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The temporal phases of autoignition and combustion in an HCCI engine have been investigated in both an all-metal engine and a matching optical engine. Gasoline, a primary reference fuel mixture (PRF80), and several representative real-fuel constituents were examined. Only PRF80, which is a two-stage ignition fuel, exhibited a “cool-flame” low-temperature heat-release (LTHR) phase. For all fuels, slow exothermic reactions occurring at intermediate temperatures raised the charge temperature to the hot-ignition point. In addition to the amount of LTHR, differences in this intermediate-temperature heat-release (ITHR) phase affect the fuel ignition quality. Chemiluminescence images of iso-octane show a weak and uniform light emission during this phase. This is followed by the main high-temperature heat-release (HTHR) phase. Finally, a “burnout” phase was observed, with very weak uniform emission and near-zero heat-release rate (HRR). To better understand these combustion phases, chemiluminescence spectroscopy and chemical-kinetic analysis were applied for the single-stage ignition fuel, iso-octane, and the two-stage fuel, PRF80. For both fuels, the spectrum obtained during the ITHR phase was dominated by formaldehyde chemiluminescence. This was similar to the LTHR spectrum of PRF80, but the emission intensity and the temperature were much higher, indicating differences between the ITHR and LTHR phases. Chemical-kinetic modeling clarified the differences and similarities between the LTHR and ITHR phases and the cause of the enhanced ITHR with PRF80. The HTHR spectra for both fuels were dominated by a broad CO continuum with some contribution from bands of HCO, CH, and OH. The modeling showed that the CO+O→CO2+hν reaction responsible for the CO continuum emission tracks the HTHR well, explaining the strong correlation observed experimentally between the total chemiluminescence and HRR during the HTHR phase. It also showed that the CO continuum does not contribute to the ITHR and LTHR chemiluminescence. Bands of H2O and O2 in the red and IR regions were also detected during the HTHR, which the data indicated were most likely due to thermal excitation. The very weak light emission in the “burnout” phase also appeared to be thermal emission from H2O and O2. 相似文献
64.
本文简要介绍了能谱放大器的工作原理,特别是新研制的放大器根据CdZnTe探测器的特点在原有能谱仪的基础上进行的改进和完善,及仪器性能、实际测量结果等.它具有高计数率时比原有放大器分辨率和稳定性都好.本放大器还适用于Si(Li)探测器、正比计数管和闪烁探测器. 相似文献
65.
A.O. Ibhadon G.M. Greenway Y. Yue P. Falaras D. Tsoukleris 《Applied catalysis. B, Environmental》2008,84(3-4):351-355
A porous organic–inorganic hybrid titania foam, prepared from a long chain organic surfactant, hexadecylamine (HDA) and a semiconductor powder was characterized by microscopic and spectroscopic techniques and photocatalytically evaluated for the solution phase decomposition of methyl orange under alkaline conditions. Kinetic data obtained indicate conformity with Langmuir–Hinshelwood kinetic model at the initial stages of the degradation reaction. An attempt was made to study the effect of experimental parameters including catalyst loading and dye concentration on photocatalytic degradation of MO. Results indicate that the rate of reaction is governed by adsorption of azo-dye into the surface of the photocatalyst materials and suggests an optimum catalyst load and dye concentration for the degradation reaction. Light absorption and scattering within the substrate reaction zone and arising from differences in optical properties of catalyst material, made it impossible to interpret entire kinetic data on the basis of a simple Langmuir–Hinshelwood kinetics. However, kinetic data obtained at the initial stages of the reaction suggest conformity with first-order kinetics. The foam promises to be a versatile material in that it can be used for the treatment of low concentrations of pollutants of biological, organic and inorganic origins in water and air. 相似文献
66.
Rutger A. van Santen 《Catalysis Today》1999,50(3-4):511-515
The combined use of quantum chemistry and spectroscopy to provide a basis of microkinetics modelling is discussed. 相似文献
67.
Recent advances and highlights in characterization methods are reviewed for cement minerals, cements and their reaction products. The emphasis is on X-ray and neutron diffraction, and on nuclear magnetic resonance methods, although X-ray absorption and Raman spectroscopies are discussed briefly. 相似文献
68.
W.D. Reinhart T.F. Thornhill L.C. Chhabildas W.G. Breiland J.L. Brown 《International Journal of Impact Engineering》2008
Results from spectral radiance measurements using optical multi-channel analyzer over the visible and near infrared regime provide estimates of temperature from expansion products resulting from shocked materials. Specifically, we have made spectral radiance measurements over the wavelength regime of 300–1500 nm. Experiments conducted on aluminum, cerium, and Composition-B high explosive span a wide regime of E/Ev, where E is the internal energy increase of the shocked material, and Ev, is the specific energy required to vaporize the material. For the materials investigated, the ratio is ∼1, 3 and 5 for aluminum, cerium, and Composition-B, respectively. The basic assumption made to deduce these temperatures is that the debris cloud is radiating as a blackbody with emissivity of one and independent of the wavelength. We are also assuming that the probe is monitoring the debris, which is at a single temperature and that there is no spatial temperature gradient. Temperatures at or above the boiling point are confirmed for aluminum and cerium, while the results for Composition-B provide the time-dependent temperature expansion history for shocked Composition-B over the stress regime of 28–130 GPa. These are the first measurements of temperature obtained from the expansion products from materials that have been shocked to very high pressures. 相似文献
69.
An effect of ZnO concentration at the surface of brass-plated steel cord on the adhesion property between a rubber compound
and a brass-plated steel cord was investigated. Cord composition was determined by an Auger microscope with Ar ion sputtering.
Two different steel cords were prepared; one (cord A) had higher ZnO concentration at the cord surface compared to the other
(cord B). Pull-out force of unaged adhesion sample of cord A was lower than that of cord B. But the adhesion durability of
the humidity-aged adhesion sample of cord A was better than the latter. Rubber coverage of the pull out cord for the unaged
adhesion samples of cord A was poor, indicating insufficient formation of an adhesion layer. Pull-out force of the thermal-aged
adhesion samples decreased with increasing aging time and that of cord A was lower than that of cord B. The enhancement of
rubber coverage during initial aging period could be explained by an additional formation of copper sulfide at the adhesion
interphase and an increase of modulus of rubber compound adjacent to the adhesion layer. With further increases of aging time,
adhesion interphase grew excessively and the physical property of rubber compound deteriorated significantly, such that rubber
coverage of adhesion samples decreased markedly with increasing aging time. 相似文献
70.
S. A. Halsey 《Journal of the Institute of Brewing》1985,91(5):306-312
Both transmission and transflectance near infrared spectroscopy have been evaluated for the rapid analysis of beer components. Results of sufficient accuracy have been obtained for ethanol content and Original Gravity. Application of a first derivative mathematical treatment on the spectral data improved calibration equations. Better accuracy was achieved using the transmission mode compared to that using the transflectance mode. 相似文献