深井重泥浆弱凝胶工艺技术初探

重泥浆强凝胶体系对钴井会产生不利影响。笔者结合川东地区的实际情况,分析了重泥浆强凝胶形成的原因和重泥浆弱凝胶的形成机制,提出了形成重泥浆弱凝胶体系的核心和设计原则,总结出了一套以正确使用泥浆添加剂并配合强有力的固控措施为主的成套深井重泥浆弱凝胶工艺技术,介绍了这套技术在川东地区的应用情况。实践证明,少用甚至不用泥浆降粘剂就可获得并维持尽可能低的静切力,使τ_s,10s为0.5—6Pα、τ_s,10min为2—12.5Pα。     

The Effect of Moisture Content on the Conversion of Ergosterol to Vitamin D in Shiitake Mushrooms

The distribution of ergosterol in different parts of shiitake mushrooms was studied in order to optimize the conversion of ergosterol to vitamin D₂ during drying. The effect of moisture on the conversion of ergosterol to vitamin D₂ was also investigated by adjusting the moisture content of fresh mushrooms to different levels in a large vacuum desiccator and subjecting them to UV irradiation at 290-320 nm wavelength, for 2 h. The moisture, ergosterol and vitamin D₂ contents were determined using standard procedures. It was found that the ergosterol content on a dry matter basis of fresh shiitake mushroom was highest in the gills (10.6 ± 0.99 mg/g DM), followed by the cap or pileus (5.34 ± 0.64 mg/g DM) and was least in the stalk or stipe (2.97 ± 0.56). The moisture content had a marked influence on the conversion of ergosterol to vitamin D₂, the best conversion taking place at a moisture content of about 70% on a wet basis.     

Hypervelocity impact computations with finite elements and meshfree particles

The ability of computations to model characteristics of hypervelocity impact is demonstrated using an algorithm for the automatic conversion of distorted finite elements to meshfree particles. The Lagrangian formulation tracks material boundaries and properties without the errors typical in an Eulerian formulation as the material traverses large distances. A computation of a sphere impacting a bumper is shown to reproduce three regions in the debris cloud that are observed in tests: a front region composed of droplets of melted projectile and target, a middle region of fragmented projectile, and a back region of spalled projectile. Additional computations reproduce the observed traits that result from variations in the projectile shape and obliquity. The computation of a projectile impacting spaced plates demonstrates the ability of the method to model the damage to the rear plate of a Whipple shield for spacecraft protection.     

A source apportioned mercury mass balance across a coal-based petrochemical complex

Coal-fired power generation facilities are the largest single anthropogenic source of mercury to the atmosphere. Global mapping of anthropogenic emissions has previously estimated the mercury emission from stationary combustion from South Africa at being 82.6 tonnes per annum, but preliminary in-house calculations have placed this at a significantly lower amount. A petrochemical facility in South Africa, utilising a significant amount of coal in its gasification and steam generation processes, undertook a project to determine a mercury mass balance across the complex, and to apportion the Hg emissions from the facility.     

Direct synthesis and catalytic performance of ultralarge pore GaSBA-15 mesoporous molecular sieves with high gallium content

Mesoporous GaSBA-15 molecular sieves with different n_Si/n_Ga ratios have been directly synthesized using Pluronic 123 triblock polymer as a structure-directing agent by pH-adjusting method. The mesoporous materials have been characterized using ICP-AES, XRD, N₂ adsorption, ⁷¹Ga-MAS NMR, SEM and TEM. ICP-AES studies show a high amount of gallium incorporation on the silica pore walls. The structural and textural properties of calcined GaSBA-15 are characterized by XRD and N₂ adsorption. ⁷¹Ga MAS NMR results demonstrate that a high amount of tetrahedral-gallium could be substituted for Si in the framework of SBA-15. TEM and FE-SEM images show the uniform pore diameter and rope-like hexagonal mesoporous structure of GaSBA-15. These GaSBA-15 materials have been used as catalysts for vapour-phase t-butylation of 1,2-dihydroxybenzene (DHB) for selective synthesis of 4-t-butylcatechol (4-TBC) under different reaction conditions. GaSBA-15(10) gave the highest 93.2% conversion of DHB and 95.7% selectivity of 4-TBC as compared with other GaSBA-15 catalysts.     

Heat loss and thermoelectric generator design

With the object of evaluating its importance to thermoelectric generator design, heat loss is introduced into the standard thermoelectric generator design theory. The theory for both the constant hot and cold junction temperatures model and the constant heat input model are so modified. The modification is first order and, therefore, is limited to small leg heat-transfer coefficients. Numerical results using representative properties show that significant differences can exist between the optimum geometry and performance of a generator idealized as lossless and those of a generator designed by the modified theory. The largest differences occur with the constant heat input model.     

Stannate and permanganate conversion coatings on AZ31 magnesium alloy

The formation of stannate and permanganate–phosphate conversion coatings on AZ31 magnesium alloy was investigated in situ by EIS measurements and their protective performances were studied by different electrochemical techniques in diluted (0.05 M) sodium sulphate solution.The influence that short or long treatment times exert on the performances of such conversion coatings is discussed. While permanganate–phosphate baths always built layers characterized by penetrating cracks, long stannate baths produced layers without interconnected porosity, but were defective. This accounted for the initial greater protectiveness achieved with the stannate treatment; nevertheless, the easy penetration of the electrolytic solution through such a layer quickly decreased its corrosion resistance.     

Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys

The corrosion protection afforded by a cerium conversion coating, formed by immersion in a solution containing rare earth salt and hydrogen peroxide, on pure magnesium and two magnesium alloys, AZ91 and AM50, has been studied. The effect of HCl pre-treatments on the morphology and on the corrosion resistance of the cerium conversion layer was investigated. A thicker and more homogeneous distribution of the conversion coating was obtained when the sample surface was pre-treated with acid. Higher amounts of cerium on the surface of the pre-treated samples were detected. The cerium conversion coating increased the corrosion resistance of the alloys because it ennobled the corrosion potential and decreased both the anodic and cathodic current. The acid pre-treatment further increased the corrosion resistance of the coated alloys. After five days of immersion in chloride environment the untreated samples showed localized corrosion while the chemical conversion coated samples appeared unaffected.     

环保型水溶性带锈防锈涂料的研制

为省去除锈除油等表面预处理工序，以简化涂漆工艺，减轻劳动强度，降低涂装成果，采用改性脲醛树脂作为水溶性带锈涂料的成膜物与转化液的最佳配比，研制出一种环保型水溶性带锈防锈涂料，较好地解决了水溶性带锈涂料耐水性和装饰性差的问题。     

环己烷氯代合成氯代环己烷的研究

由环己烷出发，经光引发氯化制氯代环己烷。对该方法的各工艺条件（反应器、反应温度和光源等）对反应的选择性及转化率的影响进行了考察，确定了生产氯代环己烷的工艺条件。