Catalytic decomposition of HCFC22 (CHClF2)

The catalytic decomposition of CHClF₂ was studied over various acidic metal oxides in a fixed-bed reactor. The Cr₂O₃ZrO₂ exhibited the highest activity. The presence of water vapor in the reaction system suppresses the transformation of oxides to fluorides, progresses the formation of CO₂, and it improves the catalysts life.     

大功率CO_2激光器非平衡态合成WO_3／Fe_2O_3新型陶瓷催化剂──Ⅱ．WO_3／Fe_2O_3烯烃歧化反应催化剂的催化活性

用大功率ＣＯ２激光器熔制ＷＯ３／Ｆｅ２Ｏ３新型烯烃歧化反应催化剂。考查了催化剂组成、激光功率及熔炼时间与丙烯歧化反应催化活性之间的关系。     

连续重整装置仿真系统的设计开发

为提高操作人员对连续重整装置开停工及事故处理的熟练程度，并对生产进行指导，采用半机理模型结合设计和现场数据介发的连续重整装置仿真系统已在现场成功投用。介绍了该仿真系统的软硬件结构、动态模型及仿真功能。     

哈尔滨炼油厂MTBE装置试生产

介绍了哈尔滨炼油厂ＭＴＢＥ装置的工艺路线、新技术的应用及特点；催化剂的装填及应用情况；总结了生产过程中遇到的一系列问题及解决办法；探索了平稳生产的新徐径，以保证装置安全、平稳、长周期运行；同时对反应器操作温度、催化蒸馏塔操作压力、原料中醇烯比等因素对异丁烯转化率及ＭＴＢＥ产品的影响做了简单的总结。     

利用独立分量分析法去除地震噪声

 独立分量分析（ICA）作为盲源分离（BSS）的一种新方法,是分解观测数据中独立信息的有力工具。以往的ICA算法一般假设噪声可以忽略不计，而实际的观测数据中又常常包含一些加性噪声。对于加性噪声的影响不能忽略的情况下，改进的ICA算法首先利用非零时间滞后协方差，应用两步特征值分解法(EVD)可成功地去除部分加性噪声的影响；再利用ICA算法就能更好地分离出原信号。本文通过对地震理论模型和实际资料的试验，说明改进的ICA算法能够有效地克服加性噪声对常规ICA算法的影响，能够分离出地震资料中的有效信号，从而实现利用独立分量分析压制地震资料噪声的目的。     

Study of direct and indirect naphtha recycling to a resid FCC unit for maximum propylene production

To satisfy the increasing propylene demand, direct and indirect naphtha recycling schemes around an existing resid fluid catalytic cracking (FCC) unit were investigated. To this aim, light cracked naphtha (LCN), heavy cracked naphtha (HCN) and a PolyNaphtha (PN) oligomerisation product were cracked under a wide range of operating conditions over a commercial Y zeolite based equilibrium catalyst. Experimental data were acquired in three different units: a fixed bed bench scale unit, a fixed fluidised bed unit and an adiabatic circulating fluidised bed pilot plant. It was shown that FCC naphthas require high operating severities to crack, and that even then their conversion remains relatively moderate. Hence, direct recycling to the main riser does not seem a viable pathway to increase propylene product. Feeding FCC naphthas to a second reaction zone operating at high severity allows to increase the propylene yield in a significant manner. Increasing conversion, however, not only leads to higher LPG and propylene yields, but also results in very high dry gas yields. An alternative scheme was proposed, in which the olefinic C₄ and C₅ fractions are converted into a naphtha fraction through oligomerisation in a dedicated unit before being recracked in the secondary riser. As the highly olefinic oligomerised effluent mainly consist of dimerised and trimerised butenes and pentenes, this feed is more easily cracked and high conversions can be achieved. This indirect interconversion of butenes and pentenes into propylene therefore effectively allows to convert these butenes and pentenes into propylene, resulting in a significant increase in propylene yield. Each of the three main naphtha recycle options (directly to the main riser, directly to a secondary riser or indirectly via a light olefin oligomerisation unit) have been analysed and compared to a base case. In the evaluation of each of these schemes, all heat balance effects, both on the riser and the regenerator side, have been accounted for. The proposed process scheme with an indirect recycle via an oligomerisation unit enhances the already inherent flexibility of the FCC unit. The naphtha recycle can be turned on or off, the second reaction zone can be used to crack naphtha or to crack resid feed to maximise throughput, while the effluent of the oligomerisation unit can be recycled to the FCC unit for propylene production or hydrogenated and sent to gasoline and kerosene pool.     

一次国际设计竞赛的尝试--多维住宅设计

在后工业时代，建筑设计已经冲破了西方思维所惯用的二元对立方式的约束，呈现出日新月异的景象，建筑表皮的创作尤为突出。这个住宅设计是从四维分解到四维连续的一种大胆尝试，并引入拓扑学的基本方法处理动态空间。     

A fictitious domain decomposition method for the solution of partially axisymmetric acoustic scattering problems. Part I: Dirichlet boundary conditions

We present a fictitious domain decomposition method for the fast solution of high‐frequency acoustic scattering problems characterized by a partially axisymmetric sound‐soft scatterer. We apply this method to the solution of various mockup submarine problems, and highlight its computational advantages and intrinsic parallelism. Copyright © 2002 John Wiley & Sons, Ltd.     

Development and Commercial Application of a Novel Catalyst DVR—1 for Catalytic Cracking of Daqing Vacuum Residue

A newly developed catalyst type DVR-1 for catalytic cracking of Daqing vacuum resid was put into use in a commercial VRFCC unit,This catalyst features uniquely active matrix and modified ultra-stable zeolite.The commercial application results show that the DVR-1 type catalyst has the advantage of high heavy oil conversion,good metal tolerance nd gooed stability for catalyst regeneration,The FCC tests have shown Favorable product distribution,acceptable product quality and enormaous economic benefits whe processing the feedstock containin 75%-100% Daqing VR.     

北京市危旧房改造的多目标分解模式

由于政府、居民、开发商之间复杂的博弈,北京市1990年提出的综合性危改目标遇到了很大的挑战,为解决这一问题,本文提出危旧房改造的目标分解模式,即建立一个以危改区域或危改项目为导向的危改目标实现框架,将北京市危旧房改造的多重目标进行分解,然后制定相应的分目标政策,建立相应的分目标制度,采取相应的分目标措施,最终从总体上实现危旧房改造的目标,主导目标的确定应遵循四个基本原则,最后提出几个政策建议。