Preserving Dependency Relationship Among Real-Time Transactions in Middleware for Replicated DRTDBS

Wireless Personal Communications - Dependency relationship plays an essential role in coordinating and processing the real time transactions (RTTs) in the replicated distributed real time database...     

Oxidation of some aliphatic polyols on anodically deposited MnO2

Galvanostatic steady state current potential measurements were carried out for oxidation of a series of aliphatic alcohols having varying number of hydroxyl groups. The anodically deposited layer of MnO₂ on platinum was used as the electrode material. The deposit was characterised by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX) and electrode potential measurements. The catalytic role of MnO₂ in the electro-oxidation of alcohols was indicated by the chronopotentiograms and the cyclic voltammograms. An analysis of the electrochemical data indicated a catalytic EC mechanism in which Mn (V) is generated electrochemically and consumed chemically in succession. Based on this and the hydrogen bonding interaction between alcoholic hydroxyl groups and MnO₂ layer, a mechanism was proposed which accounts for the variation in the observed electrochemical reaction orders. Tafel behaviour was found to be followed only approximately. Current efficiency of the electrochemical oxidation of polyols was studied. Replacement of platinum by carbon as current collector was found to leave the electrocatalytic activity of the MnO₂ deposit practically unaltered.     

A post quantum secure construction of an authentication protocol for satellite communication

Satellite's communication system is used to communicate under significant distance and circumstances where the other communication systems are not comfortable. Since all the data are exchanged over a public channel, so the security of the data is an essential component for the communicating parties. Both key exchange and authentication are two cryptographic tools to establish a secure communication between two parties. Currently, various kinds of authentication protocols are available to establish a secure network, but all of them depend on number–theoretical (discrete logarithm problem/factorization assumption) hard assumptions. Due to Shor's and Grover's computing algorithm number theoretic assumptions are breakable by quantum computers. Although Kumar and Garg have proposed a quantum attack-resistant protocol for satellite communication, it cannot resist stolen smart card attack. We have analyzed that how Kumar and Garg is vulnerable to the stolen smart card attack using differential power analysis attack described in He et al and Chen and Chen. We have also analyzed the modified version of signal leakage attack and sometimes called improved signal leakage attack on Kumar and Garg's protocol. We have tried to construct a secure and efficient authentication protocol for satellites communication that is secure against quantum computing. This is more efficient as it requires only three messages of exchange. This paper includes security proof and performance of the proposed authentication and key agreement protocol.     

A rheological study on aged binder rejuvenated with Pongamia oil and Composite castor oil

Recycling of highway materials is an effort to preserve the natural environment, reduce waste and provide a cost-effective way for construction of highways. The reclaimed asphalt pavement (RAP) contains stiffened binder caused by loss of volatile materials and oxidation. Hence, the addition of high amount of the RAP to asphalt mix may make it prone to fatigue failure. Due to this reason, addition of RAP to asphalt mixture in substantial amount has been a challenge so far. Therefore, ‘rejuvenators’ which are supposed to restore chemical and physical properties of the aged asphalts are used effectively in asphalt mixture. In this study, two locally available oils, i.e. pongamia oil (locally known as Karanja oil) derived from the seeds of Pongamia pinnata and a composite rejuvenator made of castor oil and coke oven gas condensate have been explored for rejuvenating the aged binder. The rheological properties of aged binder and rejuvenated binders were studied using a dynamic shear rheometer. From the various rheological tests conducted, it was found that certain proportion of pongamia oil as well as composite castor oil was able to impart desirable rutting as well as fatigue performance for the rejuvenated binder samples. The thermal analysis carried out using thermogravimetric analysis ensured adequate thermal stability for the binder specimens treated with these oils. In terms of binder performances, it was found that these oils could be considered as suitable rejuvenators for effectively restoring properties of the aged binder. Performance studies on RAP mixes may be extended for recommending these two oils as rejuvenators for hot mix pavement recycling.     

Modeling heterogeneous bacterial populations exposed to antibiotics: The logistic‐dynamics case

In typical in vitro tests for clinical use or development of antibiotics, samples from a bacterial population are exposed to an antibiotic at various concentrations. The resulting data can then be used to build a mathematical model suitable for dosing regimen design or for further development. For bacterial populations that include resistant subpopulations—an issue that has reached alarming proportions—building such a model is challenging. In prior work, we developed a related modeling framework for such heterogeneous bacterial populations following linear dynamics when exposed to an antibiotic. We extend this framework to the case of logistic dynamics, common among strongly resistant bacterial strains. Explicit formulas are developed that can be easily used in parameter estimation and subsequent dosing regimen design under realistic pharmacokinetic conditions. A case study using experimental data from the effect of an antibiotic on a gram‐negative bacterial population exemplifies the usefulness of the proposed approach. © 2015 American Institute of Chemical Engineers AIChE J, 61: 2385–2393, 2015     

Effect of interface coupling between polarization and magnetization in La0.7Pb0.3MnO3 (LPMO)/P(VDF-TrFE) flexible nanocomposite films

Journal of Materials Science - La0.7Pb0.3MnO3(LPMO) nanoparticles (NPs) were prepared by sol–gel auto-combustion method. These were embedded in P(VDF-TrFE) to form (0–3) nanocomposite...     

IoT Based Multimode Sensing Platform for Underground Coal Mines

Wireless Personal Communications - Real-time information of the underground environment plays a vital role for underground coal mines. For this purpose, a number of systems have been developed by...     

Modeling and simulation of temperature drift for ISFET-based pH sensor and its compensation through machine learning techniques

The paper presents modeling and simulation of ion-sensitive field-effect transistor (ISFET)-based pH sensor with temperature-dependent behavioral macromodel and proposes to compensate the temperature drift in the sensor using intelligent machine learning (ML) models. The macromodel is built using SPICE by introducing electrochemical parameters in a metal-oxide-semiconductor field-effect transistor (MOSFET) model to simulate ISFET characteristics. We account for the temperature dependence of electrochemical and semiconductor parameters in our macromodel to increase its robustness. The macromodel is then exported as a subcircuit element, which is used to design the readout interface circuit. A simple constant-voltage, constant-current (CVCC) topology is utilized to generate the data for temperature drift in ISFET pH sensor, which is used to train and test state-of-the-art ML-based regression models in order to compensate the drift behavior. The experimental results demonstrate that the random forest (RF) technique achieves the best performance with very high correlation and low error rate. Corresponding curves for output signal using the trained models show highly temperature-independent characteristics when tested for pH 2, 4, 7, 10, and 12, and we obtained a root mean squared error (RMS) variation of ΔpH ≤ 0.024 over a temperature range of 15°C to 55°C in comparison with ΔpH ≤ 1.346 for uncompensated output signal. This work establishes the framework for integration of ML techniques for drift compensation of ISFET chemical sensor to improve its performance.     

Correlation between spin–phonon coupling and magneto-electric effects in CoFe2O4/PMN-PT nanocomposite: Raman spectroscopy and XMCD study

We have investigated strain-induced spin lattice coupling in the CoFe₂O₄/0.65Pb (Mg_1/3Nb_2/3)O₃–0.35PbTiO₃(PMN-PT) composite system, evident by temperature-dependent Raman spectroscopy and magnetization measurements. The strain interactions lead to magneto-electric coupling, and the measured magneto-electric voltage coefficient is 40 mV/cm^?1Oe^?1 for the CoFe₂O₄/PMN-PT composite samples. X-ray magnetic circular dichroism (XMCD) analysis establishes modified spin structure in the electrically poled CoFe₂O₄/PMN-PT composite, further validating the coupling between magnetic and electric ordering in the composite. The magneto-electric coupling coefficient α vs dc magnetic field curves revealed hysteretic behavior and enhanced α values after electric poling, which originates from the strain-induced modifications in the magnetic structure of composite in the electrically poled samples. These findings suggest that the existence of spin lattice coupling may lead to the mechanism of strong magneto-electric effects via strain interactions in CoFe₂O₄/PMN-PT composite.

     

Multi-mode hydrogen storage in nanocontainers

Hydrogen can be stored in containers or in materials (in molecular or atomic forms). The atomic form can further exist as multiple phases. Molecular hydrogen can be adsorbed on the surface or can be present inside the material. By invoking multiple modes of hydrogen storage, we establish a paradigm shift in the philosophy of hydrogen storage. Using a novel strategy of storage of molecular hydrogen in metal (Pd) nanocontainers, we observe that 18% hydrogen is in molecular form. Interestingly, this is achieved at 25 °C and 1 atm pressure; which is in contrast to storage in MOFs and carbonaceous materials like nanotubes. Enhancement in storage capacity as compared to Pd nanocrystals of the same mass is observed (36% increase at 1 atm & 25 °C), along with fast kinetics (0.5 wt% hydrogen absorption in 5 s). A new mechanism for hydrogen storage involving the dual catalytic role of Pd is established.