CuxNi1-xO nanostructures and their nanocomposites with reduced graphene oxide: Synthesis,characterization, and photocatalytic applications

NiO nanostructure was synthesized using a simple co-precipitation method and was embedded on reduced graphene oxide surface via ultrasonication. Structural investigations were made through X-ray diffraction (XRD) and functional groups were confirmed by Fourier transform infrared spectroscopy (FTIR). XRD analysis revealed the grain size reduction with doping. Fourier transform infrared spectroscopy confirmed the presence of metal-oxygen bond in pristine and doped NiO nanostructure as well as the presence of carbon containing groups. Scanning electron microscopy (SEM) indicated that the particle size decreased when NiO nanostructure was doped with copper. BET surface area was found to increase almost up to 43 m²/g for Cu doped NiO nanostructure/rGO composite. Current-voltage measurements were performed using two probe method. UV–Visible spectroscopic profiles showed the blue and red shift for Cu doped NiO nanostructure and Cu doped NiO Nanostructure/rGO composite respectively. Rate constant for Cu doped NiO nanostructure/rGO composite found to increase 4.4 times than pristine NiO nanostructure.     

Knowledge-Based Virtual Modeling and Simulation of Manufacturing Processes for Industry 4.0

Abstract

Industry 4.0 aims at providing a digital representation of a production landscape, but the challenges in building, maintaining, optimizing, and evolving digital models in inter-organizational production chains have not been identified yet in a systematic manner. In this paper, various Industry 4.0 research and technical challenges are addressed, and their present scenario is discussed. Moreover, in this article, the novel concept of developing experience-based virtual models of engineering entities, process, and the factory is presented. These models of production units, processes, and procedures are accomplished by virtual engineering object (VEO), virtual engineering process (VEP), and virtual engineering factory (VEF), using the knowledge representation technique of Decisional DNA. This blend of the virtual and physical domains permits monitoring of systems and analysis of data to foresee problems before they occur, develop new opportunities, prevent downtime, and even plan for the future by using simulations. Furthermore, the proposed virtual model concept not only has the capability of Query Processing and Data Integration for Industrial Data but also real-time visualization of data stream processing.     

User activities and the heterogeneity of urban space:The case of Dahiyat Al Hussein park

Urban researchers have maintained a constant interest in the complexity and continuity of urban space usage. Some have applied actor–network theory (ANT) to investigate the heterogeneity of spaces and present them through the networks of their users’ activities. However, these accounts are predominantly limited in examining the extent to which these spaces may be heterogeneous when exploring such networks. This paper draws on recent ANT scholarship, which employs an ethnographic research conducted in a main park in a housing project at Dahiyat Al Hussein in Amman, Jordan. The findings describe the complex and unpredictable negotiations that occur within spaces by documenting the varieties and interrelations among user activity networks within this common and shared urban space. This research reveals the extent to which spaces, parks in this case, may be heterogeneous by unpacking their usage. The conclusions and insights assert the necessity of paying attention to design detail and creating designs that are responsive to evolving user activities.     

Effect of Thin Film Thicknesses and Materials on the Response of RTDs and Microthermocouples

Fabrication and thermal characterization of a resistance temperature detector (RTD) heater and microthermocouples (MTs) on silicon substrates have been reported in this paper. The influence of film thickness and nickel-gold (Au) electroplating on RTD on its steady-state temperature with respect to its steady-state electrical power input and resistance is studied. Further, the thermal effects of multiple thermocouples in a thermopile as well as the effects of Au layers in the contact pads of the thermopiles on their open-circuit Seebeck voltage are studied. Therein lies the novelty of this paper. The in situ operating relationships for the RTD heater and the MT are provided     

Haemolytic activity of Aeromonas species isolated in Libya

Twenty seven Aeromonas strains (5A. hydrophila, 8A. sobria and 14A. caviae) isolated from children with diarrhoea and 34 Aeromonas strains (9A. hydrophila, 7A. sobria an 18A. caviae) isolated from children without diarrhoea were tested from haemolysin production. The results obtained showed that haemolysin production using human, horse or sheep erythrocytes was significantly associated with A.hydrophila and A sobria but not with A.caviae, regardless of whether these strains were isolated from children with or without diarrhoea. Human or horse rather than sheep erythrocytes are recommended for use in the haemolysin assay.     

The equilibrium partitioning of titanium between Ti3+ and Ti4+ valency states in CaO-SiO2-TiO x slags

The redox behavior of titanium in CaO-SiO₂-TiO _x melts was investigated using a slag-gas equilibrium technique. Titanium partitioning between Ti³⁺ and Ti⁴⁺ valency states and the ratio of activity coefficients of TiO_1.5 and TiO₂ were determined as functions of oxygen partial pressure, temperature, and slag composition. The equilibrium experiments were carried out at temperatures between 1783 and 1903 K under CO-CO₂-Ar gas atmosphere with oxygen partial pressure ranging from 10⁻¹² to 10⁻⁷ atm (1.01×10⁻¹⁰ kPa to 1.01×10⁻⁵ kPa). The slags had CaO/SiO₂ ratios between 0.55 and 1.35 and total titanium oxide concentrations from 7 to 50 mass pct. Experimental results showed that the Ti³⁺/Ti⁴⁺ ratio in CaO-SiO₂-TiO _x slags, containing up to 50 mass pct TiO _x , increased with decreasing oxygen partial pressure and decreased with increasing CaO/SiO₂ ratio and decreasing temperature. Measured variation of the redox ratio Ti³⁺/Ti⁴⁺ with oxygen partial pressure closely followed the ideal behavior. Increasing the CaO/SiO₂ ratio increased the ratio of activity coefficients of TiO_1.5 and TiO₂. The effect of total titania content on this ratio was more complex and in accord with Raman spectroscopy data.     

Autoconfiguration of a dynamic nonoverlapping camera network.

In order to monitor sufficiently large areas of interest for surveillance or any event detection, we need to look beyond stationary cameras and employ an automatically configurable network of nonoverlapping cameras. These cameras need not have an overlapping field of view and should be allowed to move freely in space. Moreover, features like zooming in/out, readily available in security cameras these days, should be exploited in order to focus on any particular area of interest if needed. In this paper, a practical framework is proposed to self-calibrate dynamically moving and zooming cameras and determine their absolute and relative orientations, assuming that their relative position is known. A global linear solution is presented for self-calibrating each zooming/focusing camera in the network. After self-calibration, it is shown that only one automatically computed vanishing point and a line lying on any plane orthogonal to the vertical direction is sufficient to infer the dynamic network configuration. Our method generalizes previous work which considers restricted camera motions. Using minimal assumptions, we are able to successfully demonstrate promising results on synthetic, as well as on real data.     

A dynamic variability management approach working with agile product line engineering practices for reusing features

The Journal of Supercomputing - Agile software development (ASD) and software product line (SPL) have shown significant benefits for software engineering processes and practices. Although both...     

Security flaws in a recent RFID delegation protocol

Radio frequency identification (RFID) tag delegation enables a centralized back-end server to delegate the right to identify and authenticate a tag to specified readers. This should be used to mitigate the computational load on the server side and also to solve the issues in terms of latency and dependency on network connectivity. In this study, we describe a basic RFID delegation architecture and then under this model, we investigate the security of an RFID delegation protocol: Song Mitchell delegation (SMD), which is recently proposed by Song and Mitchell. We point out security flaws that have gone unnoticed in the design and present two attacks namely, a tag impersonation attack and a desynchronization attack against it. We also discover a subtle flaw by which a delegated entity can still keep its delegation rights after the expire of them—this infringes security policy of the scheme. More precisely, we show that the protocol will be still vulnerable to previously mentioned attacks, even if the back-end server ends the delegation right of a delegated reader and update the secrets of the delegated tags. To counteract such flaws, we improve the SMD protocol with a stateful variant so that it provides the claimed security properties.