NMR study on self-assembled cage complex of hexamethylenetetramine and cucurbit[n]urils

Self-assembled complexes between cage com-pounds cucurbit[n = 5—8]urils and hexamethylenetetramine were studied by using NMR techniques. Experimental results reveal that hexamethylenetetramine can lid cucurbit[5]uril to forming self-assembled capsules in which nothing is encap-sulated yet; the cavity of the cucurbit[7]uril can accommo-date a hexamethylenetetramine molecule to form a self- assembled host-guest inclusion. Moreover, both the cavity interaction of the cucurbit[7]uril with hexamethylenetetra-mine稨Cl and the portal interaction of the dipole carbonyl of the cucurbit[7]uril with hexamethylenetetramine稨Cl lead to form self-assembled capsules in which the hexamethylene-tetramine稨Cl are encapsulated in the hexamethylenetetra-mine稨Cl lidded cucurbit[7]uril. Although the structures of the portal and cavity to cucurbit[5]uril are similar, there is no obvious interaction between decamethylcucurbit[5]uril and hexamethylenetetramine, and also between cucurbit [6]uril or cucurbit[8]uril and hexamethylenetetramine.     

网络安全技术的探讨

论述了网络的开放性所带来的安全问题及黑客畅行所引起的不便,提出了为保证网络工作顺通应采取的方法。     

硝基甲烷正、负带电离子氢转移反应位垒的计算研究

采用DFT（UB3LYP）方法，在6—311＋＋G^＊＊基组水平上，计算研究了硝基甲烷2种带电结构[CH3NO2]^＋和[CH3NO2]^-分子内H原子向O原子转移后的O-N键的解离机理和反应位垒．结果表明，[CH3NO2]^＋发生氢转移后，O-N键的断裂是2步反应，第一步是分子内的H原子转移到O原子上，生成中间体[CH2N（OH）O]^＋，反应位垒为106．5kJ／mol；第二步是中间体中O-N键断裂，这步的反应位垒为105．5kJ／mol，理论计算得出的产物带电状态与实验一致．[CH3NO2]^-中H原子向O原子转移及O-N键断裂反应一步完成，生成一氢键复合物（H-Complex），该反应位垒为176．2kJ／mol，H—Complex进一步解离成CH2NO自由基和OH^-，或是OH自由基和[CH2NO]^-．     

视觉测量系统的像点残余误差和紧密度分析

提出了视觉测量系统的像点残余误差和紧密度的精度评价方法,基于束调整算法推导了像点残余误差和紧密度的计算公式.测量实验表明,在大尺寸视觉测量中,采用本方法更有利于对测量作精度评价,便于工业测量应用.作为实例,对实验室控制场内测量点进行三维坐标测量,50 %的待测像点坐标达到0.13像素的精度,50 %的空间点坐标的紧密度小于0.024 %.这种精度评价方法特别适合于采用束调整算法的多站位视觉测量系统,可以伤脑筋为常规精度估算方法的补充.     

伪脐子流形的Pinching定理

研究了2个嵌套空间中的子流形．对于拟常曲率流形中的常曲率黎曼子流形以及常曲率黎曼子流形中的具有平行平均曲率向量的紧致伪脐子流形，给出了这种伪脐子流形是全脐子流形的3个充分条件．     

Validation of three infiltration models on purple soil under simulated rainfall

So as to find models suitable for the prediction of water infiltration in purple soil,infiltration rates simulated by three popular empirical infiltration models,Horton model,Kostiakov model,and the modified Kostiakov model,were compared by using those observed results on slope in purple soil under rainfall simulation.28 sets of infiltration data were divided into two parts for parameter estimation and validation independently.The performance of the three infiltration models was evaluated with the Nash and Sutcliffe efficiency criterion.The results show that the percent for Nash and Sutcliffe efficiency greater than 0.7 is about 69.7% for the Horton model,and 48.48%,and 54.55% for the Kostiakov model and the modified Kostiakov model,respectively.Horton model is better than Kostiakov model and the modified Kostiakov model in most rain events in the field.However,Kostiakov model is still suitable for reasonable prediction of the infiltration in purple soil sloping farmland because fewer parameters are needed.Furthermore,rainfall intensity has significant effects on the parameter values used in the simulation models.The simulation results can be improved by choosing suitable parameters according to the rainfall intensity.     

Ca和Ba掺杂对La4/3Sr5/3Mn2O7的磁电阻效应的影响

用溶胶-凝胶法制备了双层钙钛矿锰氧化物La4/3(Sr1-xAx)5/3Mn2O7 (A是Ca或者Ba,x=0,0.1,0.2)系列多晶样品,并对其结构及电、磁输运性质进行了研究.研究结果表明:Ca和Ba的掺入虽然导致绝缘体-金属(I-M)转变温度(TI-M)降低,但可以明显提高低温区的磁电阻效应.对于x=0.2的Ca或Ba掺杂的样品,在60 K以下,磁电阻值接近100 %,且为一恒定值.对于这一实验结果可以作如下解释:Ca或Ba掺杂引起了MnO6八面体的畸变,导致eg电子占据dx2-y2轨道和d3z2-r2轨道的状态偏离了x=0时的优化组合状态,铁磁性被削弱.     

G.728中增益码书的研究

阐述了G.728编码器中增益预测器的作用；定性地对增益码书进行深入的分析，认为gi的精确表达对合成语音质量改善有很大提高，提出使用归一化波形码书的重要性。研究旨在探索一条实现8kB/sLD-CELP算法的途径。     

β-粒子在穿越铜狭缝中的横向台阶分布

文章研究了电子高速运动时所产生的横向振动。实验方法是利用半圆聚焦β-谱仪上90Sr源β-粒子在不同磁场下对于相同弯曲半径下β-粒子具有不同的能量和动量的特性，研究这些β-粒子在通过不同宽度的铜狭缝（厚8 mm）时的粒子数n和铜狭缝宽度δ的函数关系，发现不管β-粒子具有什么能量和动量，都具有横向运动的趋势和在铜狭缝中出现了台阶分布。其原因可能是β-粒子本身具有横向振幅A和周围真空起伏能量的相互作用。     

弹性连杆机构震动力最小化构件截面参数综合

本文将“最佳性准则法”应用于弹性连杆机构运动弹性动力综合,提出了在应力约束下通过修正构件截面参数,实现机构震动力最小化的一种新方法,并给出了计算实例。