Bench-scale tests to determine mechanisms of charge generation due to particle-particle and particle-wall contact in binary systems of fine and coarse particles

Bench-scale methods were utilized to determine changes in electrostatic charges and their mechanisms for various coarse and fine particles as they came into contact with each other and/or their containing vessel walls. Techniques included shaking tests and particle-copper plate contacting experiments. Electrostatic behaviour of coarse particles (glass beads and polyethylene) and fine particles (Larostat 519, glass beads and silver-coated glass beads) were investigated. Shaking tests resulted in charge separation in which the fine particles acquired significant positive charges, opposite to those carried by the large particles. In copper-plate contacting tests, charge transfer occurred between the fines and the copper plate with fines carrying away almost all of the initial charges on the plate followed by further charge separation. Charge separation was found to be the dominant charging mechanism between the coarse particle and copper plate, with the particles becoming negatively charged.     

Immobilization of Metalloporphyrin on Functionalized MCM-48 Nanoporous Silica as a Catalyst in Oxidation of Cyclohexene: The Effects of Nanoporous Structure of MCM-48 on Its Catalytic Efficiency

MCM-48 nanoporous silica were prepared by the sol–gel method and functionalized by pyridine using a silane agent. With the aid of pyridines on the surface, the nanoporous material was used as a support for immobilization of metalloporphyrin. The formation of this material was confirmed by infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy, inductively coupled plasma atomic emission spectroscopy analysis and specific surface area measurement. The application of this metalloporphyrin-immobilized MCM-48 was investigated as a heterogeneous catalyst in cyclohexene oxidation. Various parameters such as solvent and time were optimized. Also the effect of nanoporous structure on the efficiency of the catalyst was investigated by comparing the results with the same composite using nonporous silica (SiO₂). The result showed that the MCM-48 immobilized metalloporphyrin is a better catalyst for cyclohexene oxidation, which can be attributed to its nanoporous structure. The nanoporous structure increases the surface area of MCM-48 and leads to more metalloporphyrin immobilization.     

Evaluation of fiber optic sensors for remote health monitoring of bridge structures

Health monitoring of civil infrastructure systems has recently emerged as a powerful tool for condition assessment of structural performance. With the widespread use of modern telecommunication technologies, structures could be monitored periodically from a central station located several miles away from the field. Sensors are placed at several critical locations along the structure, and send structural information to the central station. This remote capability allows immediate damage detection, so that necessary actions that ensure public safety are taken. The goal of this research work is to evaluate the use of Fiber Optic sensing technology as a tool for structural health monitoring. To perform this task, a case study involving installation of Fiber Optic Sensors on a selected bridge structure during its construction phase was conducted. The bridge is located in the state of Florida, USA and is considered the first smart structure in this state. Static and Dynamic testing of the bridge were performed using loaded SU4 trucks. A 3-dimensional analytical finite element model of the bridge was developed and its results were compared to the test data. The study confirmed the accuracy of the sensors in estimating the bridge behavior under heavy truck loads. In addition, the sensors were connected to a data acquisition system permanently installed on-site. The acquisition system could be accessed through remote communication, which permits the evaluation of the bridge behavior under live traffic loads. Currently, live structural data under traffic loading is being transmitted continuously to the central maintenance office. The study revealed that the proposed health monitoring technology will enable practical, cost-effective, and reliable maintenance of bridge structures.     

Type I Interferon α/β Receptor-Mediated Signaling Negatively Regulates Antiviral Cytokine Responses in Murine Bone-Marrow-Derived Mast Cells and Protects the Cells from Virus-Induced Cell Death

Mast cells (MCs) are critical for initiating inflammatory responses to pathogens including viruses. Type I interferons (IFNs) that exert their antiviral functions by interacting with the type I IFN receptor (IFNAR) play a central role in host cellular responses to viruses. Given that virus-induced excessive toxic inflammatory responses are associated with aberrant IFNAR signaling and considering MCs are an early source of inflammatory cytokines during viral infections, we sought to determine whether IFNAR signaling plays a role in antiviral cytokine responses of MCs. IFNAR-intact, IFNAR-blocked, and IFNAR-knockout (IFNAR^−/−) bone-marrow-derived MCs (BMMCs) were treated in vitro with a recombinant vesicular stomatitis virus (rVSVΔm51) to assess cytokine production by these cells. All groups of MCs produced the cytokines interleukin-6 and tumor necrosis factor-α in response to rVSVΔm51. However, production of the cytokines was lowest in IFNAR-intact cells as compared with IFNAR^−/− or IFNAR-blocked cells at 20 h post-stimulation. Surprisingly, rVSVΔm51 was capable of infecting BMMCs, but functional IFNAR signaling was able to protect these cells from virus-induced death. This study showed that BMMCs produced pro-inflammatory cytokines in response to rVSVΔm51 and that IFNAR signaling was required to down-modulate these responses and protect the cells from dying from viral infection.     

Simulation of a calcium looping CO2 capture process for pressurized fluidized bed combustion

The Canadian regulations on carbon dioxide emissions from power plants aim to lower the emissions from coal-fired units down to those of natural gas combined cycle (NGCC) units. Since coal is significantly more carbon intensive than natural gas, coal-fired plants must operate at higher net efficiencies and implement carbon capture to meet the new regulations. Calcium looping (CaL) is a promising post-combustion carbon capture (PCC) technology that, unlike other capture processes, generates additional power. By capturing carbon dioxide at elevated temperatures, the energy penalty that carbon capture technologies inherently impose on power plant efficiencies is significantly reduced. In this work, the CO₂ capture performance of a calcium-based sorbent is determined via thermogravimetric analysis under relatively high carbonation and low calcination temperatures. The results are used in an aspenONE™ simulation of a CaL process applied to a pressurized fluidized bed combustion (PFBC) system at thermodynamic equilibrium. The combustion of both natural gas and coal are considered for sorbent calcination in the CaL process. A sensitivity analysis on several process parameters, including sorbent feed rate and carbonator operating pressure, is undertaken. The energy penalty associated with the capture process ranges from 6.8–11.8 percentage points depending on fuel selection and operating conditions. The use of natural gas results in lower energy penalties and solids circulation rates, while operating the carbonator at 202 kPa(a) results in the lowest penalties and drops the solids circulations rates to below 1000 kg/s.     

Experimental analysis of the unit cell approach for two-phase flow dynamics in curved flow channels

Flow behavior of gas–liquid mixtures in thin channels has become increasingly important as a result of miniaturization of fluid and thermal systems. The present empirical study investigates the use of the unit cell or periodic boundary approach commonly used in two-phase flows. This work examines the flow patterns formed in small tube diameter (<3 mm) and curved geometry flow systems for air–water mixtures at standard conditions. Liquid and gas superficial velocities were varied from 0.1 to 7.0 (～±0.01) m/s and 0.03 to 14 (～±0.2) m/s for air and water respectively to determine the flow pattern formed in three geometries and dispersed bubble, plug, slug and annular flow patterns are reported using high-frame rate videography. Flow patterns formed were plotted on the generalized two-phase flow pattern map to interpret the effect of channel size and curvature on the flow regime boundaries. Relative to a straight a channel, it is shown that a ‘C shaped’ channel that causes a directional change in the flow induces chaotic advection and increases phase interaction to enhance gas bubble or liquid slug break-up thus altering the boundaries between the dispersed bubble and plug/slug flow regimes as well as between the annular and plug/slug flow regimes.     

Synthesis of ZnFe2O4 Nanoparticles Confined Within Nanoporous Silica Using Trinuclear Oxo-centered Complex: Inorganic Complexes as a Precursor for the Preparation of Magnetic Nanoporous Silica

MCM-48 Nanoporous silica (Mobil Composition of Matter, #48) was synthesized and functionalized by pyridine groups. The formation of this functionalized nanoporous silica was confirmed by elemental analysis, low angle x-ray powder diffraction and N₂ adsorption. The trinuclear oxo-centered Fe₂Zn(μ₃-O)(CF₃COO)₆(H₂O)₃ cluster was synthesized and immobilized inside the pyridine functionalized MCM-48 pores. The immobilization of this cluster was confirmed by IR spectroscopy and flame atomic adsorption spectroscopy. Fe₂ZnO₄ nanoparticles were confined within the nanoporous silica pores by thermolysis of the immobilized Fe₂Zn(μ₃-O)(CF₃COO)₆(H₂O)₃ cluster and were characterized by high angle X-ray powder diffraction and high resolution transmission electron microscopy. This method is suitable for the one-pot preparation of Fe₂ZnO₄ confined nanoporous silica.