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991.
A series of new polyamides 3a–d containing aryl-azo, ether and sulfone groups in the main chain were synthesized from bis[4-(4-aminophenoxy)phenyl sulfone]
1 and several azo aromatic diacyl chlorides 2a–d by the low temperature solution polycondensation technique. FTIR spectroscopy, nuclear magnetic resonance (NMR) and elemental
analyses confirmed the structure of these polymers. Owing to the aryl and amide groups in the main chain, these polymers exhibit
photochromic properties as well as excellent thermal stabilities. The transition temperatures (T
g) are between 242 and 265 °C, and the char yields at 800 °C in nitrogen atmosphere were above 39%. Based on incorporation
of flexible ether linkages and polar sulfone groups, the polyamides show desirable solubility in organic solvents such as
DMAc, N,N-dimethylformamide (DMF), N-methyl-2-pyrroidinone (NMP) and dimethylsulfoxide (DMSO). And it is exemplified that
polyamide containing 2 and 2′ substitutes performed better solubility.
Funded by the National Natural Science Foundation of China (No. 50572081) 相似文献
992.
The catalysts of air electrode were prepared by sintering the active carbon loaded with manganese nitrate and potassium permanganate
at 360 °C The air electrode was made up of a catalyst layer, a waterproof and gas-permeable layer, a current collecting substrate
and a second waterproof and gas-permeable layer. The cell was assembled by the air electrode, pure magnesium anode and 10%
NaCl solution used as electrolyte. The microstructures of air electrodes before and after discharging were characterized by
SEM. The electrochemical behaviors of the air electrodes were determined by means of polarization curves, volt-ampere curves
and constant current discharge curves. The polarization voltage of air electrode is—173 mV (vs SCE) at the current density of 50 mA/cm2. The air electrodes exhibits good activity and stability in neutral electrolyte. The magnesium-air cell could work at 5 W
for more than 7 h. 相似文献
993.
为研究局部安全系数法中不同约束条件对土坡稳定分析的影响,结合两典型土坡,对局部安全系数法这一双重优化问题中的约束条件进行了分析,约束条件主要包括极大化问题中条块间法向力、剪切力、条底法向力需满足的约束以及极小化问题中可行滑动面需满足的约束条件,研究结果表明,限制条块间法向力为正,而允许条间剪切力为负条件下,局部安全系数法所得结果较为合理. 相似文献
994.
Antibacterial and corrosive properties of copper implanted austenitic stainless steel 总被引:1,自引:0,他引:1
Juan Xiong) Bo-fan Xu) Hong-wei Ni) ) School of Physics Electronic Technology Hubei University Wuhan China ) School of Material Metallurgy Wuhan University of Science Technology Wuhan China 《北京科技大学学报(英文版)》2009,16(3):293-298
Copper ions were implanted into austenitic stainless steel (SS) by metal vapor vacuum arc with a energy of 100 keV and an ions dose range of (0.5-8.0)×1017 cm-2. The Cu-implanted SS was annealed in an Ar atmosphere furnace. Glancing X-ray diffrac-tion (GXRD), transmission electron microscopy (TEM) and Auger electron spectroscopy (AES) were used to reveal the phase compositions, microstructures, and concentration profiles of copper ions in the implanted layer. The results show that the antibacterial property... 相似文献
995.
Guo-jun Wang ) Bai-qing Xiong) Yong-an Zhang) Zhi-hui Li) Pei-yue Li) ) State Key Laboratory for Fabrication Processing of Nonferrous Metals General Research Institute for Nonferrous Metals Beijing China ) Northeast Light Alloy Co. Ltd. Harbin China 《北京科技大学学报(英文版)》2009,16(4):427-431
The microstructure of the as-cast 2D70 aluminum alloy and its evolution during homogenization were investigated by means of optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and differential scanning calorimetry (DSC) analysis. The results indicate that the microstructure of the as-cast 2D70 aluminum alloy mainly consists of the dendritic network of aluminum solid solution and intermetallic compounds (Al2CuMg, Al2Cu, Al9FeNi, Cu2FeAl7... 相似文献
996.
In order to investigate Joule heating power, a three-dimensional finite element model (FEM) was developed to predict Joule
heating power in the channels of double-loop inductor. The simulated results were compared with experimental data from low
load trials for a 400 kW inductor. The results, such as power factor and Joule heating power, show reasonable correlation
with experimental data, and Joule heating rate reaches the maximum at the corners and the minimum at the centre of the cross-section
area. With increasing relative permeability of iron core, length of coils, current frequency and resistivity of metal melt,
the power factor and Joule heating power change. It is concluded that current frequency, the resistivity and length of the
coil play a critical role in determining the power factor and Joule heating power, whereas relative permeability of the magnetic
core shows no significant influence on them. 相似文献
997.
Twelve samples derived from different locations in south central area of China are treated by enrichment and spread-plate
technique for initial screening. Seven chitinase-producing strains are isolated. The chitinase present in the culture supernatant
of strain CS-01 possesses the maximum activity of 0.118 U/mL. Analysis of the morphological feature and the ITS rDNA sequence
reveals that strain CS-01 belongs to Aspergillus fumigatus. Production of the chitinase is regulated by a inducible way and the maximum activity appears at 36 h in colloidal chitin
culture. Purification of the chitinase is carried out by salting out, gel filtrate chromatography and anion exchange chromatography
sequentially. Native-PAGE and SDS-PAGE indicate that the chitinase from A. fumigatus CS-01 is a monomer with the relative molecular mass estimated to be 4.50×104. Its maximum activity appears at pH 5 and 55 °C. The chitinase is stable at pH 4.0–7.5 and below 45 °C.
Foundation item: Projects(50621063, 50674101) supported by the National Natural Science Foundation of China 相似文献
998.
Identification and fermentation optimization of protopectinase-overproducing strain Aspergillus niger CD-01 for pectin production 总被引:1,自引:1,他引:0
In order to solve the citrus peel resource waste problem and minimize the drawbacks of chemical extraction of pectin, a protopectinase-overproducing
strain CD-01 for pectin production was isolated from a pit soil dumped with perished orange in Changde City, Hunan Province
of China. The strain CD-01 had the same morphology and 28S rRNA gene sequence (FJ184995) as that of Aspergillus niger (ATCC 64028). It was thus identified and named as Aspergillus niger CD-01. The fermentation condition was optimized based on L9(34) orthogonal experimental design and the variances analyses. The results show that the optimal condition for producing pectin
is as follows: time 36 h, temperature 35 °C, pH 5, and urea as the nitrogen source. Under this condition, the pectin yield
can reach up to 24.5%. This shows a great potential of Aspergillus niger CD-01 in pectin extraction from citrus.
Foundation item: Projects(50621063, 50674101) supported by the National Natural Science Foundation of China 相似文献
999.
Ji-ping Chen) Yong-lin Kang ) Ying-min Hao) Guang-ming Liu) Ai-ming Xiong) ) School of Materials Science Engineering University of Science Technology Beijing Beijing China ) The State Key Laboratory for Advanced Metals Materials China ) Steel Research Institute of Shougang Beijing China 《北京科技大学学报(英文版)》2009,16(5):540-548
A Ti+Nb bearing ultra-low carbon bake hardening sheet steel hot-rolled in the conventional austenite region and in the ferrite region with lubrication was experimentally studied.Subsequent cold rolling and continuous annealing processes were also conducted.The results show that microstructures of ultra-low carbon bake hardening hot strips at room temperature are basically irregular polygonal ferrites.The yield strength,ultimate tensile strength,n value,and r value of the No.2 specimen hot-rolled in the ferr... 相似文献
1000.
ZHANG Chuan-xiang DUAN Yu-ling XING Bao-lin ZHAN Liang QIAO Wen-ming LING Li-cheng 《中国矿业大学学报(英文版)》2009,19(3):295-299
Nitrogen-containing carbons were prepared by modification of activated carbons. The modified carbons were used as electrode materials with improved electrochemical performance. Precursor anthracite was activated by KOH (KOH: anthracite= 1:1), modified by melamine or urea and then treated at 1173 K to obtain the modified carbons. The porous structure, the chemical composition and the electrochemical characteristics of the carbons were investigated by nitrogen sorption, XPS and electrochemical methods respectively. Electrochemical experiments were performed in an organic electrolytic solution of 1 M (C2H5)4NBF4/PC.The samples modified by the different methods showed differences in chemical composition that introduced varying degrees of electrochemical performance enhancement. The presence of nitrogen enhanced the electron donor properties and the surface wettability of the activated carbons: this ensured a sufficient utilization of the exposed surface for charge storage. 相似文献