电火工品用水电池的研究

采用正交试验法研究了Mg/AgCl,Mg/Cu2Cl2和Mg/MnO2 3类水电池的放电性能，并根据正交试验的结果，对适宜于电火工品的电池组成进行了研究，通过电点火头的点火试验表明，本文给出的3组电池均能较好的使其发火。     

基于WindoWs内核模式的iSCSI启动器设计

介绍了一种基于Windows 2000内核模式的iSCSI启动器设计,通过SCSI小端口驱动实现虚拟磁盘,从文件系统截取I/O请求,然后在操作系统内核根据iSCSI协议处理,并且利用TDI技术将封装好的iSCSI PDU通过TCP网络发送给目标器,从而实现了iSCSI启动器在Windows操作系统中的无缝集成.     

牙科光固化复合树脂材料的性能与展望

牙科光固化复合树脂具有色泽美观,强度高,临床操作方便,粘结固位效果好等优点,在牙科修复领域引起了广泛关注.该复合材料是由树脂基体、无机填料和光引发体系组成的,原料混合后经特定波长的可见光照射即可固化.牙科光固化复合树脂虽然已在临床上得到了应用,但在性能方面仍然存在某些不足之处,所以如何进一步提高其性能成为目前研究的热点之一.该文作者综述了树脂基体、无机填料和光引发剂的研究情况,对光固化复合树脂的力学性能、聚合度、吸水性和溶解性等性能及其影响因素进行了评述,并对今后的研究进行了展望.     

阳离子絮凝剂P(DMC-AM)的合成及其絮凝性能

采用氧化还原剂和偶氮化合物组成的复合引发体系,合成了阳离子絮凝剂 P(DMC-AM)。探讨了反应体系 pH 值、单体浓度、阳离子度、反应时间、烘干温度等因素对产物特性粘数的影响。较佳工艺条件为:反应体系 pH=4.5、单体浓度40%、阳离子度40%、反应时间2.5 h、烘干温度60℃,产物的特性粘数为13.4 dL/g。在污水处理实验中,经其处理过的污泥的透光率、脱水率等指标均与国外同类产品的絮凝效果相当。     

Anionic functional initiators. 1: 3-dimethylaminopropyllithium as an initiator for the synthesis of Bi- and difunctional polybutadienes

Methods are described whereby a series of novel bi- and difunctional (telechelic) high 1,4-microstructure polybutadienes are prepared by use of an anionic functional initiator. This initiator, 3-dimethylaminopropyllithium, has been extensively investigated and methods for its preparation and use in non-polar solvents are described. When utilised in such non-polar solvents the polybutadienes produced are uniquely functionalised, possessing a high 1,4-structure and a low glass transition temperature. Evidence is presented to demonstrate that these reactions are true ‘living’ polymerisations and that quantitative functional termination reactions may be used to yield a wide range of multi-, bi- or difunctional polymers.     

发电机运行中突然进相的原因分析及对策

通过对发电机运行中突然进相的现象、原因进行分析,阐述了进相对机组的影响,并提出了应对、处理措施,取得了较好的效果。     

Exploding Foil Initiator (EFI) Modes of Operation Determined Using Down‐Barrel Flyer Layer Velocity Measurement

Exploding Foil Initiator (EFI) flyer layer velocities measured down the barrel of an EFI are presented. Flyer velocity was shown to be proportional to supply voltage and of a similar order to other studies previously conducted. Bridge volume ejection was shown to be proportional to capacitor voltage. Current density increased with respect to capacitor voltage up to a point of saturation between 2400 V and 3000 V (evidenced electrically). Beyond the saturation voltage, high voltages demonstrated sustained energy delivery at a reduced current. This work indicates that control of active bridge volume or electrical supply signal may enable more closely controlled EFI flyer layer ejection behavior, and it demonstrates the relevance of using current per active bridge (specific current) as a metric to describe EFI electrical performance with relevance to dynamic response of the EFI. The impulse delivered by an EFI can be modulated via manipulation of the firing circuit input signal giving rise to system behavior variation.     

Multifunctional Initiator with Platinum-Acetylide Dendritic Core for Living Polymerization of Isocyanides

A novel multifunctional initiator has been developed by peripheral modification of a Pt-acetylide dendrimer. Pd–Pt μ-ethynediyl units were introduced to the first-generation dendrimer by a divergent method. The dendritic initiator was applicable to the living polymerization of aryl isocyanides, producing high molecular weight polymers with a narrow polydispersity index in quantitative yields. The ³¹P NMR spectrum of the resulting polymer suggested that all Pd–Pt μ-ethynediyl units in the dendritic molecule actually functioned as an initiator.     

RAFT法制备窄分布温敏性PNIPAAm

以N,N-二甲基甲酰胺(DMF)为反应介质,偶氮二异丁氰(AIBN)、三硫代碳酸二(α,α′-二甲基-α-乙酸)酯(BDATC)作为链转移剂,使N-异丙基丙烯酰胺(NIPAAm)进行可逆加成—断裂链转移自由基(RAFT)聚合,考察了引发剂(I)与链转移剂(CAT)的浓度比对NIPAAm的RAFT反应结果的影响。结果表明:70℃下,当[CAT]0/[I]0介于20:1～5:1,均可得到分子量分布窄、分子量可控的PNIPAAm,说明其聚合过程符合活性聚合反应的特征。     

淀粉接枝共聚高吸水树脂的研究进展及应用

介绍了淀粉系高吸水性树脂的制备引发方式,阐述了利用化学引发法合成的淀粉接枝丙烯腈类、丙烯酸类和丙烯酸酯或丙烯酰胺类3个系列吸水树脂的研究进展,并且介绍了淀粉接枝共聚高吸水树脂在个人卫生、医药、农业园林等方面的应用。简要指出了高吸水树脂的研究及发展方向。