Fluoride-mediately solvothermal synthesis and tunable photocatalytic selectivity of urchin-like ZrO2 hollow microspheres

Photocatalysts often show excellent performances on the basis of their surface state of exposed faces with high reactivity, but unfortunately surfaces of this type are usually concealed into the interior of crystals for their high surface energy. We report here a possibility that for fluorine-terminated surfaces of monoclinic ZrO₂, these higher-energy surfaces could be retained and exposed. Urchin-like ZrO₂ hollow microspheres (UZHS) composed of nanoribbons with exposed (010) facets are obtained through a fluoride mediately solvothermal method. We prove the stabilization effect of fluorine adsorption on (010) facets by density functional theory calculations. More interestingly, UZHS exhibit tunable photocatalytic selectivity in dye degradation. The fluorinated UZHS exhibit good performances both on decomposing Congo red (CR) and methylene blue, while the surface-modified UZHS by calcination only favor decomposition of CR.     

固液分离水力旋流除砂器的数值模拟

利用CFD软件,采用雷诺应力模型分别计算了300型和250型水力旋流除砂器的内流场,得到了2种水力旋流除砂器的轴向、径向、切向速度及压强的分布曲线。通过对所得结果的分析,发现模拟结果基本符合旋流除砂器的运行规律。比较2种旋流除砂器的内流场,表明改进的300型水力旋流除砂器的结构及分离能力优于原来250型水力旋流除砂器,为水力旋流除砂器的优化设计和选型提供了可靠的设计依据。     

一种无线电引信杆试验升降装置

针对目前广泛使用的无线电引信杆试验升降装置的不足，提供一种先进、简单、实用的升降装置，此装置主要由一体化减速、制动电机和控制电路组成，具有体积小、可靠性高、成本低廉等优点，是解决无线电引信杆试验测试弹升降问题的较好方案。     

A fuzzy cerebellar model articulation controller based visual servo system for robot

This paper presents a novel online learning visual servo controller integrating the FCMAC with proportion controller for the control of position of manipulator end-effector. Since the FCMAC has good learning capability and fast learning speed, and can save much computer memory space by fuzzy processing of input space division and memory unit activation, it is used to develop an adaptive control law by learning the relationship between the image feature errors and manipulator input, and the aim of online learning of the FCMAC is to minimize the output of proportion controller. Furthermore, the FCMAC has no need for models of robot manipulator and image feature extraction, so that the capability of proposed controller for tasks under uncertain environment can be improved. Finally, the proposed controller is proved to be effective by the experiment, and compared with BP neural network.     

中国粗锑精炼研究现状与展望

我国是全球最大的锑生产国,但因锑资源的快速消耗,锑的生产已由以辉锑矿为主转向以处理含锑复杂多金属共生矿为主.目前,我国广泛应用的火法炼锑工艺处理含锑复杂多金属共生矿均不理想,适合处理含锑复杂多金属共生矿的湿法炼锑工艺将是锑生产发展的重要方向.因此,现有的粗锑精炼工艺能否满足未来锑生产发展的需要值得关注.结合粗锑精炼的基本要求,对粗锑碱性火法精炼、水溶液电解精炼、真空蒸馏精炼、熔盐电解精炼以及联合精炼工艺的特点以及面临的问题进行评述,总结归纳了当前各精炼工艺的研究现状.碱性火法精炼工艺适合处理火法炼锑工艺产出的粗锑,水溶液电解精炼工艺和真空蒸馏精炼工艺适合处理含贵金属粗锑,熔盐电解精炼工艺可用于高纯锑生产,联合精炼工艺用于难处理粗锑的精炼.在此基础上,指出传统的碱性火法精炼工艺应着重开发多用途高效复合除杂剂,并提出了将真空蒸馏精炼工艺和碱性火法精炼工艺配合使用的粗锑精炼新方向.     

真空蒸馏法从铟中脱除Cd、Tl的研究

介绍真空蒸馏法取代传统试剂法从铟中脱除镉和铊。通过实验研究了采用真空蒸馏的方法从铟中脱除铊的最佳工艺条件。实验表明,控制蒸馏温度950℃,恒温时间40m in,即可使残余物中铊的含量为0.0006%,铟的挥发率2.14%。     

水下滑翔机李雅普诺夫稳定性分析

水下滑翔机作为一种新型的水下机器人利用了水平固定翼将净重力转换为前进驱动力,从而降低了水下机器人的功耗,在海洋科学研究、环境监测、资源探测和军事侦察等方面都具有广阔的应用前景。为了得到实际水下滑翔机稳定性与设计参数和控制参数之间的关系,将已建立的水下滑翔机一般数学模型应用于具体的实际水下滑翔机上。在此基础上将模型线性化,结合李雅普诺夫稳定性第一定理和第二定理,分析出水下滑翔机定常运动的动态稳定性随设计参数(初稳性高)和控制参数(姿态调节控制量)变化的规律。为水下滑翔机器人的设计和控制提供理论依据。     

热膨胀法判定建窑黑瓷烧成温度的应用研究

以热膨胀仪判定建窑黑瓷烧成温度的研究为例,综合运用多种测试方法对建窑黑瓷标本进行了系统研究,探讨如何从建窑黑瓷胎体重烧热膨胀曲线中筛选有效转折点的问题及其转折点的形成原因。研究表明:(1)建窑黑瓷胎体重烧热膨胀曲线上有三个转折点,分别为收缩转折点、膨胀转折点和急剧收缩点。其中第一个收缩转折点是判定其古代烧成温度的关键点。(2)建窑黑瓷胎体重烧热膨胀曲线上膨胀转折点和急剧收缩点的形成皆与其胎体中大量Fe_2O_3在高温下发生分解反应有关。该研究不仅为热膨胀仪测定建窑黑瓷烧成温度的应用研究提供判定依据,也将为科学认识古陶瓷胎体重烧热膨胀曲线上多个转折点的形成机理提供数据支持。     

Effects of ZrO2 on the structure and magnetic properties of CoPt thin films

[CoPt 1.5 ml/ZrO2 xnm]10 multilayer films were deposited on glass substrates by magnetron sputtering and then annealed in vacuum at 600℃ for 30 min. Their structures and magnetic properties were investigated as a function of ZrO2 content. The results show that the grain size and coercivity first increase and then decrease with the increase in ZrO2 content. The maximum coercivity and grain size are obtained at 37 vol.% of ZrO2. The content of ZrO2 in the film plays an important role in the separation of CoPt grains and in the reduction of intergrain exchange interaction. On the basis of the studies of angular dependent coercivity, it is found that the magnetization reversal of CoPt films with （111 ） texture is different from either the domain wall motion or the S-W type of rotation mode.     

闸坝调度对水质改善的可调性研究

以沙颖河干流上的槐店闸为代表性闸坝,提出一套闸坝调度对河流水质改善的可调性评估技 术方法。其内容包括:首先,对闸坝调度改善水质状况的可调性的概念及其内涵进行了界定;为了定 量评估闸坝可调性,进一步研制了闸坝调度影响模型(考虑闸坝及底泥影响的一维水动力和水环境模 型)和闸坝可调性的评价指标和评价方法;然后将以上方法应用于槐店闸,对槐店闸改善河流水质的 可调性进行了识别。