A regenerable Fe/AC desulfurizer for SO2 adsorption at low temperatures

A novel regenerable Fe/activated coke (AC) desulfurizer prepared by impregnation of Fe(NO₃)₃ on an activated coke was investigated. Experiment results showed that at 200 °C the SO₂ adsorption capacity of the Fe/AC was higher than that of AC or Fe₂O₃. Temperature-programmed desorption (TPD) revealed that H₂SO₄ and Fe₂(SO₄)₃ were generated on the desulfurizer upon adsorption of SO₂. Effect of desulfurization temperature was also investigated which revealed that with increasing temperature from 150 to 250 °C, the SO₂ removal ability gradually increases. The used Fe/AC can be regenerated by NH₃ at 350 °C to directly form solid ammonium-sulfate salts.     

Synthesis and Characterizations of Triphenylamine End-Functionalized Polymers via Reversible Addition-Fragmentation Chain Transfer Polymerization

A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA) group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers. The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE as the RAFT agent. Number-average molecular weight (M_n,GPC) increased linearly with monomer conversion, and molecular weight distributions were relatively narrow (PDI< 1.50). The results of chain-extension reaction, ¹H NMR spectra and UV/Vis spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine (TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated.     

弱电系统中的地线干扰与接地方法

介绍了地线的干扰机理以及减小地线干扰的对策和接地的基本方法.在电子电路中,地线不仅为电路提供一个电位公共参考点,而且也为电流提供一条能够流回源的低阻抗路径.由于地线存在阻抗,当电流流过地线时,会在地线上产生电压差,从而形成地线干扰,严重时将会影响电路的正常工作.减小或消除地线干扰的主要方法是减小地线的阻抗和地线电流.为此,可以针对不同的信号频率及干扰性质,根据系统的结构和功能采用相应的接地方式,将接地、屏蔽及滤波等措施结合使用.     

Electrical properties and positron annihilation study of (Ba<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Ho<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>)TiO<Subscript>3</Subscript> ceramics

DC resistivity, dielectric constant, dielectric loss and positron annihilation spectra of (Ba_1−x Ho _x )TiO₃ ceramics have been measured as a function of holmium concentration x. It has been found that the DC resistivity of (Ba_1−x Ho _x )TiO₃ is strongly dependent on the Ho content: it decreases three orders of magnitude and reaches a minimum at x = 0.4%. Doping with 0.6% holmium increases the permittivity of BaTiO₃ by approximately three times (from ∼1,300 to ∼4,000), with only a slight increase in the corresponding dielectric loss. The local electron density and defect concentration estimated using positron annihilation technique conforms well to the features found in the dielectric and resistivity measurements. The results have been discussed in terms of a mixed compensation model.     

钻井企业技术创新评价模型研究

随着中国钻井企业改革的深化和市场经济的不断发展完善，在中国钻井企业中将会出现技术创新的热潮。以当前钻井企业所面临的问题与挑战为背景，根据近年来国内外技术创新与评价理论的最新研究成果，结合当前钻井企业技术创新的实际，构建了钻井企业技术创新评价指标体系，运用层次分析法和模糊综合评价法构建了钻井企业的技术创新评价模型，并进行了实例分析。     

Synthesis and characterization of novel copolymer containing pyridylazo-2-naphthoxyl group via reversible addition–fragmentation chain transfer (RAFT) polymerization

A novel monomer containing pyridylazo-2-naphthoxyl group, 1-(1-(4-vinylbenzyloxy)naphthalen-2-yl)-2-(pyridin-2-yl)diazene (VBNPA), was successfully synthesized and copolymerized with styrene (St) in N,N-dimethyl formamide (DMF) via reversible addition–fragmentation chain transfer (RAFT) polymerization using 2-cyanoprop-2-yl-1-dithionaphthalate (CPDN) as RAFT agent. The polymerization behavior exhibited “living”/controlled characters. The obtained copolymer, poly(St-co-VBNPA), with pre-determinable molecular weight and narrow molecular weight distribution can be used as a carrier in metal ion detection and analysis via pre-concentration technique. The copolymer–metal ion (copper (Cu) and europium (Eu)) complexes were prepared and characterized.     

以应力分析为基础的汽包封头强度计算

本文介绍应力分析设计法的原理，通过有限元计算得到汽包封头的温度场、应力场，并以应力分析为基础对汽包封头强度作了校核。     

体相纳米气泡及其研究进展

纳米气泡是直径在1μm以下的气泡,已被证明可以在固液界面、体相中长期稳定存在。基于跨越气液界面的拉普拉斯压强定理,气泡无法保持热力学稳定,将在微秒的尺度上消失。然而,大量试验报道,体相纳米气泡可以长时间稳定存在。目前,关于纳米气泡的产生技术、表征手段和相关的稳定机制已被世界各国的课题组竞相报道。该综述对现有纳米气泡的研究成果,尤其是体相纳米气泡的研究进行总结概述。首先,总结了体相纳米气泡产生和表征的主要方法;其次,介绍了体相纳米气泡的稳定机制;再次,概括了体相纳米气泡的试验应用情况;最后,对体相纳米气泡的进一步研究和应用作出展望。     

Hydroxyl Groups Promoted Ag Dispersion and Excellent Performance of Ag/Al2O3 Catalyst for HCHO Oxidation

Catalysis Letters - Hydroxyl groups are considered as anchoring sites for active components on catalysts. Guided by this viewpoint, 4 wt. % Ag/Al2O3 catalyst derived from Boehmite (AlOOH) was...