Feasibility study of large-scale mass customization 3D printing framework system with a case study on Nanjing Happy Valley East Gate

At present, the development and implementation of digital transformation are the keys to promoting high-quality industry development. The new digital fabrication method of robotic 3D printing is a research area being studied by many to tackle the issue of the declining productivity of traditional construction methods. Although many studies have been done, most of the current 3D printing projects are facing limitations in terms of scale. In order to bridge the gap, this article proposed a mass customization 3D printing framework system for large-scale projects. This article discusses how mass customization is made possible through the joint operation of the FUROBOT software and 3D printing hardware. By taking the east gate of Nanjing Happy Valley Plaza as a case study, the article demonstrates and studies the feasibility of the large-scale mass customization 3D printing framework system.     

齿轮装夹倾斜误差对齿轮精度检测的影响研究

齿轮是机械传动中的重要零部件,制造精度要求高。对齿轮的使用要求也较高,常通过对齿轮精度测设备进行了分类介绍,针对齿轮装夹倾斜产生误差影响齿轮精度检测的问题,基于齿轮装夹定位原理,分析造成齿轮装夹倾斜误差的原因,构建含误差的齿面模型,分析装夹倾斜误差对齿轮偏差精度影响程度,齿轮装夹倾斜角度,通过齿轮检测中心对齿轮倾斜角度的偏差指标进行检测,可得出装夹倾斜误差对齿轮检测精度影响较大,还需进一步完善了齿轮装夹工艺理论。     

用于0.4 kV微电网的四桥臂APF改进型控制策略研究

采用无谐波检测控制原理,提出一种基于多内模原理的四桥臂APF改进型控制策略。首先通过等量代换直接将网侧电流、直流母线电压作为状态变量,建立四桥臂APF在αβγ静止坐标系下的数学模型。然后,针对应用于0.4 kV微电网的四桥臂APF的特殊要求:功率波动频繁、动态响应速度快,在αβγ静止坐标系下采用所提出的四桥臂APF改进型控制策略,即由比例积分PI、矢量谐振VR、重复控制RC构成的多内模复合控制器作为四桥臂APF的电流环控制器,使得四桥臂APF具有动态响应速度快、稳态精度高、计算量小的特点,为0.4 kV微电网的优质电能提供保障。最后通过仿真和实验验证所提控制策略的可行性。     

MC型埋刮板输送机的改进设计

针对原MC型埋刮板输送机在生产中出现的运转不稳定等问题,对刮板输送机机体的下料装置、刮爪形式、防粘装置进行了改进设计,并进行了生产验证。结果表明:改进后的刮板输送机运行平稳可靠、性能稳定,杜绝了跳链、断链等现象的发生,刮板输送机运载电流由20 A降到18 A,保证了油脂浸出车间的生产安全。     

究竟值几星?钉钉

最近,不少中小学生给《钉钉》打了“一星差评”,这是因为《钉钉》为学生们提供了一个在线学习渠道。而对于“一星差评”,《钉钉》也识趣地“求饶”。但摒除偏见,《钉钉》究竟能值几星?一份完整的线上协同方案,一场全社会的云办公实验作为阿里巴巴旗下的优质产品,《钉钉》本身是一款专为企业打造的工作沟通、协同、智能移动办公平台,它为企业提供了安全高效的即时通讯解决方案,并且为企业量身定制免费OA办公系统,大幅提高了工作效率.     

Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.     

Diporphyrin tweezer for multichannel spectroscopic analysis of enantiomeric excess

Chiral 1,1’-binaphthyl-linked diporphyrin ‘tweezers’ (R)-1/(S)-1 and the corresponding zinc(II) complexes (R)-2/(S)-2 were prepared as chiral host molecules, and their utility for chiral analyses (especially enantiomeric excess (ee) determinations) were evaluated. Tris(1-n-dodecyl)porphyrins were used for the first time as the interacting units. Host capabilities of the diporphyrin tweezers were investigated by titrations with (R,R)- and (S,S)-cyclohexane-1,2-diamine (CHDA). The host molecules could be used as multichannel probes of ee by using UV-vis, circular dichroism (CD), fluorescence emission and ¹H nuclear magnetic resonance (¹H-NMR) methods. Chiral configurations could also be differentiated using CD or ¹H-NMR spectroscopy. All three optical techniques give good resolution of ee with reasonable sensitivity considering the low concentrations used (ca. 10⁻⁶ mol·L⁻¹). The ee determination of CHDA enantiomers using NMR spectroscopy is also possible because of the reasonably well separated resonances in the case of (R,R)- and (S,S)-CHDA. Non-metallated (R)-1/(S)-1 hosts could not be used to detect chiral information in a strongly acidic chiral guest. This work demonstrates the utility of 1,1’-binapthyl-linked chiral hosts for chiral analysis of ditopically interacting enantiomers.     

静水位止浆垫预注浆技术在立井掘进中的应用

望云煤矿回风立井掘进穿越K5灰岩含水层时,涌水量突增至75 m~3/h左右,导致施工困难。为保证后续施工安全,采用工作面预注浆方法来封堵涌水。因该段围岩破碎,采用静水位止浆垫预注浆技术,对破碎围岩加固堵水,取得较好效果。     

Nickel phosphonate MOF as efficient water splitting photocatalyst

A novel microporous two-dimensional(2D)Ni-based phosphonate metal-organic framework(MOF;denoted as IEF-13)has been successfully synthesized by a simple and green hydrothermal method and fully characterized using a combination of experimental and computational techniques.Structure resolution by single-crystal X-ray diffraction reveals that IEF-13 crystallizes in the triclinic space group Pi having bi-octahedra nickel nodes and a photo/electroactive tritopic phosphonate ligand.Remarkably,this material exhibits coordinatively unsaturated nickel(II)sites,free-P0₃H₂and-P0₃H acidic groups,a C0₂accessible microporosity,and an exceptional thermal and chemical stability.Further,its in-deep optoelectronic characterization evidences a photoresponse suitable for photocatalysis.In this sense,the photocatalytic activity for challenging H₂generation and overall water splitting in absence of any co-catalyst using UV-Vis irradiation and simulated sunlight has been evaluated,constituting the first report for a phosphonate-MOF photocatalyst.IEF-13 is able to produce up to 2,200 fimol of H₂per gram using methanol as sacrificial agent,exhibiting stability,maintaining its crystal structure and allowing its recycling.Even more,170μmol of H₂per gram were produced using IEF-13 as photocatalyst in the absence of any co-catalyst for the overall water splitting,being this reaction limited by the 0₂reduction.The present work opens new avenues for further optimization of the photocatalytic activity in this type of multifunctional materials.