated by comparing them to the rate constants derived from the 14C-assay. For predicted rate constants greater than 0.003 per year, the predicted rate constants agreed with the measured rate constants within a factor of three. The qPCR assay serves as a convenient screening tool to determine whether MNA is a plausible remedy for an aerobic plume of TCE. 相似文献
2.
Despite several decades of discussion and debate around the role of GIS in the discipline of Geography, it would be a stretch to argue that GIS has not irreversibly altered the discipline, both in the scope of research and teaching as well as in the wider imagination of a general public. However, it remains a challenge to incorporate the range of geographic knowledge, born of a diversity of modalities, into operational insights and analytical pre‐conditions in a GIS. To be certain, some irreconcilability between GIS and geographical inquiry is to be expected, epistemologically speaking. In what follows, we consider what might be meant by a shift to geographic analysis as scholars from disciplines in the humanities and social sciences turn to GIS as a method of observation, interpretation, analysis, and representation. In this context, we engage in a thought experiment and offer some commentary, fixing the notion of information system, while opening the geographic in GIS to more variable understanding. The point is to pursue greater development of GIS theory and method, encompassing, while not reducing, scientific, social scientific, and humanities research. 相似文献
3.
Soil water dynamics under different forest vegetation cover: Implications for hillslope stability 总被引:1,自引:0,他引:1 下载免费PDF全文
Elyas Hayati Ehsan Abdi Mohsen Mohseni Saravi John L. Nieber Baris Majnounian Giovanni B. Chirico Bruce Wilson Moharramali Nazarirad 《地球表面变化过程与地形》2018,43(10):2106-2120
Though it is well known that vegetation affects the water balance of soils through canopy interception and evapotranspiration, its hydrological contribution to soil hydrology and stability is yet to be fully quantified. To improve understanding of this hydrological process, soil water dynamics have been monitored at three adjacent hillslopes with different vegetation covers (deciduous tree cover, coniferous tree cover, and grass cover), for nine months from December 2014 to September 2015. The monitored soil moisture values were translated into soil matric suction (SMS) values to facilitate the analysis of hillslope stability. Our observations showed significant seasonal variations in SMS for each vegetation cover condition. However, a significant difference between different vegetation covers was only evident during the winter season where the mean SMS under coniferous tree cover (83.6 kPa) was significantly greater than that under grass cover (41 kPa). The hydrological reinforcing contribution due to matric suction was highest for the hillslope with coniferous tree cover, while the hillslope with deciduous tree cover was second and the hillslope with grass cover was third. The greatest contributions for all cover types were during the summer season. During the winter season, the wettest period of the monitoring study, the additional hydrological reinforcing contributions provided by the deciduous tree cover (1.5 to 6.5 kPa) or the grass cover (0.9 to 5.4 kPa) were insufficient to avoid potential slope failure conditions. However, the additional hydrological reinforcing contribution from the coniferous tree cover (5.8 to 10.4 kPa) was sufficient to provide potentially stable hillslope conditions during the winter season. Our study clearly suggests that during the winter season the hydrological effects from both deciduous tree and grass covers are insufficient to promote slope stability, while the hydrological reinforcing effects from the coniferous tree cover are sufficient even during the winter season. Copyright © 2018 John Wiley & Sons, Ltd. 相似文献
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Shane?M.?RooyakkersEmail authorView authors OrcID profile Colin?J.?N.?Wilson C.?Ian?Schipper Simon?J.?Barker Aidan?S.?R.?Allan 《Contributions to Mineralogy and Petrology》2018,173(5):35
Quenched juvenile mafic inclusions (enclaves) are an occasional but informative component in the deposits of large felsic eruptions. Typically, the groundmasses of these inclusions rapidly crystallize as the mafic magma is chilled against a more voluminous, cooler felsic host, providing a physical and chemical record of the nature and timing of mafic–felsic interactions. We examine mafic inclusions of two compositional lineages (tholeiitic and calc-alkaline) from deposits of the 25.4 ka Oruanui eruption (Taupo, New Zealand). 2-D quantitative textural data from analysis of back-scattered electron images reveal a marked diversity in the groundmass textures of the inclusions, including median crystal sizes (amphibole: 14–45 µm; plagioclase: 21–75 µm) and aspect ratios (amphibole: 1.7–4.2; plagioclase: 2.1–4.0), area number densities (amphibole: 122–2660 mm?2; plagioclase: 117–2990 mm?2), area fractions (?) of minerals (?plag?=?23–45%, ?amph?=?0–28%, ?cpx?=?0–6%, ?oxides?=?0.6–5.5%), and the relative abundance of plagioclase and amphibole (?plag/?amph?=?1.0–4.6). Textural parameters vary more significantly within, rather than between, the two compositional lineages, and in some cases show marked variations across individual clasts, implying that each inclusion’s cooling history, rather than bulk composition, was the dominant control on textural development. Groundmass mineral compositions are also diverse both within and between inclusions (e.g. plagioclase from An34–92, with typical intra-clast variability of ~?20 mol%), and do not correlate with bulk chemistry. Diverse groundmass textures and mineral and glass chemistries are inferred to reflect complex interplay of a range of factors including the degree and rate of undercooling, bulk composition, water content and, possibly, intensive variables. Our data are inconsistent with breakup of a crystallizing ponded mafic layer at the base of the Oruanui melt-dominant body, instead implying that each inclusion partially crystallized as a discrete body with a unique cooling history. Extensive ingestion of mush-derived macro-crystals suggests that mechanical breakup of mafic feeder dikes occurred within a transition zone between the mush and melt-dominant magma body. In this zone, the mush lacked yield strength, as has been inferred from field studies of narrow (meters to few tens of meters) mush-melt transition zones preserved in composite intrusions. Evidence for plastic deformation of inclusions during eruption and the abundance of fresh residual glass in inclusions from all eruptive phases suggest that the inclusions formed syn-eruptively, and must have been formed recurrently at multiple stages throughout the eruption. 相似文献
6.
The coastal ocean model FVCOM is applied to quantify the changes in circulation, flushing, and exposure time in Great South Bay, New York, after Superstorm Sandy breached the barrier island in 2012. Since then, the lagoon system is connected to the Atlantic via five instead of four inlets. The model simulations are run on two high-resolution unstructured grids, one for the pre-breach configuration, one including the new inlet, with tidal-only forcing, and summer and winter forcing conditions. Despite its small cross-sectional size, the breach has a relatively large net inflow that leads to a strengthening of the along-bay through-flow in Great South Bay (GSB); the tidally driven volume transport in central GSB quadrupled. The seasonal forcing scenarios show that the southwesterly sea breeze in summer slows down the tidally driven flow, while the forcing conditions in winter are highly variable, and the circulation is dependent on wind direction and offshore sea level. Changes in flushing and exposure time associated with the modified transport patterns are evaluated using a Eulerian passive tracer technique. Results show that the new inlet produced a significant decrease in flushing time (approximately 35% reduction under summer wind conditions and 20% reduction under winter wind conditions). Maps of exposure time reflect the local changes in circulation and flushing. 相似文献
7.
Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada 下载免费PDF全文
Rebecca N. Greenberger John F. Mustard Gordon R. Osinski Livio L. Tornabene Alexandra J. Pontefract Cassandra L. Marion Roberta L. Flemming Janette H. Wilson Edward A. Cloutis 《Meteoritics & planetary science》2016,51(12):2274-2292
Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe3+ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars. 相似文献
8.
Charismatic wildlife can be difficult to manage due to the controversies they generate among stakeholders, which may be rooted in their symbolic meaning. Using construal-level theory, we coded the images of gray wolves mentioned by respondents to a national survey (n?=?621) and an issue public survey (n?=?447) as symbolic (abstract) or corporeal (concrete). We analyzed the relationship between these representations of wolves and several perceptions that may perpetuate social conflict. Most people thought of wolves abstractly, and abstract thoughts were associated with positive feelings toward wolves and agreement with existence beliefs regarding wolves. Concrete representations were associated with identifying as a gun or property rights advocate, hunter, or farmer/rancher. Given these disparate views of wolves, engaging stakeholders through collaborative processes designed to foster a shared understanding of this species, while addressing the concerns of those groups, could be useful in reducing conflict concerning wolf management. 相似文献
9.
Peter Wilson 《Geology Today》2011,27(4):149-153
The Lake District is a region of great scenic beauty in north‐west England that has inspired artists and poets alike, and which comes high on the list of classic geological localities in Great Britain in terms of both bedrock and geomorphological features. With its inspiring views, the Lake District is often portrayed as the product of repeated glaciation, mainly because of the clarity of the erosional and depositional features that can be seen there. But since the last glaciers disappeared other processes have been modifying the landscape, processes that have superimposed their own signatures on to the glacial features. Hillslopes in particular have undergone significant changes, as a result of slope failures in both bedrock and superficial sediments. Although these landforms are not unknown, they have not received the same level of investigation as the glacial features, resulting in a limited appreciation of their spatial distribution and significance in reshaping the landscape. This article outlines the characteristics and origins of some slope failure types, and demonstrates that there is still much to learn about the Lake District landscape. 相似文献
10.
Codie Wilson Stephanie K. Kampf Sandra Ryan Tim Covino Lee H. MacDonald Hunter Gleason 《水文研究》2021,35(1):e13975
Wildfire increases the potential connectivity of runoff and sediment throughout watersheds due to greater bare soil, runoff and erosion as compared to pre-fire conditions. This research examines the connectivity of post-fire runoff and sediment from hillslopes (< 1.5 ha; n = 31) and catchments (< 1000 ha; n = 10) within two watersheds (< 1500 ha) burned by the 2012 High Park Fire in northcentral Colorado, USA. Our objectives were to: (1) identify sources and quantify magnitudes of post-fire runoff and erosion at nested hillslopes and watersheds for two rain storms with varied duration, intensity and antecedent precipitation; and (2) assess the factors affecting the magnitude and connectivity of runoff and sediment across spatial scales for these two rain storms. The two summer storms that are the focus of this research occurred during the third summer after burning. The first storm had low intensity rainfall over 11 hours (return interval <1–2 years), whereas the second event had high intensity rainfall over 1 hour (return interval <1–10 years). The lower intensity storm was preceded by high antecedent rainfall and led to low hillslope sediment yields and channel incision at most locations, whereas the high intensity storm led to infiltration-excess overland flow, high sediment yields, in-stream sediment deposition and channel substrate fining. For both storms, hillslope-to-stream sediment delivery ratios and area-normalised cross-sectional channel change increased with the percent of catchment that burned at high severity. For the high intensity storm, hillslope-to-stream sediment delivery ratios decreased with unconfined channel length (%). The findings quantify post-fire connectivity and sediment delivery from hillslopes and streams, and highlight how different types of storms can cause varying magnitues and spatial patterns of sediment transport and deposition from hillslopes through stream channel networks. 相似文献