Critical roles of the rhombohedral-phase inducers in morphotropic NaNbO3-BaTiO3-ABO3 quasi-ternary lead-free piezoelectric ceramics

A morphotropic phase boundary (MPB) between rhombohedral (R) and tetragonal (T) phases was identified in a few (0.9-x)NaNbO₃-0.1BaTiO₃-xABO₃ (x?=?0–0.05) lead-free systems. Critical roles of R-phase inducers were specially evaluated in terms of phase boundary position, microstructure and piezoelectric responses. The results indicate not only the tolerance factor of the ABO₃ additive but also its ferroelectricity and corresponding volume change would influence the formation of phase boundary and further determine dielectric and ferroelectric responses. The piezoelectric coefficient d₃₃ of MPB compositions was compared with theoretically-calculated d_33-cal according to d₃₃?=?2P_r·ε₃₃·Q₃₃, demonstrating that the piezoelectric response of these systems should be determined by combined effects of the phase coexistence, nano-scale domains and particularly enhanced dielectric responses. The largest d₃₃ ～305 pC/N, the highest ε₃₃^T/ε_o ～2815 and the lowest P_r ～14.7 μC/cm² were achieved in the MPB composition with 3.75% SrZrO₃. These experimental results provide a valuable reference for designing new NaNbO₃-based lead-free piezoelectric materials.     

Experimental research on dynamic response of PZT-5H under impact load

In order to improve the stability of PZT-based sensors, the mechanical, dielectric, ferroelectric and piezoelectric properties of PZT-5H under impact load were studied experimentally by using the separated Hopkinson pressure bar (SHPB) with an electrical output measurement device. At the same time, the experimental study on the material properties of PZT-5H before and after the impact was carried out. The effect of impact cracks on the output voltage of PZT-5H was also analyzed. The results show that the dynamic piezoelectric constants of PZT-5H under low stress impact (10–50 MPa) are different from those under quasi-static state, and the empirical relationship between them and the peak stress is obtained through experiments. The dielectric properties of PZT-5H did not change under low stress impact, but micro-cracks occurred in the material and dielectric loss increased at high frequencies. Under short circuit, the residual polarization intensity of PZT-5H decreases sharply due to impact load. While the impact load causes the secondary polarization and the increase of the residual polarization intensity of PZT under open circuit. When the stress is over 45 MPa, the PZT-5H breaks. The formation of cracks causes abnormal discharge voltage and gap discharge.     

Modeling and Analytical Solution of Hybrid Thermopiezoelectric Micro Actuator and Performance Study Under Changing of Different Parameters

Micro actuators are an irreplaceable part of motion control in miniaturized systems and are intended to have a high range of deformation, high accuracy, large force, and quick response. In this article, an analytical model for a hybrid thermopiezoelectric micro actuator is developed in which a double lead-zirconnate-titanate piezoceramic (PZT) beam structure consisting of two arms with different lengths are used. Governing differential equation of motion and electrical field are derived and solved. Out of parametric studies it was observed that, under application of temperature and voltage gradients, the deflection of the actuator shows different trends depending on the geometry of the micro actuator and also type of PZT material.     

压电精密驱动柔性微夹钳设计

为了实现对微纳尺度下物件的精密夹持,建立了柔性微夹钳系统。并对该系统柔性夹钳设计、运动学、动力学和控制方法等进行研究。首先,利用柔性铰链设计方法设计了柔性微夹钳,利用伪刚体法建立了机械的伪刚体模型。接着,以伪刚体模型法建立了系统的运动学模型,即机械放大比和输入刚度等数学模型。然后,利用拉格朗日方法建立了系统的动力学方程,得出系统的自然振动频率。最后,通过ANSYS有限元方法对系统建立的模型进行了仿真分析和验证,此外,利用PID控制算法对微夹钳系统进行实验控制。实验结果表明:跟踪控制结果误差为2.4%;放大比为9.12倍。基本满足微纳尺度下的微夹持工作,其工作精度可达微米级别甚至纳米级别,符合设计要求。     

Thermally stable cellular poly(vinylidene) ferroelectrets: Optimization of CO2 driven inflation process

Electrically charged cellular ferroelectrets can show excellent thermally stable piezoelectric activity and are therefore progressively used in electrochemical transducers. Given that an optimized cellular structure is a key for improving charge density and the associated piezoelectric properties in this material, we investigated the influence of CO₂ inflation treatment using various gas diffusion expansion or inflation procedures on the piezoelectric d₃₃ coefficient and thermal stability of cellular poly(vinylidene) ferroelectrets and compare with the results (partially) obtained by N₂ inflation as reported in our previous study (Jahan, Mighri, Rodrigue, Ajji, J. Appl. Polym. Sci. 2019, 136, 47540). Samples were prepared using the conventional extrusion–stretching–inflation–corona charging method. Maximum d₃₃ coefficient for CO₂-inflated samples is found to be around 30% higher than that of N₂-inflated samples (327 pC/N compared to 251 pC/N) by stepwise pressure application method. The key parameters addressed in the inflation procedures are the changes in sample thickness, morphology, and the void-height distribution in both gas treatments. The ferroelectrets show excellent thermal stability for up to 4 days at 90, 110, and 120 °C in both treatments with a slightly improved performance in CO₂ gas. The higher activation energy of CO₂-inflated samples (0.52 eV) than the N₂-inflated ones (0.43 eV) further confirms the stability data. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47929.     

Dielectric,ferroelectric, and piezoelectric properties of lead-free Ba0.95Ca0.05Ti1-xZrxO3 ceramics

Abstract

Ba_0.95Ca_0.05Ti_1-xZr_xO₃ (BCTZO) ceramics were prepared by a solid state reaction method. The samples were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and X-ray absorption near edge structure (XANES). The ceramics exhibit a pure perovskite structure. The average grain size gradually decreases with increasing Zr concentration. XANES results indicate that the intensities of pre-edge peaks dropped with increasing Zr concentration. The BCTZO ceramic of x?=?0.05 has the optimum electrical properties with the maximum dielectric constant (ε'_m), remanent polarization (2P_r), coercive electric field (2E_c) and piezoelectric charge constant (d₃₃) of 7,244, 12.54 (μC/cm²), 5.29 (kV/cm) and 288 (pC/N), respectively.     

Time and thermal stability improvement of polyethylene ferroelectrets

Ferroelectrets with good piezoelectric coefficients have been produced based on cellular polyethylene (PE) via extrusion film blowing. The quasi-static piezoelectric coefficient (d₃₃) value obtained (935 pC/N) was well above typical values for cellular polypropylene (PP) considered as the workhorse of piezoelectric polymers. Here, a focus was made on increasing the time and thermal stability of cellular PE piezoelectric activity. To do so, specific thermal treatments were applied on the films to improve their microstructure. First, films crystallinity was increased via thermal annealing at 80 °C for 5 min leading to a 32% increase of the initial d₃₃ value as well as its time stability. However, thermal treatment did not give a significant thermal stability improvement because the treated films almost completely lost their piezoelectric activity (96%) at 80 °C. Therefore, the films were treated with orthophosphoric acid resulting in substantial charge stability improvements, especially at higher temperature. Overall, it was possible to increase the continuous service temperature (CST) of PE ferroelectrets from 40 to 80 °C, which is similar to the typical CST of PP. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47646.     

被动湍流控制圆柱驰振能量收集的等效电路研究

为更好的预测驰振压电能量收获机的性能,首先建立了等效电路仿真模型(ECM)并通过实验验证,最大误差不超过10%。采用该方法分析了被动湍流控制(PTC)下圆柱驰振压电能量收集的仿真模型,且该方法可将驰振能量转化系统的质量-弹簧-阻尼(M-C-K)控制方程中各参数用等效电路的电子元件来表示,从而可以分析过往仿真手段所不能解决的直流电路耦合问题。其次,从能量收集效率角度分析了交流-直流等效电路中临界风速(Ucr)随外接载荷的变化规律,及输出电压与功率随不同风速和外界载荷的变化规律。结果表明,交流电路中Ucr随载荷的增大先增大后减小,直流电路中Ucr随载荷的增大逐渐减小。当风速达到Ucr的最大值时,驰振在任一电阻下均会发生。U≥Ucr时,驰振出现锁定现象,输出电压和功率均随着风速的增大而增大。当风速过大时,增长率有减小趋势。输出电压均随着电阻的增大而增大,功率随电阻的增大先增大后减小。相比于交流电路,直流电路的最佳负载由1.1 MΩ提高到2.0 MΩ,同时功率峰值从0.08 mW降低到0.04 mW。     

一种压电半导体纳米线的热电耦合性能研究

采用有限元分析方法,研究了一种n型压电半导体纳米线(氧化锌)的电热耦合性能,分析了外部温度对氧化锌纳米线内部机械场、电场及电流场分布的影响,并讨论了本构方程线性化对电学参数的影响。研究结果表明,温度对氧化锌纳米线的电场、载流子浓度和电流密度影响很大,采用线性本构和非线性本构求得的电场、电子浓度和电流密度最大相差分别为24%,32%和68%,基于非线性本构分析压电半导体的电学性能会引起很大误差。该研究结果可为压电半导体器件利用温度调控电场、电流提供理论依据。     

Wind turbine speed control of a contactless piezoelectric wind energy harvester

ABSTRACT

Wind turbine control is an important task to make the electricity generation secure in terms of energy demand and machine safety. It also yields to control the desired power level and optimized energy because of the assignment of turbine speed. The contactless piezoelectric wind energy harvester (CPWEH) used in this study has three piezoelectric layers located around the shaft with 120 degrees apart and they are buckled by the magnetic force without any physical contact. The superiority of this device is to generate energy for low wind speeds such as 1.5 m/s. However, for high speeds, high total harmonic distortions (THDs) govern the waveforms, thus controlling the turbine speed becomes necessary for optimizing the output power. Encouraged by this, a small low inertia dc generator is coupled with the wind turbine, and the generator terminals are connected to a resistor through a power switch to generate a braking torque that opposes to wind speed direction. By controlling the switch properly, turbine speed is ensured to remain within a certain band, which accordingly prevents the turbine from rotating very fast at damaging wind speeds. Several experiments are performed on the developed CPWEH with/without the presented control scheme which prove the existence of promising performance of our proposal.