Head-to-head polymers: 33. Bromination of cis-1,4-polybutadiene to head-to-head poly(vinyl bromide)

Cis-1,4-polybutadiene (PB) in a 0.5% solution of a solvent mixture of dichloromethane and 1,2-dibromoethane or tetrahydrofuran was quantitatively brominated with elemental bromine at 0°C under careful exclusion of oxygen to head-to-head poly(vinyl bromide). Partially brominated PB has a structure of random or block sequences of butadiene units in the polymer depending on the bromination solvent but shows no stereospecificity in the CHBrCHBr-dyads. Partially brominated PB with block structure showed a microphase-separated morphology over a wide range of composition. Microphase separation is less pronounced for the more random structure of butadiene units. I.r and ¹³C n.m.r. spectroscopy of the partially brominated PB was used to follow the progress of the bromination.     

1000m~3/h空分设备板翅式换热器带水冻堵故障处理

介绍 10 0 0m3 /h空分设备板翅式换热器循环水加杀菌剂产生泡沫 ,引起空冷塔雾沫夹带而严重带水冻堵的故障现象、原因及处理措施 ,并指出运行中的不足。     

自干扰抵消盲空时DS-CDMA信号检测技术

针对传统单用户检测器存在远近效应和性能下界问题,近年来提出的一系列最大SINR准则盲空时RAKE接收机,可以较好地合并期望用户的多径分量,同时抑制多址干扰用户能量.本文对这类接收机进行了进一步的研究,提出了一种自干扰抵消方法,更有效地克服了单用户检测器存在的性能下界以及远近效应问题.仿真结果验证了本文方法的有效性.     

石英砂脱水性能的研究

通过大量试验结果 ,研究了各种粒度范围的石英砂的脱水性能 ,包括沉降特性、过滤性能、极限压缩浓度等 ,为进行此类产品的固液分离提供了重要的参考数据     

CDMA时变色散信道的两级盲辨识算法

本文通过对时变信道的扩展函数在时频域进行正则采样，得到了CDMA时变系统的离散正则模型。针对该模型提出了一种具有较低运算量的两级盲辨识算法。为避免两级算法产生的误差传播效应，文章将理想SIMO模型等效为加性噪声模型来处理。与基展开模型方法相比，该算法具有不需利用观测数据的高阶统计量估计展开基频率的优点。文章通过仿真验证了该算法是可行的。     

含氨废水处理方法的探讨

对催化剂厂含氨废水的处理，提出了多种方法，着重分析了A/O生物法、膜分离法和汽提法，比较后确定采用汽提法处理该废水，建成投产达到预期效果。     

轴快流CO2激光器气体压力控制

激光切割对激光功率模式、功率密度和功率稳定性要求很高,采用轴快流CO2激光器时,控制工作气体压力工作在最佳状态并保持其恒定是激光器输出连续、稳定功率的必要条件和关键技术之一。在深入研究激光器工作原理和影响激光输出功率因素的基础上,采用带积分分离的智能PID控制算法对工作气体压力进行调节。该过程控制算法简单实用,可以有效地提高气体压力控制精度,改善功率控制精度和稳定性,并用实验加以验证。     

涡流管类比逆流换热器方法的研究

结合Scheper，Lewins和Bejan的理论模型，对涡流管类比逆流换热器模型进行了深入地分析，得出了冷流分量对温度分离效应的函数关系式，为了解涡流管机理和实验中强化涡流管温度分离效应提供了理论依据。     

Variability in stepping direction explains the veering behavior of blind walkers.

Walking without vision results in veering, an inability to maintain a straight path that has important consequences for blind pedestrians. In this study, the authors addressed whether the source of veering in the absence of visual and auditory feedback is better attributed to errors in perceptual encoding or undetected motor error. Three experiments had the following results: No significant differences in the shapes of veering trajectories were found between blind and blindfolded participants; accuracy in detecting curved walking paths was not correlated with simple measures of veering behavior; and explicit perceptual cues to initial walking direction did not reduce veering. The authors present a model that accounts for the major characteristics of participants' veering behavior by postulating 3 independent sources of undetected motor error: initial orientation, consistent biases in step direction, and, most important, variable error in individual steps. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Hebbian无导师学习原理的盲均衡：（Ⅱ）非最小相位通道

本文介绍了根据信号码的相互独立性，利用噪声情况下盲信号分离的原理，实现非最小相位通道特性的盲均衡。