全文获取类型
收费全文 | 10784篇 |
免费 | 863篇 |
国内免费 | 423篇 |
学科分类
工业技术 | 12070篇 |
出版年
2024年 | 35篇 |
2023年 | 158篇 |
2022年 | 249篇 |
2021年 | 385篇 |
2020年 | 329篇 |
2019年 | 306篇 |
2018年 | 309篇 |
2017年 | 310篇 |
2016年 | 297篇 |
2015年 | 423篇 |
2014年 | 506篇 |
2013年 | 688篇 |
2012年 | 633篇 |
2011年 | 704篇 |
2010年 | 579篇 |
2009年 | 606篇 |
2008年 | 527篇 |
2007年 | 515篇 |
2006年 | 481篇 |
2005年 | 442篇 |
2004年 | 294篇 |
2003年 | 292篇 |
2002年 | 283篇 |
2001年 | 286篇 |
2000年 | 234篇 |
1999年 | 281篇 |
1998年 | 286篇 |
1997年 | 241篇 |
1996年 | 192篇 |
1995年 | 173篇 |
1994年 | 157篇 |
1993年 | 111篇 |
1992年 | 94篇 |
1991年 | 85篇 |
1990年 | 67篇 |
1989年 | 68篇 |
1988年 | 62篇 |
1987年 | 42篇 |
1986年 | 36篇 |
1985年 | 39篇 |
1984年 | 29篇 |
1983年 | 19篇 |
1982年 | 36篇 |
1981年 | 26篇 |
1980年 | 17篇 |
1979年 | 14篇 |
1977年 | 20篇 |
1976年 | 19篇 |
1974年 | 19篇 |
1973年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 343 毫秒
1.
Sumeng Wei Yining Xu Baohua Kong Meijuan Wang Jingming Zhang Qian Liu Yuling Yang 《International Journal of Food Science & Technology》2022,57(8):5024-5035
The present work was conducted to illustrate the mechanism of gel formation of myofibrillar proteins (MPs) under different microwave heating times. The results showed that the denaturation enthalpy (ΔH) of the MPs significantly decreased when the heating time increased from 3 to 9 s and then completely disappeared as the heating time progressed, indicating that the MPs gradually denatured and subsequently aggregated with increasing heating time, which was further verified by the changes in the secondary structure, electrophoretic bands, and gel properties (e.g., water holding capacity and textural profiles) of the MPs. Microstructural images indicated that the MP gel formed under 12 s had the most compact network, indicating that extended microwave heating time could induce quality deterioration of MP gels. Moreover, the hydrophobic forces, electrostatic forces, and disulphide bonds of the MPs gradually intensified with increasing microwave heating time, suggesting that both non-covalent and covalent bonds could promote molecular denaturation and subsequent aggregation of MPs. In addition, correlation analysis revealed that the changes in the molecular conformation of MPs induced by different microwave heating times could effectively regulate the formation of MP gels and their related properties. 相似文献
2.
3.
4.
5.
Sumeng Wei Yuling Yang Xiao Feng Shanshan Li Lei Zhou Jingyu Wang Xiaozhi Tang 《International Journal of Food Science & Technology》2020,55(7):2691-2699
Structures and properties of myofibrillar protein gel prepared at different power (300–800 W) were evaluated. Amino acid analysis demonstrated that changes in microwave power did not alter primary structure of gel. However, an increase in microwave power could change higher structures of gel. As microwave power increased, α-helix content decreased and β-sheet content increased. Increased microwave power probably facilitated protein to unfold and expose the internal groups, causing surface hydrophobicity and the formation of disulphide bonds were enhanced, which indicated changes in tertiary and quaternary structures of protein. At 500 W, gel had the best ultrastructure where surface morphology, springiness and water holding capacity reached the optimum. Our findings suggested that microwave at an appropriate power (500 W) could change higher structures of myofibrillar protein gel to achieve desired processing and quality protein gel characteristics. 相似文献
6.
8.
Wei-Cheng Tang Yi-Che Su Yun-Shan Huang Ya-Tin Yu Hsin-Lung Chen I-Ming Chu 《应用聚合物科学杂志》2019,136(39):48003
While perfluoroalkyl acids (PFAAs), also known as C8s, are used extensively in textile repellent coatings, concerns have arisen for their carcinogenicity and hazardous effects on the environment. In this study, a novel water-based, nonfluoro, and nanobrush textile repelling agent was prepared by conventional sol–gel chemistry using amorphous fumed silica and n-octyltriethoxysilane as the starting materials. Minimal interaction between the designed repelling agent and marketed water-based resins was confirmed using linear viscosity region (LVR) analysis and asymmetric-flow field-flow fractionation (AF4), suggesting the self-stratification potential of the repelling agent. More specifically, the repelling agent exhibited excellent compatibility and self-stratifying ability with a force-emulsified acrylic-based resin, affording a water contact angle of 104.3° when incorporated at 7% solid content. Performance tests carried out on thermoplastic polyurethane (TPU) revealed excellent adhesion (100/100) of a final formulation, and a significant increase in water contact angle from 80.1° to 103.8° after treatment. In addition, the fouling area after the removal of a submerged sample from a mixture of slurry, polymer, and oil decreased from 48 to 1% when the repelling agent was added. Moreover, the sludge-fouling property remained unchanged after 1000 cycles of abrasion. These findings demonstrate the potential of the described nonfluoro, nanobrush repelling agent as an environmentally safe alternative for use with commercial resins, in turn realizing a fully water-based hydrophobic coating. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48003. 相似文献
9.
Chen Yonghong Chu Zhaorong Wei Yijun Liu Xingqin Meng Guangyao 《中国稀土学报(英文版)》2006,24(3):301-301
Pr0.6-x NdxCa0.4 FeO3-δ ( x = 0.0, 0.2, 0.3, 0.4, 0.5, 0.6) were synthesized using Pechini method. A number of studies were conducted concerning composition, specific area, crystalline structure and microstructure of the samples by means of FT-IR, BET, XRD TG-DTA and SEM. The results show that all the samples with different doping amounts of Pr^3+ and Nd^3+ on A-site are fine dispersed, and mean particle size less than 100 nm. The powders have good sinterability, and the relative density is 95% after sintered at 1200 ℃ for 2 h. It is found that all specimens are entirely single phase solid solutions with orthorhombic perovskite structure, the stable perovskitetype phase is formed completely after calcination at 900 ℃. 相似文献
10.
介绍了循环伏安法的产生背景、原理。应用该技术可以快速、方便地对润滑油中抗氧剂、总酸(碱)值进行测定,并且可以对不同厂家润滑油的抗氧剂包进行区别。该技术还可以有效地评价润滑油的使用寿命和设备工作状况。 相似文献