表面吸附对JO-9159炸药感度影响的分子动力学模拟

为研究表面吸附对JO-9159炸药感度的影响,通过Materials Studio软件搭建JO-9159的无定形六组分模型,在COMPASS力场和NPT系综下,对其(001)、(010)和(100)3种晶面的表面吸附进行了周期性分子动力学模拟,基于平衡轨迹对JO-9159的感度进行了研究。结果表明:在295K温度下,吸附后其引发键N-NO_2最大键长(L_(max))较吸附前增大,引发键连双原子作用能(EN-N)和内聚能密度(CED)较吸附前减小,表明吸附后体系感度增大;随着JO-9159炸药表面吸附气体分子数量的增加,L_(max)递增,EN-N递减,CED呈减小趋势,都表明体系感度随着吸附分子数的增加而增大;在195~395K温度内,随着温度的升高,吸附后的JO-9159中N-NO_2的Lmax递增,E_(N-N)呈递减趋势,CED递减,与感度随温度升高而增大的实验事实相一致。     

基于温升常数的电火工品感度可靠性分析

针对电火工品感度可靠度难以直接度量的问题,利用瞬态脉冲试验得到电火工品电压——时间曲线以及温升常数,基于Matlab软件,采用支持向量机算法和数理统计方法,对电火工品感度可靠性进行了分析。结果表明计算结果符合实际,本研究为电火工品感度可靠性的分析提供了新的途径。     

半导体GaN功率开关器件灵敏度测试技术

测试半导体GaN功率开关器件灵敏度对掌握器件性能具有重要意义,提出一种新的半导体GaN功率开关器件灵敏度测试技术。通过分析半导体GaN功率开关器件的导通电阻与击穿电压关系、空穴电流与栅极电流关系掌握功率开关器件击穿机理,在此基础上,测试半导体GaN功率开关器件灵敏度;根据灵敏度测试原理与微频通道衰减值周期检查原理,测量功率开关器件微频信号功率和微频通道衰减值,汇总微频通道衰减值和最后一次开关灵敏时的衰减值,得到半导体GaN功率开关器件灵敏度。实验结果表明：所提测试技术测量半导体GaN功率开关器件灵敏度过程中,平均测试误差为0.03 dB,仅平均花费9.42ms,是一种高效、可靠的半导体GaN功率开关器件灵敏度测试技术。     

Stability parameter analysis of a composite foundation of an oil storage tank in a loess area treated with compaction piles

The research takes the composite foundation of the Lintao oil depot belonging to the Gansu branch of PetroChina treated with compaction piles in the collapsible loess region as the research background. A large number of compaction piles dispersed in the composite foundation are simplified using the equivalent continuum method. Discrete piles arranged in a triangular shape are simplified in the model, where the annular piles and compacted soil are arranged alternately, which can provide new ideas for the three-dimensional calculation mode of composite foundation and greatly improve the convergence and computational efficiency of the finite element model. To more realistically reflect the actual situation, the soil-structure and fluid–structure interactions, the material and the contact nonlinearities are considered, and a large-scale three-dimensional calculation model, which includes the composite foundation, concrete foundation, tank and liquid, is established. A sensitivity analysis is used to analyze the sensitivity of the elastic modulus, internal friction angle and cohesion of the composite foundation. The sensitivity of a single factor is evaluated based on the absolute value of the slope of the result-parameter curve; the relative sensitivity of various parameters is discussed according to the dimensionless sensitivity. The results show that for composite foundation, an increase in the friction angle or the cohesion of the foundation will significantly increase the safety factor. The sensitivity of the friction angle is greater than that of cohesion, and the sensibility of the elasticity modulus on the stability is very small. The results suggest that the accuracy of the mechanical parameter selection should be considered in the research on the stability of composite foundations. Measures to increase the angle of internal friction should be preferentially taken and increasing the cohesion should be considered secondary to improve the stability and safety reserve of composite foundation.     

自然保护区的现实问题与分区模式创新研究

传统封闭式和孤岛式的分区模式使得自然保护区的发展遭遇瓶颈。保护与开发之间的〉中突是目前自然保护区可持续发展的最大障碍。分区是自然保护区管理和经营的有效工具,以生态系统稳定性的弹性机制为理论依据,从栖息地适宜性、生态系统稳定性和生态系统敏感性3个维度构建自然保护区的有机分区方法。基于GIS技术的多标准判断法和生态演替分析法对自然保护区内的土地单元进行生态价值评估和分区,提出“核心区,缓;中区”2大区、“自然环境区／游赏区／生产经营区／科学实验区／管理服务区”5小区的划分方式。旨在通过生态价值的差异性对保护区内土地单元进行划分,从而解决自然保护区内不同利益者之间的矛盾,并且以马头山自然保护区为例对有机分区体系进行实证研究。     

Effect of Drying on Particle Size and Sensitivities of Nano hexahydro-l,3,5-trinitro-l,3,5-triazine

Nano hexahydro-l,3,5-trinitro-l,3,5-triazine （RDX） was prepared using a bi-directional rotation mill and dried under different conditions （liquid, temperature and drying）. It shows that the samples cake seriously and the particles grow up obviously by ordinary drying in different liquids at 70 ℃, which occurs again after vacuum drying. With the increase of temperature, the degrees of caking and aggregation are enhanced. Well dispersed sample maintaining constant particle size is extracted by supercritical drying, especially freeze drying. Furthermore, the me- chanical sensitivities of I-RDX, O-RDX and F-RDX, of which the average sizes are 88.03 μm, 15.32 μm and 0.16 μm, respectively, are evaluated. Compared with I-RDX, the friction, impact and shock sensitivities of O-RDX are slightly lower. However, the friction, impact and shock sensitivities of F-RDX are reduced by 30%, 99.0% and 59.9%, respectively.     

Sensitivity Analysis as a Tool for Estimating Numerical Modeling Results

Modeling of real physical processes by numerical methods is highly time-consuming and requires significant computational capacity. In some cases, tens or even hundreds of hours of high-power computing are needed to virtually model a real process that lasts one second. Processes that take many hours, such as drying, pose an even greater challenge. This problem can be solved in two ways: by using faster computers (such as computing clusters) or by significantly simplifying the modeled process (its geometry, physical phenomena, or the impact of individual factors). For this reason, all methods which speed up or minimize the number of simulations required to achieve the research objective should be analyzed. This article focuses on the latter approach, and it proposes a simple method for predicting the responses of a numerical model (values of any output parameter) to changes in input values (values of any input parameter). This method requires a base model, such as a numerical model which is qualitatively and quantitatively consistent with experimental observations, and a sensitivity analysis. This article discusses the mathematical and logical premises for the discussed model, and it proposes two methods for predicting numerical simulation results. Those methods are illustrated with examples which analyze the behavior of the Eulerian Multiphase Model and describe phase interactions based on Gidaspow's approach. The discussed example relies on data from a series of articles published by the authors in Drying Technology. This article was inspired by the observations made during a time-consuming process of modeling a spouted bed grain dryer, which was described in the above publications. The objective of this study was to discuss the advantages and possibilities created by sensitivity analyses of numerical models and to encourage their practical application.     

Electrochemical synthesis of a novel poly(2,5-dimethoxy aniline) nanorod for ultrasensitive glucose biosensor application

We report for the first time a rapid electrochemical synthesis of one-dimensional poly(2,5-dimethoxyaniline) nanorods (PDMA-NR) in the presence of surfactant. FE-SEM and TEM images confirm the PDMA-NR formation and the average diameter of single rod sizes in the range of ∼200–300 nm. An enzymatic glucose biosensor was fabricated through immobilizing glucose oxidase (GOx) into PDMA-NR matrix. The amperometric current response of PDMA-NR/GOx to glucose is linear in the concentration range between 1 and 10 μM with a detection limit of 0.5 μM (S/N = 3). The PDMA-NR/GOx electrode possesses high sensitivity (5.03 μA/μM), selectivity, stability, and reproducibility toward glucose.     

区域空间规划生态分级保护研究 ——以华蓥山东麓为例

生态分级保护是空间规划中重要支 撑性内容,是全面协调生态保护与开发利用 关系,实现各类空间差异化管控,促进区域 可持续发展的重要途径。本文以华蓥山东麓 为例,通过生态功能重要性和生态敏感性评 价,同时结合景观生态安全格局进行分析, 构建生态保护分级指数模型,按保护程度由 高至低将研究区划分为Ⅰ、Ⅱ、Ⅲ、Ⅳ级。其 中,I级保护区为基本生态控制区,实行严格 的生态保护制度;II级保护区为生态缓冲区, 实行生态修复与城乡建设、产业发展负面清 单管理制度;III级保护区为农业生态区,加 强农业生态环境保护,建立健全绿色生态农 业导向机制;IV级保护区主要为城镇村庄生 态区,加强城乡居民点环境保护,推进人居 环境建设。研究结果可为华蓥山东麓生态修 复保护总体规划提供借鉴,对华蓥山自然保 护区与城镇建设区之间生态过渡地带的精细 化、精准化、差别化管理具有重要意义。     

基于误差预测的机床精度分析与设计

数字化精度分析是当前确保机床设计精度的重要手段。精度建模与精度分析等重要手段主要针对机床几何精度、运动精度及工件表面成形运动精度。对于复杂成形运动机床,目前精度设计标准与工件加工精度之间尚无准确对应关系。为此,提出了基于误差预测的机床精度设计方案,该方案分为两阶段数字化精度分析。第一阶段通过技术系统实现工件到工艺系统各部件精度分配与检测,在规定的精度下达到机床输出精度。第二阶段通过机床系统完成机床输出到机床各组成部件精度分配与检查。文中以YK3610滚齿机为例,详细分析了两系统误差模型及应用方法,并通过试验验证机床的实际切割精度可达5-4-4等级,因此该方法为复杂成形运动机床精度的设计提供了依据。