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991.
Materials Science - We solve the plane problem of the theory of elasticity for a circular disk weakened by an arbitrarily located internal radial crack subjected to the action of a model contact... 相似文献
992.
Alan Pasha Tabatabai Daniel S. Seara Joseph Tibbs Vikrant Yadav Ian Linsmeier Michael P. Murrell 《Advanced functional materials》2021,31(10):2006745
Unlike nearly all engineered materials which contain bonds that weaken under load, biological materials contain “catch” bonds which are reinforced under load. Consequently, materials, such as the cell cytoskeleton, can adapt their mechanical properties in response to their state of internal, non-equilibrium (active) stress. However, how large-scale material properties vary with the distance from equilibrium is unknown, as are the relative roles of active stress and binding kinetics in establishing this distance. Through course-grained molecular dynamics simulations, the effect of breaking of detailed balance by catch bonds on the accumulation and dissipation of energy within a model of the actomyosin cytoskeleton is explored. It is found that the extent to which detailed balance is broken uniquely determines a large-scale fluid-solid transition with characteristic time-reversal symmetries. The transition depends critically on the strength of the catch bond, suggesting that active stress is necessary but insufficient to mount an adaptive mechanical response. 相似文献
993.
Programming and Computer Software - This paper presents new verification techniques that target to prove multimodel compliance in terms of individual trace semantics. As compared to traditional... 相似文献
994.
Gokhan Kilic Erkan Ilik Shams A.M. Issa Bashar Issa M.S. Al-Buriahi U. Gokhan Issever Hesham M.H. Zakaly H.O. Tekin 《Ceramics International》2021,47(13):18517-18531
Different samples of xTeO2.(25-y)B2O3.zV2O5.yYb2O3 (or TBVY) new glass material were synthesized by the classical melt-quenching method. Structural, optical, physical, and thermal analyses of the synthesized glasses were performed in addition to Monte Carlo simulation to test radiation shielding properties. The results showed that increasing ratios of Yb2O3 (y = 0.0, 0.5, 1.0, and 1.5 mol%) produced monotonic density values of the synthesized glasses ranging from 4.70058 g cm?3 to 5.01038 g cm?3. XRD and FTIR analyses were used to confirm the glass structure of all samples. Optical transmittance and absorption parameters varied almost monotonically with increasing ratios of Yb2O3 indicating the ability to predict and control these properties using Yb2O3 additive. Furthermore, simulated radiation interaction parameters, such as attenuation coefficients and half-value layer, exhibited well-behaved dependence on the concentration ratio of the Yb2O3 additive. This approach to glass material synthesis demonstrate the useful synergetic effect of combining structural, optical, and radiation characteristics. 相似文献
995.
D.G. Krotkevich E.B. Kashkarov M.S. Syrtanov T.L. Murashkina A.M. Lider S. Schmiedeke N. Travitzky 《Ceramics International》2021,47(9):12221-12227
The paper describes the structure and properties of preceramic paper-derived Ti3Al(Si)C2-based composites fabricated by spark plasma sintering. The effect of sintering temperature and pressure on microstructure and mechanical properties of the composites was studied. The microstructure and phase composition were analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. It was found that at 1150 °C the sintering of materials with the MAX-phase content above 84 vol% leads to nearly dense composites. The partial decomposition of the Ti3Al(Si)C2 phase becomes stronger with the temperature increase from 1150 to 1350 °C. In this case, composite materials with more than 20 vol% of TiC were obtained. The paper-derived Ti3Al(Si)C2-based composites with the flexural strength > 900 MPa and fracture toughness of >5 MPa m1/2 were sintered at 1150 °C. The high values of flexural strength were attributed to fine microstructure and strengthening effect by secondary TiC and Al2O3 phases. The flexural strength and fracture toughness decrease with increase of the sintering temperature that is caused by phase composition and porosity of the composites. The hardness of composites increases from ~9.7 GPa (at 1150 °C) to ~11.2 GPa (at 1350 °C) due to higher content of TiC and Al2O3 phases. 相似文献
996.
Jessica H. Sathissarat Lianrui Chu Robert Danso H. Ralph Rawls Kyumin Whang 《应用聚合物科学杂志》2021,138(31):50773
This research continued the development of a difunctional Oxirane and multifunctional Acrylate interpenetrating polymer network composite System (OASys) with antimicrobial properties. The effects of 4-Isopropyl-4′-methyldiphenyliodonium tetrakis (pentafluorophenyl) borate (Borate), hexamethylene diamine (HMDA) and N,N-dimethyl p-toluidine (DMPT) on OASys (Epalloy 5001:dipentaerythritol hexaacrylate) composite hardness, contact angle, monomer-to-polymer degree of conversion (DoC), mechanical properties, polymerization shrinkage, shrinkage stress, and antimicrobial properties were determined. Bis-GMA:TEGDMA composites were used as the control. OASys composites with 9 wt% Borate and 0.5 wt% DMPT or 1.5 wt% HMDA had comparable hardness, DoC's and polymerization shrinkages to controls, but had lower contact angles and mechanical properties. Additionally, OASys composites with 1.5 wt% HMDA had significantly less polymerization stress than controls and demonstrated significant antibacterial activity against Streptococcus mutans and Lactobacillus casei out to 3 months. With lower shrinkage stress and long-term antimicrobial activity, OASys composites look promising for increasing the clinical lifetime of dental composites, but improvements in mechanical properties are needed. 相似文献
997.
Oguzhan Oguz Nicolas Candau Adrien Demongeot Mehmet Kerem Citak Fatma Nalan Cetin Grégory Stoclet Véronique Michaud Yusuf Z. Menceloglu 《Polymer Engineering and Science》2021,61(4):1028-1040
There is currently considerable interest in developing stiff, strong, tough, and heat resistant poly(lactide) (PLA) based materials with improved melt elasticity in response to the increasing demand for sustainable plastics. However, simultaneous optimization of stiffness, strength, and toughness is a challenge for any material, and commercial PLA is well-known to be inherently brittle and temperature-sensitive and to show poor melt elasticity. In this study, we report that high-shear mixing with cellulose nanocrystals (CNC) leads to significant improvements in the toughness, heat resistance, and melt elasticity of PLA while further enhancing its already outstanding room temperature stiffness and strength. This is evidenced by (i) one-fold increase in the elastic modulus (6.48 GPa), (ii) 43% increase in the tensile strength (87.1 MPa), (iii) one-fold increase in the strain at break (∼6%), (iv) two-fold increase in the impact strength (44.2 kJ/m2), (v) 113-fold increase in the storage modulus at 90°C (787.8 MPa), and (vi) 103-fold increase in the melt elasticity at 190°C and 1 rad/s (∼105 Pa) via the addition of 30 wt% CNC. It is hence possible to produce industrially viable, stiff, strong, tough, and heat resistant green materials with improved melt elasticity through high-shear mixing. 相似文献
998.
Egorov A. F. Savitskaya T. V. Mikhailova P. G. 《Theoretical Foundations of Chemical Engineering》2021,55(2):225-252
Theoretical Foundations of Chemical Engineering - An analytical review of the state of multiproduct chemical plants has been proposed. A comprehensive analysis is made of works of Russian and... 相似文献
999.
Raul D. Rodriguez Sergey Shchadenko Gennadiy Murastov Anna Lipovka Maxim Fatkullin Ilia Petrov Tuan-Hoang Tran Alimzhan Khalelov Muhammad Saqib Nelson E. Villa Vladimir Bogoslovskiy Yan Wang Chang-Gang Hu Alexey Zinovyev Wenbo Sheng Jin-Ju Chen Ihsan Amin Evgeniya Sheremet 《Advanced functional materials》2021,31(17):2008818
Polyethylene terephthalate (PET) is the most widely used polymer in the world. For the first time, the laser-driven integration of aluminum nanoparticles (Al NPs) into PET to realize a laser-induced graphene/Al NPs/polymer composite, which demonstrates excellent toughness and high electrical conductivity with the formation of aluminum carbide into the polymer is shown. The conductive structures show an impressive mechanical resistance against >10000 bending cycles, projectile impact, hammering, abrasion, and structural and chemical stability when in contact with different solvents (ethanol, water, and aqueous electrolytes). Devices including thermal heaters, carbon electrodes for energy storage, electrochemical and bending sensors show this technology's practical application for ultra-robust polymer electronics. This laser-based technology can be extended to integrating other nanomaterials and create hybrid graphene-based structures with excellent properties in a wide range of flexible electronics’ applications. 相似文献
1000.
Eitan Oksenberg Calvin Fai Ivan G. Scheblykin Ernesto Joselevich Eva L. Unger Thomas Unold Charles Hages Aboma Merdasa 《Advanced functional materials》2021,31(22):2010704
Understanding energy transport in metal halide perovskites is essential to effectively guide further optimization of materials and device designs. However, difficulties to disentangle charge carrier diffusion, photon recycling, and photon transport have led to contradicting reports and uncertainty regarding which mechanism dominates. In this study, monocrystalline CsPbBr3 nanowires serve as 1D model systems to help unravel the respective contribution of energy transport processes in metal-halide perovskites. Spatially, temporally, and spectrally resolved photoluminescence (PL) microscopy reveals characteristic signatures of each transport mechanism from which a robust model describing the PL signal accounting for carrier diffusion, photon propagation, and photon recycling is developed. For the investigated CsPbBr3 nanowires, an ambipolar carrier mobility of μ = 35 cm2 V−1 s−1 is determined, and is found that charge carrier diffusion dominates the energy transport process over photon recycling. Moreover, the general applicability of the developed model is demonstrated on different perovskite compounds by applying it to data provided in previous related reports, from which clarity is gained as to why conflicting reports exist. These findings, therefore, serve as a useful tool to assist future studies aimed at characterizing energy transport mechanisms in semiconductor nanowires using PL. 相似文献