Synthesis of Hollow Three-Dimensional Channels LiNi_(0.5)Mn_(1.5)O_4 Microsphere by PEO Soft Template Assisted with Solvothermal Method

A appropriate size with three-dimension(3 D) channels for lithium diffusion plays an important role in constructing highperforming LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode materials, as it can not only reduce the transport path of lithium ions and electrons, but also reduce the side effects and withstand the structural strain in the process of repetitive Li~+ intercalation/deintercalation. In this work, an e fficient method for designing the hollow LNMO microsphere with 3 D channels structure by using polyethylene oxide(PEO) as soft template agent assisted solvothermal method is proposed. Experimental results indicate that PEO can make the reagents mingle evenly and nucleate slowly in the solvothermal process, thus obtaining a homogeneous distribution of carbonate precursors. In the final LNMO products, the hollow 3 D channels structure obtained by the decomposition of PEO and carbonate precursor in the calcination can provide abundant electroactive zones and electron/ion transport paths during the charge/discharge process, which benefits to improve the cycling performance and rate capability. The LNMO prepared by adding 1 g PEO possesses the most outstanding electrochemical performance, which presented an excellent discharge capacity of 143.1 mAh g~(-1) at 0.1 C and with a capacity retention of 92.2% after 100 cycles at 1 C. The superior performance attributed to the 3 D channels structure of hollow microspheres, which provide uninterrupted conductive systems and therefore achieve the stable transfer for electron/ion.     

基于跨临界CO2热泵的茶叶生产能源系统负荷削减潜力

乡村产业中的化石能源设备逐渐被电能技术替代，引起了乡村负荷波动增大、部分时段产生集中高负荷的问题。为了解决以上问题，将低品位清洁能源应用至乡村的茶叶生产中，针对烘茶全过程的工艺要求提出了跨临界CO₂热泵烘茶技术；并以某茶叶生产乡村为对象，对其代表台区的全年日用电量及产茶日负荷进行了分析，得出采用CO₂热泵烘茶后其负荷得到大幅度削减，整体可降低至原负荷的39.6%~46.8%，峰值负荷与平时负荷的比值由原本的13.6降至5.4~6.2。跨临界CO₂热泵应用至农产品生产中可有效缓解乡村供电压力。     

Waveguide external cavity narrow linewidth semiconductor lasers

Narrow linewidth light source is a prerequisite for high-performance coherent optical communication and sensing.Waveguide-based external cavity narrow linewidth semiconductor lasers(WEC-NLSLs)have become a competitive and attractive candidate for many coherent applications due to their small size,volume,low energy consumption,low cost and the ability to integrate with other optical components.In this paper,we present an overview of WEC-NLSLs from their required technologies to the state-of-the-art progress.Moreover,we highlight the common problems occurring to current WEC-NLSLs and show the possible approaches to resolving the issues.Finally,we present the possible development directions for the next phase and hope this review will be beneficial to the advancements of WEC-NLSLs.     

高吸水性树脂提高井壁混凝土水密性能的机理

裂缝的产生会导致井壁混凝土的水密性能和耐久性能降低.高吸水性树脂(SAP)可在裂缝中膨胀并堵塞裂缝,从而提高井壁混凝土的水密性能和耐久性能.但SAP堵塞裂缝的机理仍需进一步研究.探究了SAP对混凝土力学性能的影响.通过水渗透测试分析了SAP的裂缝堵塞效果.并借助X射线计算机断层扫描技术探究了裂缝中SAP颗粒的形态特征.结果表明,SAP的掺入导致混凝土的抗压强度和劈裂抗拉强度略有减小.SAP的掺入也会导致预开裂砂浆中的水流速减小,水流速的减小程度随SAP掺量的增加而增大.SAP可在SAP孔中膨胀并堵塞SAP孔位置的裂缝,说明SAP导致水流速减小的原因是SAP能够在裂缝中发生膨胀.     

基于落渣碰撞信号的锅炉结渣诊断技术的研究

针对我国燃煤锅炉普遍存在的结渣问题,提出了基于落渣碰撞信号的结渣诊断方法:能量包络线法以信号的第一个峰值点作为到达时刻,后通过网格法确定撞击区域。通过多种质量、软硬程度材料的平板冲击实验模拟炉内落渣碰撞信号,结果表明该方法具有较高的定位精度,相对误差在10%以内,且随落渣的质量和硬度的增大,定位精度有所提升;在一定强度的噪声干扰下,仍能较好地定位撞击区域,具有工程应用价值。