Formation of Zinc–Antimony-Based Spinel Phases

Formation of spinel phases in ZnO–Sb₂O₃and ZnO–Sb₂O₃–Bi₂O₃systems is studied by the use of X-ray diffraction. The formation of nonstoichiometric Zn_2.33Sb_0.67O₄phase is observed in both the systems at ∼900°C. However, in these systems, at higher temperatures ( T ≥ 1100°C), formation of the inverse spinel phase Zn₇Sb₂O₁₂is observed. The study has been extended to understand the effect of CrO₃doping on the stability of the different spinel phases in the previously mentioned systems. Interestingly, in both the systems, samples doped with CrO₃, displayed the presence of Zn_2.33Sb_0.67O₄phase <1200°C, indicating the stabilization of the spinel phase by CrO₃.     

Nonlinear radiation on Maxwell fluid in a convective heat transfer with viscous dissipation and activation energy

The present analysis addresses linear and nonlinear radiation effects in hydrodynamic viscous Maxwell fluid flow on a unidirectional stretching surface through viscous dissipation. The relaxation effect is considered in the mathematical model, which elucidates mass transport mechanisms under binary chemical reaction and activation energy. Mathematical modeling contains nonlinear partial differential equations using boundary conditions. Appropriate transformations convert the partial differential equations into ordinary differential equations. Numerical solutions for regular differential equations are brought by Runge–Kutta–Fehlberg numerical quadrature and a shooting method with a tolerance level of 10⁻⁹. The influence of physical variables, such as Deborah relaxation number, rotation parameter, Biot number, activation energy parameter, reaction rate parameter, Eckert number, and Prandtl number are investigated. Increasing the Biot number improves the temperature region in the boundary layer. With high rotation, the increasing Deborah number enhances the fluid temperature substantially throughout the boundary layer.     

MALEO: Modular Assembly in Low Earth Orbit: Alternate Strategy for Lunar Base Development

Modular assembly in low Earth orbit (MALEO) is a new strategy for building an initial operational‐capability lunar habitation base, the main purpose of which is to safely initiate and sustain early lunar base buildup operations. In this strategy the lunar base components are brought up to low Earth orbit (LEO) by the Space Transportation System (STS), and assembled there to form the complete lunar base. Specially designed propulsion systems are then used to transport the MALEO lunar base, complete and intact, all the way to the moon. Upon touchdown on the lunar surface, the MALEO lunar habitation base is operational. The strategy is unlike conventional concepts, which have suggested that the components of the lunar base be launched separately from the Earth and landed one at a time on the moon, where they are assembled by robots and astronauts in extravehicular activity (EVA). The architectural drivers for the MALEO concept are, first, the need to provide an assured safe haven and comfortable working environment for the astronaut crew as safely and as quickly as possible, with the minimum initially risky EVA, and secondly, the maximum exploitation of the evolutionary benefits derived from the assembly and operation of space station Freedom (SSF‐1). Commonality and inheritability from the space station assembly experience is expected to have an advantageous impact on both the space station program as well as the MALEO lunar base.     

Electrocatalytic reduction of hydrogen peroxide at nanostructured copper modified electrode

The electrocatalytic reduction of hydrogen peroxide (H₂O₂) has been studied at nanostructured copper (Cu_nano) modified glassy carbon (GC/Cu_nano) electrode in phosphate buffer (pH 7.2). The electrical properties of GC/Cu_nano modified electrodes were studied by electrochemical impedance spectroscopy (EIS). Surface and electrochemical characterization were carried out by using atomic force microscopy (AFM) and cyclic voltammetry. A well-defined H₂O₂ reduction signal, which is due to mediation of a surface active site redox transition exhibits at the GC/Cu_nano electrode. The Cu_nano is acting as a bridge without the aid of any other electron mediator, which enables the direct electron transfer between the modified electrode and the substrate. The results are compared with bulk copper macroelectrode and emphasized the efficiency of the Cu_nano modified electrode. Systematic investigations were made to optimize the experimental parameter, such as applied potential (E_app) for copper electrodeposition. The calibration curve obtained from chronoamperometric studies was found to be linear in the range 0.5 to 8.0 μM H₂O₂ with a detection limit of ca.10 nM (S/N = 3) at the GC/Cu_nano electrode. The modified electrode is stable for 1 week in phosphate buffer after repetitive measurements.     

Poly(4‐vinyl pyridine)‐grafted graphene oxide for drug delivery and antimicrobial applications

Graphene oxide (GO) was covalently functionalized with poly(4‐vinyl pyridine) (P4VP) by atom transfer radical polymerization for drug delivery and antimicrobial applications. The physiochemical properties, chemical structure, composition and morphology of the P4VP‐functionalized GO (GO‐P4VP) were studied. Simple physisorption of a cancer drug, camptothecin (CPT), via π ? π stacking and/or hydrophobic interactions on the GO‐P4VP was tested for drug loading and its release by altering the pH. The GO‐P4VP has low cytotoxicity, and the CPT‐loaded GO‐P4VP exhibited a high potency for killing cancer cells in vitro. Prominent antimicrobial properties against Escherichia coli and Staphylococcus aureus were also observed. Thus, the GO‐P4VP can be utilized as a drug delivery vector with high biocompatibility, solubility and stability in physiological solutions, a suitable payload capacity and excellent bacterial toxicity. Owing to its small size, low cost, large specific area, ready scalability and useful non‐covalent interactions, GO‐P4VP is a novel material for biomedical, industrial and environmental applications. © 2015 Society of Chemical Industry     

An improved distance‐based ant colony optimization routing for vehicular ad hoc networks

Vehicular ad hoc network (VANET) has earned tremendous attraction in the recent period due to its usage in a wireless intelligent transportation system. VANET is a unique form of mobile ad hoc network (MANET). Routing issues such as high mobility of nodes, frequent path breaks, the blind broadcasting of messages, and bandwidth constraints in VANET increase communication cost, frequent path failure, and overhead and decrease efficiency in routing, and shortest path in routing provides solutions to overcome all these problems. Finding the shortest path between source and destination in the VANET road scenario is a challenging task. Long path increases network overhead, communication cost, and frequent path failure and decreases routing efficiency. To increase efficiency in routing a novel, improved distance‐based ant colony optimization routing (IDBACOR) is proposed. The proposed IDBACOR determines intervehicular distance, and it is triggered by modified ant colony optimization (modified ACO). The modified ACO method is a metaheuristic approach, motivated by the natural behavior of ants. The simulation result indicates that the overall performance of our proposed scheme is better than ant colony optimization (ACO), opposition‐based ant colony optimization (OACO), and greedy routing with ant colony optimization (GRACO) in terms of throughput, average communication cost, average propagation delay, average routing overhead, and average packet delivery ratio.