Dependence of pressure on elastic,electronic and optical properties of CeO2 and ThO2: A first principles study

The phase transformation of CeO₂ and ThO₂ from fluorite to cotunnite-type structure under pressure is predicted within the density functional theory implemented with the GGA-PW91 method, the pressure induced structural phase transition occurs at 28.9 GPa for CeO₂ and 29.8 GPa for ThO₂. These values are in excellent agreement with the experimentally measured data. The elastic, electronic and optical properties at normal as well as for high-pressure phase have been calculated, particular attention is devoted to the cotunnite phase. Further, the dependence of the elastic constants, the bulk modulus B, the energy band gaps and the dielectric function on the applied pressure are presented.     

A comparative study on life cycle assessment of micro and macro components

Micro manufacturing is an extremely demanding technological field where very special materials are used, extreme production condition like clean room, super high temperature, toxic chemicals, etc. are employed. Due to these facts, micro products can be environmentally damaging even after their smaller dimensional scale. So performing of LCA for micro products is equally important as it is for macro products. Keeping this motivation in mind, current paper systematically performs the LCA of a micro Socket used in hearing aids. The analysis makes a guide line about how to use the conventional knowledge about LCA and tools for the efficient LCA analysis of the micro parts. A comparative study is made in the paper by comparing two different sockets of hearing aid and it shows well how to make a comparative study for LCA when the manufacturer makes a new product to replace an old one. Another comparative study is made in the paper for micro and macro which shows that scaled up effect of the micro product compared to macro counterpart. The critical finding of this comparative study shows that the relative environmental damage done by micro product is higher than the macro product and that is confirmed by the net impact analysis. Finally, the LCA procedure presented in the paper, and the knowledge documented can be a valuable source of information for the researchers and scientists who work with the LCA of micro and macro products.     

Scaling Up of Chemical Injection Experiments

Abstract

It is well known that laboratory experiments are the most useful means of developing predictive models for various engineering applications. However, scaling laws should be known in order to scale up laboratory results to field conditions. This scaling up offers a formidable challenge in scenarios involving complex solid/fluid interactions which are predominant in chemical processes such as in petroleum engineering and environmental remediation. This article presents a series of chemical adsorption tests and provides one with the scaled-up versions; these results are then compared with numerical simulation results. Finally, recommendations are made as to how to interpret laboratory experimental results and apply scaling laws to predict field behavior.     

Solvothermal synthesis of greigite (Fe3S4)– Conducting polypyrrole nanocomposite and its application towards arsenic removal

In the present investigation, Greigite-conducting polypyrrole nanocomposite (GPPy nanocomposite) was prepared, characterized and used to remove arsenite and arsenate from aqueous solution. Fe₃S₄ was synthesized using solvothermal synthetic method and it was grafted to conducting polypyrrole matrix. The nanocomposite was characterized using FE-SEM, EDX, XRD, FTIR, TGA/DSC and BET surface area. Kinetic studies revealed that the removal process followed first order kinetics. Batch isotherm studies were performed to determine the binding capacity. Thermodynamic parameters were also computed and it indicated the spontaneous nature of the process. Electrophoretic studies were carried out to determine the point of zero charge.     

Design and performance analysis of a nanoscaled inverter based on wrap-aroundgate nanowire MOSFETs

The design and analysis of a silicon nanowire inverter with a wrap-around-gate nMOS is presented and its performance is compared with that of a conventional inverter. The analysis shows that the nano-channel structure design can improve carrier mobility by suppressing the transverse component of the electric field. This results in an enhancement in the current drive of the nMOS, and contributes to lowering power consumption and the switching delay. Simulated power consumption and rise time of the proposed design was found to be about 20 μW and 0.5 ns, respectively, compared with 2.5 mW and 1.5 ns achievable with conventional planar MOSFETs. Investigation of the gate length shows that a nMOS with shorter gates have an improved switching response compared with long channel devices.     

Implications of Biofuel Policies for Water Management in India

India has developed a national biofuel policy to increase energy security, reduce greenhouse gas emissions, and stimulate rural development. In this policy, the government has set blending targets for mixing ethanol and biodiesel with gasoline and diesel, respectively. In India, ethanol is produced from irrigated sugar-cane while biodiesel is produced from jatropha, which is said to require no irrigation. This paper analyzes the possible impacts of an increase in sugar-cane and jatropha production on water management and use. It finds that India's biofuel policy is likely to place additional pressure on scarce water resources. Although the development of biofuels may be necessary, care must be taken to anticipate its likely impacts on water resources.     

The phase equilibria in the Mg–Ni–Ca system

The three binary systems Mg–Ni, Ca–Ni and Mg–Ca have been re-optimized. A self-consistent thermodynamic database of the Mg–Ni–Ca system is constructed by combining the optimized parameters of these three constituent binaries. Lattice stability values are not added to the pure elements Mg-hcp, Ni-fcc, Ca-fcc and Ca-bcc to construct this database. The Redlich–Kister polynomial model is used to describe the liquid and the terminal solid solution phases, and the sublattice model is used to describe the non-stoichiometric phase, in this system. The constructed database is used to calculate the three binary and the ternary systems. The calculated binary phase diagrams along with their thermodynamic properties such as Gibbs energy, enthalpy, entropy and activities are found to be in good agreement with experimental data from the literature. This is the first attempt to construct the ternary phase diagram of the Mg–Ni–Ca system. The established database for this system predicted three ternary eutectic, five ternary quasi-peritectic, two ternary peritectic and two saddle points.     

A low-power RF integrated circuit for implantable sensors

A low-power low-voltage analog signal processing circuit has been designed, fabricated, and tested. The circuit is capable of processing an analog sensor current and producing an ASK modulated digital signal with modulating signal frequency proportional to the sensor current level. An on-chip regulator has been included to stabilize the supply voltage received from an external RF power source. The circuit can operate with a power supply as low as 1 V and consumes only about 20 μW of power, which is therefore very suitable for implantable biomedical applications. The whole chip was laid out and fabricated in a 0.35 μm bulk CMOS technology. Experimental results show good agreement with the simulation results.     

Raman amplifiers for telecommunications

Raman amplifiers are being deployed in almost every new long-haul and ultralong-haul fiber-optic transmission systems, making them one of the first widely commercialized nonlinear optical devices in telecommunications. This paper reviews some of the technical reasons behind the wide-spread acceptance of Raman technology. Distributed Raman amplifiers improve the noise figure and reduce the nonlinear penalty of fiber systems, allowing for longer amplifier spans, higher bit rates, closer channel spacing, and operation near the zero-dispersion wavelength. Lumped or discrete Raman amplifiers are primarily used to increase the capacity of fiber-optic networks, opening up new wavelength windows for wavelength-division multiplexing such as the 1300 nm, 1400 nm, or short-wavelength S-band. As an example, using a cascade of S-band lumped amplifiers, a 20-channel, OC-192 system is shown that propagates over 867 km of standard, single-mode fiber. Raman amplifiers provide a simple single platform for long-haul and ultralong-haul amplifier needs and, therefore, should see a wide range of deployment in the next few years