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Reliable joints of Ti3SiC2 ceramic and TC11 alloy were diffusion bonded with a 50 μm thick Cu interlayer. The typical interfacial structure of the diffusion boned joint, which was dependent on the interdiffusion and chemical reactions between Al, Si and Ti atoms from the base materials and Cu interlayer, was TC11/α-Ti + β-Ti + Ti2Cu + TiCu/Ti5Si4 + TiSiCu/Cu(s, s)/Ti3SiC2. The influence of bonding temperature and time on the interfacial structure and mechanical properties of Ti3SiC2/Cu/TC11 joint was analyzed. With the increase of bonding temperature and time, the joint shear strength was gradually increased due to enhanced atomic diffusion. However, the thickness of Ti5Si4 and TiSiCu layers with high microhardness increased for a long holding time, resulting in the reduction of bonding strength. The maximum shear strength of 251 ± 6 MPa was obtained for the joint diffusion bonded at 850 °C for 60 min, and fracture primarily occurred at the diffusion layer adjacent to the Ti3SiC2 substrate. This work provided an economical and convenient solution for broadening the engineering application of Ti3SiC2 ceramic. 相似文献
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In this paper, we first re-examine the previous protocol of controlled quantum secure direct communication of Zhang et al.’s scheme, which was found insecure under two kinds of attacks, fake entangled particles attack and disentanglement attack. Then, by changing the party of the preparation of cluster states and using unitary operations, we present an improved protocol which can avoid these two kinds of attacks. Moreover, the protocol is proposed using the three-qubit partially entangled set of states. It is more efficient by only using three particles rather than four or even more to transmit one bit secret information. Given our using state is much easier to prepare for multiqubit states and our protocol needs less measurement resource, it makes this protocol more convenient from an applied point of view. 相似文献
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荆山玉是湖北省保康县新发现的一个玉石品种,形成于大陆边缘—洋盆区过渡带的热水沉积环境,为晚震旦世—早寒武世灯影组的一种硅质角砾岩:原地震碎角砾岩,由角砾和胶结物二部分构成,角砾局部可拼接;角砾成分为早期硅质岩碎裂产物,胶结物除早期硅质岩碎裂产物外,还有少量后期充填的石英、铁质等,受角砾、胶结物颗粒大小、裂隙发育程度不同的影响,后期热液改造程度不同,角砾和胶结物化学成分存在一定的差异,色调与铁质有关。荆山玉的形成主要经历了三个阶段的演化:第一阶段,低温150~225℃、弱氧化—弱还原条件下热水成因的硅质岩形成;第二阶段,热力膨胀外力作用下,硅质岩局部原地震碎形成硅质角砾岩,热水温度243~340℃,富氧氧化—贫氧过渡环境,红褐色的Fe~(3+)在胶结物、裂隙中富集;第三阶段,热水温度116~127℃、缺氧还原条件,黄色的Fe~(2+)在胶结物、裂隙中富集。 相似文献
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Hong Wei Li Li Ya‐Li Ma Ru‐Xue Liu Shuang‐Yan Meng Li‐Tong Niu Zhe Zhang Zhi‐Wang Yang 《火与材料》2019,43(7):868-879
Through the simple precipitation of palygorskite (PGS) by zinc borate (ZB) (to make PGS@ZB) and the decoration of PGS@ZB by dodecylamine (N), a novel organic‐inorganic@inorganic hybrid flame retardant of PGS@ZB‐N was prepared and was incorporated with ethylene vinyl acetate copolymer (EVA) to improve its flame retardance. The structure and morphology of PGS@ZB‐N were characterized by Fourier transform infrared (FTIR) spectroscopy, X‐ray diffraction (XRD), and scanning electron microscopy (SEM), and it was confirmed that the PGS@ZB‐N hybrid had been successfully prepared. The flame retardancy and burning behavior of EVA/PGS@ZB‐N/EG (EG = expandable graphite) composite were studied through thermogravimetric analysis (TGA), limiting oxygen index (LOI), UL‐94 (by the vertical burning test), and cone calorimeter test (CCT) characterizations. The prepared EVA/PGS@ZB‐N/EG composite obtained an LOI value of 41.2% with the addition of 30 wt% PGS@ZB‐N/EG. It was found that EVA/PGS@ZB‐N/EG was protected through a gas phase and condensed phase alternating synergistic effect mechanism. 相似文献
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Siqi Yu Qin Wang Jianwei Wang Yong Xiang Xiaobin Niu Tingshuai Li 《International Journal of Hydrogen Energy》2021,46(27):14331-14337
Artificial nitrogen fixation is emerging as a promising approach for synthesis of ammonia at mild conditions. Inspired by biological nitrogen fixation based on bacteria containing iron, zinc doped Fe2O3 nanoparticles are proposed as an efficient and earth abundant electrocatalyst for converting N2 to NH3. In neutral media, it achieves a maximum Faradaic efficiency (FE) of 10.4% and a large NH3 yield rate of 15.1 μg h?1 mg?1cat. at ?0.5 V vs. reversible hydrogen electrode. This catalyst also exhibits excellent selectivity and stability. Theoretical calculations suggest the reaction follows the associative enzymatic mechanism and it has a barrier of as low as 0.68 eV. 相似文献
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