粉煤灰基多孔陶瓷过滤材料的制备和性能

以粉煤灰为骨料,采用添加造孔剂法制备粉煤灰基多孔陶瓷过滤材料,研究了造孔剂用量和烧结温度对其性能的影响.通过压汞仪、X射线衍射仪和场发射扫描电子显微镜等分析测试技术对试样进行了性能表征.结果表明:随着造孔剂用量的增加,显气孔率和吸水率升高,抗弯强度和密度下降.提高烧结温度可以有效提高抗弯强度,而不影响材料的主要物相组成;当烧结温度大于1 175℃时,显气孔率和透气度显著下降.造孔剂用量为35%,烧结温度为1 175℃时,可制得抗弯强度大、气孔发达及高比表面积的多孔陶瓷过滤材料.     

两阶段控制冷却工艺对含钼X80抗大变形管线钢组织与性能的影响

采用TMCP热轧及轧后两阶段控制冷却技术,在试验室制备了含Mo成分的X80级抗大变形管线钢,并利用扫描电镜和透射电镜等分析方法研究了不同冷却条件对组织与性能的影响.结果表明,采用两阶段控制冷却工艺的含Mo成分X80抗大变形管线钢为铁素体-贝氏体双相组织;随加速冷却中开冷温度降低,组织中铁素体含量增加,试样强度降低,屈强比降低,均匀伸长率提高;随加速冷却中终冷温度降低,贝氏体中M/A含量减少,尺寸更细小,分布更分散,试样强度变化不大但均匀伸长率显著提升.分析表明,当铁素体含量一定时,均匀伸长率与贝氏体中M/A密切相关,细小且均匀分布的M/A可提高加工硬化速率,推迟颈缩发生,使均匀伸长率升高.当加速冷却中开冷温度为690℃、终冷温度为450℃时,组织中铁素体的体积分数约为23%、晶粒尺寸约为5μm,M/A岛尺寸约为1μm,组织均匀性良好,试样得到最优的强度塑性匹配.     

加热温度对TRIP钢连续冷却转变曲线及室温组织的影响

采用膨胀法在DIL805热膨胀仪上测定了不同加热温度下实验钢的连续冷却转变(CCT)曲线,通过光学显微镜和扫描电镜分析不同加热温度对CCT曲线和冷却试样显微组织的影响.结果表明:当加热温度由完全奥氏体化温度降低到两相区内较高温度时,CCT曲线中铁素体转变区左移;当加热温度处在两相区范围内时,随着加热温度的降低,铁素体转变被推迟,使得CCT曲线右移;新生铁素体外延生长方式和奥氏体中碳富集程度的差异是导致上述变迁的主要因素.     

Effect of TRT process on GFA, mechanical properties and microstructure of Zr-based bulk metallic glass

The effect of yttrium addition on the glass-forming ability(GFA) and mechanical properties of the Zr-based (Zr_(0.525)Al_(0.1)Ti_(0.05)Cu_(0.179)Ni_(0.146))_(100-x)Y_x and(Zr_(0.55)Al_(0.15)Ni_(0.1)Cu_(0.2))_(100-x)Y_x(x=0,0.2,0.4 0.6,1,2) alloys was studied.Micro-alloying of 0.6%yttrium enhances the room temperature ductility as well as the GFA of the Zr-based alloys.The mechanism of enhancing the GFA and room temperature ductility was analyzed.It is indicated that proper yttrium addition stabilizes the...     

Deformation heterogeneity of Ti under cryogenic channel-die compression

Commercial purity Ti was subjected to channel die compression in liquid nitrogen for the purpose of studying its deformation characteristics from the viewpoint of the grain refinement induced by severe plastic deformation.Deformed specimens showed microstructural heterogeneity in that the initial blocky grains of about 50 urn in size turned into a mixture of the easily deforming soft grains and the hard grains revealing local concentration of dislocations and deformation twins.Using electron back scatter...     

Preparation and microstructure of CuO-CoO-MnO/SiO_2 nanocomposite aerogels and xerogels as catalyst carriers

CuO-CoO-MnO/SiO_2 nanocomposite aerogels and xerogels were prepared using tetraethyl orthosilicate(TEOS) as Si source,and aqueous solution of Cu,Co and Mn acetates as the precursor via sol-gel process,CO_2 supercritical drying(SCD) technique or ambient pressure drying technique.The microstructure of the CuO-CoO-MnO/SiO_2 nanocomposite aerogels and xerogels were characterized by field emission scanning electron microscopy(FE-SEM),transmission electron microscopy(TEM) and X-ray diffraction(XRD).The specifi...     

Deformation heterogeneity of Ti under cryogenic channel-die compression

Commercial purity Ti was subjected to channel die compression in liquid nitrogen for the purpose of studying its deformation characteristics from the viewpoint of the grain refinement induced by seve re plastic deformati on. Deformed specimens showed microstructural heterogeneity in that the initial blocky grains of about 50 μm in size turned into a mixture of the easily deforming soft grains and the hard grains revealing local concentration of dislocati ons and deformation twins. Using electron back scattered diffraction analysis the in-grain misorientation-axis distribution was studied, from which it was found that the deformation heterogeneity resulted from the anisotropy of individual grains with respect to the compression die: while the soft grains were those oriented favorably for the prism < a> slip, the hard ones were oriented for non-prism slips and deformation twinning. The difference in the response of individual grains, therefore, led to a remarkable effect of the crystal texture of specimens on the maximum strain that can be imposed on specimens without cracking. Based on the present results, a way to achieve expedient grain refinement through the cryogenic plane-strain compression was suggested.     

Al-12.7Si-0.7Mg合金交流TIG焊接头组织与性能

采用进口ER4043和ER4047作为填充焊丝对Al-12.7Si-0.7Mg合金热挤压板材实施交流TIG直缝对焊.利用金相观察、显微硬度测定及拉伸性能测试等方法研究了焊接接头的显微组织与力学性能.结果表明:在所选的焊接工艺参数条件下,交流TIG焊可以获得焊缝质量良好的焊接接头;焊缝区(WZ)是明显的熔融金属激冷形成的铸态组织,热影响区(HAZ)Si颗粒有聚集长大的趋势;接头显微硬度分布显示硬度在焊缝区达到最高,在熔合区急剧下降,在热影响区达到最低.两种焊丝焊接接头抗拉强度都达到基材的90%以上.     

真空轧制不锈钢复合板的组织和性能

采用真空轧制法对6mm厚的奥氏体不锈钢板和50mm厚的碳钢板复合.在高真空、高温和大轧制力的共同作用下,界面实现了牢固的冶金结合并且最终得到了高质量的不锈钢复合板.研究发现界面无开裂和氧化层,仅在界面附近分布少量细小弥散的Si-Mn氧化物颗粒.通过能谱发现不锈钢侧的Cr和Ni向碳钢迁移,在界面形成一薄层富Cr,Ni层,导致复合层硬度升高;碳钢中的C向不锈钢侧迁移导致出现脱碳区,且该区硬度最低.界面的剪切强度达467MPa.     

6061合金电磁半连续铸锭与二次加热组织研究

用电磁半连续铸造技术制备6061合金半固态坯料,并在不同的保温温度和保温时间下进行二次加热实验,观察铸锭及二次加热坯料的微观组织,研究保温温度和保温时间对二次加热淬火组织的影响.结果表明:6061合金可以通过电磁半连续铸造获得具有细小、均匀、非枝晶组织的铸锭;二次加热过程中,随着保温温度的升高,组织转变速度加快;保温温度过高,淬火组织粗大,对成形件性能不利;随着保温时间的增加,初生α-Al不断球化,淬火组织也越圆整,但晶粒长大明显;在610~630℃下保温10~15 min,所得淬火组织均匀,晶粒细小,是理想的成形组织.