国产气相聚乙烯浆液催化剂的工业应用

本文简要阐述了北化院BCS01和上海院SLC-S两种国产气相聚乙烯浆液催化剂的性能、催化剂结构,在Unipol聚乙烯工业装置上应用结果,以及和进口同类催化剂UCAT-J的性能比较。     

采用表面粘涂技术提高设备的抗腐蚀性能

通过表面粘涂，对受到腐蚀、冲蚀、气蚀的设备进行表面修补与防护，可提高设备的使用寿命。     

水利工程施工应急能力G1-灰色评价方法研究

为有效加强水利工程应急能力建设,采用G1-灰色综合评价法对水利工程应急能力进行了综合评价研究。在水利工程施工特点和应急管理研究基础上,建立应急能力评价指标体系。通过采用G1法分析各应急能力评价指标相互关系,确定了指标权重。引入灰色理论将样本信息处理成灰色评价矩阵,并结合指标权重进行单值化处理得到应急能力综合评价值和评价等级。研究结果表明,搜救抢险能力、应急资源调配能力和应急决策指挥能力对于水利工程应急能力建设起到最主要的作用。该评价方法不仅可揭示指标重要程度关系,还能有效量化和评价水利工程项目综合应急水平,具有较好的实用性。     

传统法制备嗪草酮印迹聚合物

农药嗪草酮应用广泛,它的残留问题引起了人们的普遍关注,发展快速准确的检测方法势在必行。而分子印迹技术因其独特的优点使它成为痕量残留快速检测的一种较好的方法。采用传统法制备嗪草酮印迹聚合物,以甲基丙烯酸(MAA)为功能单体,N,N-亚甲基双丙烯酰胺为交联剂,甲苯为溶剂,在50℃时聚合得到选择性、吸附性最佳的印迹聚合物。     

Reliability-based robust design optimization: A general methodology using genetic algorithm

In this paper, we present an improved general methodology including four stages to design robust and reliable products under uncertainties. First, as the formulation stage, we consider reliability and robustness simultaneously to propose the new formulation of reliability-based robust design optimization (RBRDO) problems. In order to generate reliable and robust Pareto-optimal solutions, the combination of genetic algorithm with reliability assessment loop based on the performance measure approach is applied as the second stage. Next, we develop two criteria to select a solution from obtained Pareto-optimal set to achieve the best possible implementation. Finally, the result verification is performed with Monte Carlo Simulations and also the quality improvement during manufacturing process is considered by identifying and controlling the critical variables. The effectiveness and applicability of this new proposed methodology is demonstrated through a case study.     

Experimental design in soap manufacturing for optimization of fuzzified process capability index

In manufacturing industries, the quality of a product depends on the combined effect of multiple input variables working singly or together and therefore attention has been given on process capability indices to shift from single to multivariate domain. In case of multivariable domain the capability to incorporate uncertainties at the time of decision making becomes necessary. Fuzzy system is introduced to take care of this requirement. In this article the process parameters of soap manufacturing industries have been analyzed. The process capability is determined using Fuzzy Inference System rule editor based on a set of justified if then statements as applicable for the process. The data has been collected in linguistic form to derive its process capability, using a set of justified rules and the effect of each factor has been determined using Design of Experiments (DoE) and analysis of variance technique (ANOVA) for improving the soap quality from perspective of its softness. This article ventures to propose a new methodology by integrating Fuzzy with DoE providing better result followed by DoE and Fuzzy Inference system in isolation.     

聚丙烯纤维性能及其在混凝土中的应用

在混凝土中掺加聚丙烯纤维能有效地提高混凝土材料的抗裂性、抗冲击性、抗冻性能、改善混凝土的抗疲劳特性。分析了纤维改性混凝土机理。介绍了聚丙烯纤维在混凝土中的应用。指出了聚丙烯改性混凝土的发展趋势以及加强高性能、多功能以及复合聚丙烯纤维改性水泥土研究的重要性。     

Synthesis and electrochemical characteristics of Al2O3-coated LiNi1/3Co1/3Mn1/3O2 cathode materials for lithium ion batteries

LiNi_1/3Co_1/3Mn_1/3O₂ cathode materials have been coated with Al₂O₃ nano-particles using sol-gel processing to improve its electrochemical properties. The X-ray diffraction (XRD) pattern of the as-prepared Al₂O₃ nano-particles was indexed to the cubic structure of the γ-Al₂O₃ phase and had an average size of ∼4 nm. The XRD showed that the structure of LiNi_1/3Co_1/3Mn_1/3O₂ was not affected by the Al₂O₃ coating. However, the Al₂O₃ coatings on LiNi_1/3Co_1/3Mn_1/3O₂ improved the cyclic life performance and rate capability without decreasing its initial discharge capacity. These electrochemical properties were also compared with those of LiAlO₂-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathode material. The electrochemical impedance spectroscopy (EIS) was studied to understand the enhanced electrochemical properties of the Al₂O₃-coated LiNi_1/3Co_1/3Mn_1/3O₂ compared to uncoated LiNi_1/3Co_1/3Mn_1/3O₂.     

聚氯乙烯弹性体气候老化性能研究

将聚氯乙烯(PVC)弹性体试样进行户外曝晒试验,对试样老化前后的外观、力学性能、扫描电镜、红外光谱等试验结果进行分析比较,考察了光、热、氧对PVC弹性体气候老化性能的影响。研究结果表明:曝晒6个月后PVC的外观暗淡但有韧性,出现少量裂纹,分布也不均匀;拉伸强度逐渐增加,而断裂伸长率逐渐下降,16个月时下降到73.26%。导致断裂伸长率下降和拉伸强度逐渐增加的原因是DOP增塑剂的慢慢挥发。PVC样品经过16个月的曝晒后的红外光谱显示:波峰1620cm-1的出现说明有C=C存在,波峰969cm-1的消失说明高分子中的CH2断裂,这些都是分子老化所造成的。最后通过数学建模应用软件计算16个月后的断裂伸长率,预测可知:PVC弹性体在户外暴露30个月后就失去使用价值。     

一种基于随机GA的提高BP网络泛化能力的方法

LM-BP网络对其初始权值和阈值敏感,泛化能力不强,针对该缺点,采用遗传算法（GA）对其初始权阈值进行优化,在一定程度上能提高LM-BP网络的泛化能力。为进一步扩展GA初始种群的覆盖范围,进一步提高LM—BP网络的泛化能力,采用多次随机产生初始种群多次优化的方法。以伦河孝感段氟化物含量为实例,建立随机GA的LM—BP网络模型,对原始数据进行拟合及测试,结果表明该方法基本能100％拟合,测试误差不超过2．3％。经过对比实验,证明了该方法的有效性。