PVC／NBR（HNBR）／HDPE共混体系相容性研究（Ⅲ）共混体系动态力学行为和结晶行为研究

用ＤＭＡ和ＤＳＣ研究了ＮＢＲ和氢化ＮＢＲ对ＰＶＣ／ＨＤＰＥ共混体系的增容作用。由于增容剂在相界面与ＰＶＣ和ＨＤＰＥ所产生的作用改变了界面分子的作用形式，使体系中ＰＶＣ和ＨＤＰＥ相的内耗峰内移。而ＤＳＣ的结果表明，增容剂降低了体系中结晶相ＨＤＰＥ的熔点，说明增容剂增加了ＰＶＣ／ＨＤＰＥ的相容性。     

PVC／NBR／HDPE共混体系相容性研究（Ⅰ）增容剂对力学性能的影响

采用丁腈橡胶（ＮＢＲ）及其氢化还原后产物（ＨＮＢＲ）为ＰＶＣ／ＨＤＰＥ共混体系的增容剂，研究了增容剂结构、用量及丙烯腈含量对共混体系相容性的影响。发现丁腈橡胶（ＮＢＲ２９及ＨＮＢＲ２９）对ＰＶＣ／ＨＤＰＥ体系有较好的增容作用，而ＮＢＲ４０及ＨＮＢＲ４０较差。当增容剂用量为２％，ＰＥ含量为８％～１２％时，共混物具有较好的相容性，力学性能得到改善。     

FLOCCULATION OF KAOLIN SUSPENSION OF ISOTACTIC-AND ATACTIC-POLY(N-PROPYL-2-VINYLPYRIDINIUM BROMIDE)

Isotactic-and atactic-poly(N-propyl-2-vinylpyridinium bromide)QIP2VP and QAP2VP were used asflocculants for kaolin suspension.The effects of their molecular structure of floeculation were studied.Theresults are as follows:(1)The ability of flocculation of QAP2VP is better than that of QIP2VP.(2)The flocculating efficiency of QAP2VP,but not QIP2VP,increased as the molecular weight in-creased.(3)In the range of lower degree of quaternization,the efficiency of flocculation increased as thedegree of quaternization of flocculants decreased.(4)An abnormal phenomenon,which is considered as the“homocharge stabilization”,was discoveredat a certain concentration of flocculants.(5)An equation of the relationship among the experimental parametars,such as sedimentation rate,sedimentation volume and turbidity,was derived.     

掺合料对水泥基材料抗酸腐蚀性能的影响

水工结构混凝土酸腐蚀较普遍,严重影响了水工结构的寿命.文中以提高混凝土的抗酸性能为目标,从混凝土原材料方面展开研究,以聚丙烯纤维、粉煤灰、矿粉和水玻璃为主要掺合料,系统地研究了多掺复合料对水泥基材料抗酸腐蚀性能的影响.研究表明,粉煤灰掺量为15%～30%时,抗酸性能较好;矿粉掺量为15%～30%时,抗弱酸性能较好,抗强酸性能变化较小;水玻璃掺量为1.5%～3.0%时,抗酸性能较好;复掺时,粉煤灰:矿粉:水玻璃=15%:30%:1.5%效果较佳.     

Environmentally benign chitosan as reductant and supporter for synthesis of Ag/AgCl/chitosan composites by one-step and their photocatalytic degradation performance under visible-light irradiation

A novel Ag/AgCl/chitosan composite photocatalyst was successfully prepared by a simple one-step method. During this progress, environmentally benign chitosan not only served as reductant to reduce Ag⁺ to Ag⁰ species, but also acted as supporter for Ag/AgCl nanoparticles. XRD, SEM, EDX, UV-vis DRS and XPS were employed to characterize the as-prepared simples. SEM images of Ag/AgCl/chitosan composites revealed that Ag/AgCl nanoparticles were successfully loaded onto chitosan without obvious aggregation. All Ag/AgCl/chitosan composites exhibited efficient photocatalytic activity for the degradation of rhodamine B (RhB) under visible-light irradiation. The result of photocatalytic degradation experiment indicated that 20% of the mass ratio of AgCl to chitosan was the optimum, and after 40 min photocatalytic reaction, the degradation rate reached about 96%.     

基于LabWindows/CVI与Matlab混编的在线BCI系统

基于LabWindows/CVI和Matlab设计一个BCI在线控制系统,对8Hz～30Hz的运动想象脑电信号提取时域均值、中值偏差估计、瞬时能量均值、AR模型参数等特征,应用增量式支持向量机进行分类,实现人脑对虚拟汽车直接控制。系统采用了多线程技术,保证各项工作的同时进行,在CVI中完成脑电数据采集、Matlab调用和控制指令的发送,在Matlab中进行脑电模式识别,两个程序共同完成对虚拟汽车的运动控制。经过实际测试证明,该系统具有操作简单方便、界面友好、可扩展性强、效率和可靠性高等优点,进一步推动了BCI的应用。     

锅炉水管系统设计数据的描述与处理

根据锅炉水管系统结构的特点，提出以管子布置方式描述水管系统的特征结构；讨论了由布置方式以及管子零件图来生成水管系统三视图的数据处理方法．     

Preparation,Characterization and Properties of Novel Cationic Gemini Surfactants with Rigid Amido Spacer Groups

A series of novel cationic gemini surfactants with rigid amido groups inserted as the spacers, named C ₁₂ ‐PPDA‐C ₁₂ , C ₁₄ ‐PPDA‐C ₁₄ and C ₁₆ ‐PPDA‐C ₁₆ , were synthesized by a two‐step reaction with dimethyl terephthalate, N,N‐dimethyl propylene diamine and alkyl bromide as raw materials. The chemical structures of the prepared compounds were confirmed by IR, ¹H and ¹³C NMR and element analysis. Surface activity properties of the synthesized compounds were investigated by surface tension, electrical conductivity and fluorescence. Increasing the number of carbon atoms in the hydrophobic alkyl chain, decreased the critical micelle concentration (CMC), surface tension at the CMC and the minimum surface area. Other relevant properties including foaming ability and emulsion stability were investigated. The results indicated that the synthesized gemini surfactants possess good surface properties, emulsifying properties and steady foam properties.     

詹家湾滑坡地质特征及其稳定性分析评价

詹家湾滑坡为三峡库区典型的堆积层滑坡,总结该滑坡的发育特征并分析评价其稳定性,对于研究库区同类滑坡具有借鉴意义。基于大量勘探资料,该文从滑坡空间形态、滑坡物质组成及结构特征、滑坡水文地质、滑带土物理力学性质、滑坡成因机制分析、滑坡变形特征等多个方面揭示了詹家湾滑坡的地质特征,并在此基础上按自重、地表荷载、库水位从175m降至145m、地震5、年一遇暴雨等各种工况组合对滑坡稳定性进行了计算,最后综合分析和评价了该滑坡稳定性。分析认为现阶段滑坡处于不稳定状态,须进行工程处理。     

武钢高炉喷煤工艺技术进步

对武钢高炉喷煤制粉系统及喷吹系统工艺技术进步进行了总结,阐述了制粉系统、喷吹系统工艺技术及生产实践中出现的问题及改进措施.