Geochemical evolution and timescale of seawater intrusion into the coastal aquifer of Israel

This study is an attempt to quantify the geochemical processes and the timescale of seawater intrusion into a coastal aquifer from changes in the major ionic composition of the water and the natural distribution of the cosmogenic isotopes ¹⁴C and ³H. For that purpose, we sampled saline and brackish groundwaters from the Israeli coastal aquifer. A multilayer sampler (MLS) was used to obtain very high resolution (10 cm) profiles across the fresh-saline water interface (FSI).The chemical and stable isotope data revealed three distinct water types (end members) that are located in different zones on the route to the coastal aquifer: (1) slightly modified Mediterranean seawater (SWS); (2) slightly diluted (with up to 20% fresh groundwater) saline groundwater (SDS); and (3) fresh groundwater (FGW).The SWS samples generally show an excess of total alkalinity and total dissolved inorganic carbon (DIC), and a depletion of ¹³C_DIC and ¹⁴C_DIC with respect to normal seawater indicating that anaerobic oxidation of organic matter is the first diagenetic reaction that affects seawater during its penetration into the bottom sediments. SDS waters appear when SWS is slightly diluted, gain Ca²⁺ and Sr²⁺, and is depleted in K⁺, suggesting that the main processes that transform SWS into SDS are slight dilution with fresh groundwater and cation exchange. At the fresh-saline water interface, SDS generally shows conservative mixing with FGW.Inspection of chemical data from coastal aquifers around the world indicates that intensive ion exchange in slightly diluted saline groundwater is a globally important phenomenon of seawater intrusion. Most of our saline groundwater samples contain substantial amounts of ³H suggesting that penetration of Mediterranean seawater and its inland travel to a distance of 50-100 m onshore occurred 15-30 yr ago. This is supported by the ¹⁴C_DIC mass balance that explains the relatively low ¹⁴C_DIC activities in the SDS as influenced by diagenesis and not by simple radioactive decay.     

Reevaluation of the lake-sediment chronology in the Dead Sea basin, Israel, based on new Th/U dates

The Dead Sea is surrounded by chemical and detrital sediments that were deposited in its larger precursor lakes, Lake Samra and Lake Lisan. The sedimentary history of these lakes was recon-structed by means of ²³⁰Th/²³⁴U ages of 30 samples, mostly of argonite laminae, from 8 columnar sections up to 110 km apart. The general validity of the ages was demonstrated by subjecting them to tests of internal isotopic consistency, agreement with stratigraphic order, and concordance with ¹⁴C ages. In the south, only the part of the Samra Formation older than 170,000 yr is exposed, while the aragonite-detritus rhythmites found in the central and northern region are generally younger than 120,000 yr. The Lisan Formation started accumulating about 63,000 yr B.P., with the clay and aragonite beds in the south-central area reflecting a rise in water level to at least −280 m. The upper part of the Lisan Formation, the aragonite-rich White Cliff Member, started accumulating about 36,000 yr B.P. The lake probably reached its highest level sometime after this, based on the ages of Lisan sediments preserved in the southernmost reaches of the basin.     

Impact of water overexploitation on highland lakes of eastern Ethiopia

The eastern Ethiopian highland is endowed with large potential of water resources in terms of rainfall, groundwater and surface water. Yet, due to overpumping of lake water and groundwater and environmental degradation, Lakes Haromaya and Adele have completely dried up. The environmental degradation, due to deforestation and clearing of land for farming, has increased the rate of siltation in the lakes that dramatically decreases the lakes’ volume and surface albedo, which increased the rate of evaporation. The impact of these factors is aggravated due to decreasing net recharge to the lake and the alluvial aquifer. Over the last 35 years, pumping of lake water for irrigation, mainly for subsistence farming, domestic and industrial use shows an increasing trend. Hence, the available water for drinking and industrial purposes decreased drastically. In this research, classical Penman aerodynamic combined energy budget, Penman nomogram methods, conventional soil moisture water balance method and Penman–Monteith model were adopted to estimate free evaporation, actual and potential evapotranspirations. The results indicate that evaporation is the dominant factor for the loss of water and water abstraction is 316% higher than the effective precipitation, which is 110 mm/year. Therefore, overexploitation of the available resources has played an aggravating role for the loss of the lakes in the area. The main cause for such resource depletion is the lack of integrated water resources management strategies. The current water shortage in the area has mainly affected urban residents of Harar, Awoday and Alemaya towns and the surrounding villages, which depend heavily on the two lakes. To alleviate the current crises interbasin water transfer and rainwater harvesting would be possible alternatives besides ameliorating environmental situation of the basin.     

Evaluation of the Flow Measurement Performance of Compound Sharp-Crested Over-Fall Weirs and Optimized Discharge Measurement in Data Scarce Areas

Water Resources - The hydraulic relationships of flow through the weir of different common shapes were investigated in this study. The hydraulic performances of weirs were carried out...     

Genetic Structure and Diversity of the Moon Jellyfish Aurelia coerulea Polyp Population in Jaran Bay,Korea, Revealed by Mitochondrial COI and 16S rRNA Genes

Ocean Science Journal - Blooms of the moon jellyfish (Aurelia coerulea) have been responsible for huge economic losses and environmental disruptions in oceans around the world. The mass occurrence...     

Gravitational instability in isotropic MHD plasma waves

The effect of compressive viscosity, thermal conductivity and radiative heat-loss functions on the gravitational instability of infinitely extended homogeneous MHD plasma has been investigated. By taking in account these parameters we developed the six-order dispersion relation for magnetohydrodynamic (MHD) waves propagating in a homogeneous and isotropic plasma. The general dispersion relation has been developed from set of linearized basic equations and solved analytically to analyse the conditions of instability and instability of self-gravitating plasma embedded in a constant magnetic field. Our result shows that the presence of viscosity and thermal conductivity in a strong magnetic field substantially modifies the fundamental Jeans criterion of gravitational instability.     

Basin hydrogeological characterization using remote sensing,hydrogeochemical and isotope methods (the case of Baro-Akobo,Eastern Nile,Ethiopia)

Hydrogeochemical and isotopic signatures of the waters of the Baro-Akobo River Basin show deviation from signatures in other Ethiopian river basins. In this study, hydrogeochemical and isotope methods were employed to determine regional and local hydrogeology and characteristics of the basin. Optical, thermal and radar remote sensing products were used to update geological and structural maps of the basin and determine sampling points using the judgment sampling method. A total of 363 samples from wells, springs, rivers, lakes, swamps and rain were collected for this study, and an additional 270 water quality data sets were added from previous studies. These data were analyzed for their hydrogeochemical characteristics and isotope signatures. Analysis of the oxygen, deuterium and tritium isotopes shows the groundwater of the basin is modern water. Among all basins in Ethiopia, the Baro-Akobo Basin shows the highest enrichment. This indicates the proximity of the rainfall sources, which presumably are the Sudd and other wetlands in South Sudan. The hydrochemical properties of the waters show evapotranspiration is the dominant hydrologic process in the basin and explains the large amount of water that is lost in the lowland plain. Analysis of radon-222 shows no significant groundwater flux over the wetlands, which are part of Machar Marshes. This shows evaporation to be dominant hydrologic process in this zone. Results from all analyses help explain the limited holding capacity of the aquifers in the recharge zone and their vulnerability to anthropogenic impacts and climate variability. There is a trend of decreasing surface flow and rainfall and increasing water soil erosion.     

Hydrochemical characterization of complex volcanic aquifers in a continental rifted zone: the Middle Awash basin, Ethiopia

The Middle Awash basin is an arid region in Ethiopia where surface waters are scarce and local communities are dependent on groundwater resources for water supply. The complex hydrogeological system of this basin has been conceptualized. Multivariate statistical analysis of hydrochemical variables and water isotopes were used to study the rock?Cwater interaction, geochemical reaction processes and the hydrological link between aquifers. Groundwaters from aquifers of the high-rainfall plateau bounding the rift are slightly mineralized, as well as depleted in ??¹⁸O and ??D, and contain ³H above 0.8?TU. This suggests a low degree of rock?Cwater interaction and that groundwater is under recharge from heavy rain that falls on surrounding highlands. On the other hand, groundwaters from aquifers of the rift floor are highly mineralized and show slight enrichment in ??¹⁸O and ??D with positive oxygen shift, but contain ³H below 0.8?TU. The positive oxygen shift in rift floor groundwaters may be caused by the isotopic exchange of oxygen between groundwater and aquifer materials during rock?Cwater interaction, whereas the low ³H content could be due to the decay of tritium along relatively long flow paths. The approach utilized in this study may be applicable to understanding hydrogeochemical processes in other complex volcanic terrains.     

Multi-proxy approach (H/H, O/O, C/C and Sr/Sr) for the evolution of carbonate-rich groundwater in basalt dominated aquifer of Axum area, northern Ethiopia

Isotopic and chemical composition of groundwater from wells and springs, and surface water from the basalt-dominated Axum area (northern Ethiopia) provides evidence for the origin of water and dissolved species. Shallow (depth < 40 m) and deep groundwater are distinguished by both chemical and isotopic composition. Deep groundwater is significantly enriched in dissolved inorganic carbon up to 40 mmol l⁻¹ and in concentrations of Ca²⁺, Mg²⁺, Na⁺ and Si(OH)₄ compared to the shallow type.The δ²H and δ¹⁸O values of all solutions clearly indicate meteoric origin. Shifts from the local meteoric water line are attributed to evaporation of surface and spring water, and to strong water–rock interaction. The δ¹³C_DIC values of shallow groundwater between −12 and −7‰ (VPDB) display the uptake of CO₂ from local soil horizons, whereas δ¹³C_DIC of deep groundwater ranges from −5 to +1‰. Considering open system conditions with respect to gaseous CO₂, δ¹³C_DIC = +1‰ of the deep groundwater with highest PCO₂ = 10^−0.9 atm yields δ¹³C_CO2(gas) ≈ −5‰, which is close to the stable carbon isotopic composition of magmatic CO₂. Accordingly, stable carbon isotope ratios within the above range are referred to individual proportions of CO₂ from soil and magmatic origin. The uptake of magmatic CO₂ results in elevated cations and Si(OH)₄ concentrations. Weathering of local basalts is documented by ⁸⁷Sr/⁸⁶Sr ratios of the groundwater from 0.7038 to 0.7059. Highest values indicate Sr release from the basement rocks. Besides weathering of silicates, neoformation of solids has to be considered, which results in the formation of, e.g., kaolinite and montmorillonite. In several solutions supersaturation with respect to calcite is reached by outgassing of CO₂ from the solution leading to secondary calcite formation.