改性膨润土在环境保护中的应用

综述了改性膨润在环境修复、环境净化、环境替代功能等环境保护方面的应用研究最新进展，并展望了改性膨润土在环境保护中的应用前景。     

用于深井、高温井泥浆的粘土材料

根据粘土的结构特点，分析了膨润土、海泡石、累托石泥浆在高温条件下的特性，提出了适用于高温泥浆的粘土材料。     

蒙脱石提纯研究进展

总结了蒙脱石的各种提纯方法及其试验原理和提纯分离效果。主要涉及重力选矿、水力分析、絮凝法、离心分离和化学提纯。对电泳法提纯作了简介。研究证实，与蒙脱石粒度相近的方石英和石英微粒等杂质很难去除。氢氧化钠溶蚀法会对蒙脱石、石英和方石英同时产生溶蚀，引入新的物相杂质。     

优质膨润土泥浆在大直径深桩基工程中的应用

为解决在澳门美高梅金殿超濠博彩场及酒店项目桩基工程中大直径深护筒无法回收的难题,笔者在分析港澳地区灌注桩传统工艺缺陷的基础上,采用具有预处理能力的优质膨润土泥浆.施工实践表明,2#配方泥浆能有效的保持桩孔稳定性,桩孔的平均充盈系数为1.0794;改善了钻进泥浆的性能,使泥浆的重复利用率提高到45.33%,泥浆废弃率仅为2.38%;降低了工程成本,减小了对环境的影响.同时,为钻孔灌注桩施工总结了各个阶段泥浆性能标准.     

高压实膨润土热湿力性能测试

本文介绍了高压实样品的制样特点,测试了高压实膨润土样的导热系数,热膨胀系数,对高压实膨润土热湿力特性研究有较大参考价值。     

膨润土的工艺特性及其应用

膨润土作为一种非常有用的非金属矿物原料,广泛地应用于工业、农业和其他各个领域。近年来对膨润土的不民研究和开发,进一步拓宽了其应用领域。本文试图对膨润土的工艺特性及其应用途径和现状作一系统概述。     

南京汤山膨润土矿地质特征,物化性质及矿床成因

通过对南京近郊汤山膨润土矿床的矿区地质、矿床地质特征的分析,阐明了该矿床的成因及其矿石的物化性能。综合研究表明,该矿床是以流纹岩及凝灰岩为成矿原岩,在特定的条件下,经热液蚀变改造而形成的矿床。此矿床之矿石属钙基膨润土,经适当选矿后可用于深加工。     

Research on purification and modification of I/S bentonite

Analyzing raw material's structure and performance of bentonite from Panzhihua in Sichuan, the authors think that it is adequate for agglomerant of iron smelting. According to its composition and property we have researched the purification and modification of I/S bentonite under conditions of different dispersants and sodium agent. XRD test result reveals that the essential minerals of Panzhihua bentonite are I/S mixed-layer ones, and FTIR analysis shows that when adding 1 5% sodium pyrophosphate to the bentonite slurry during purification, the composition of quartz in bentonite decreases to less than 4% and I/S is more than 90%. The optimized modification technic conditions are Na2CO3 (4%) and CMC-Na (3%) as modified agents, the clay and water are 10 vs. 1, and the temperature is 75℃. It is 40 min for stirring time and reacting time is 4 h. Under the conditions we can get the modified I/S bentonite with colloid index more than 500 ml/15 g.     

壳聚糖和PDMDAAC改性膨润土用于处理含油废水的研究

含油废水污染范围广,对人类和生态环境危害大。采用常规方法(如浮选法、絮凝法、电化学法、膜分离法和生物法)处理的除油率不高于91%,成本较高,因此急需开发一种高效低廉的吸附剂。膨润土是一种优良的吸附剂,但用其直接处理含油废水的效果较低。本文选用壳聚糖和PDMDAAC两种有机物作为改性剂,对钠基膨润土改性,使膨润土能有效地处理含油废水。通过实验比较了两种有机改性膨润土处理含油废水的最佳去除条件,探讨了表征对其吸附性能的影响。去油效果结果表明:壳聚糖改性膨润土的除油率可达87.8%,PDMDAAC改性膨润土的除油率可达89.3%,处理所需时间少于15 min;除油效率和处理时间都优于常规方法。吸附性能表征结果显示,两种改性剂均以负载的方式和钠基膨润土颗粒结合,吸附性能良好;相比而言,PDMDAAC改性膨润土的处理效果比壳聚糖改性膨润土更好。PDMDAAC应用于含油废水的处理,具有成本低、效率高、操作简单的特点,在含油废水处理领域具有较好的应用前景。     

Analysis of the FEBEX multi‐barrier system including thermoplasticity of unsaturated bentonite

Deep geological repository involving a multibarrier system constitutes one of the most promising options for isolating high‐level radioactive waste from the human environment. To certify the efficiency of waste isolation, it is essential to understand the behaviour of confining geomaterial under a variety of environmental conditions. To this end, results from a near‐to‐real experiment, the full‐scale engineered barriers in situ experiment, are studied by means of a thermo–hydro–mechanical finite element approach, including a consistent thermoplastic constitutive model for unsaturated soils. Laboratory tests are simulated to calibrate model parameters. The results of the numerical simulations are compared with sensor measurements and show the ability of the model to reproduce the main behavioural features of the system. The influence of the hysteretic and temperature‐dependent retention of water on the mechanical response is exhibited. Finally, those results are interpreted in the light of thermoplasticity of unsaturated soils, which reveals the highly coupled and non‐linear characters of the processes encountered. Copyright © 2011 John Wiley & Sons, Ltd.