HLD-001TM甲苯歧化与烷基转移催化剂的工业试验

对中国石油化工股份有限公司上海石油化工研究院研发的高空速、低氢烃比甲苯歧化与烷基转移催化剂(HLD-001~(TM))进行了工业试验。结果表明,该催化剂具有优良的综合催化性能。在反应温度340～365℃,反应压力2.8～3.0 MPa,质量空速2.0～3.0 h~(-1),氢烃分于比3.0～3.7条件下,转化率46%～48%(质量),选择性90%～93%(质量),产物中二甲苯/苯为2.5～3.0(mol),歧化苯冰点不低于5.45℃,达到优级品的指标。     

深圳市抛石填海区物探方法研究

在深圳某抛石填海区,由于存在较厚的淤泥层,而且在淤泥层中大量的分布着大小不均的石块,在物探作业的时候,往往难以探测到淤泥下面的基岩面,本文基于以上情况,通过对几种常规的物探方法的对比,从理论到实践,从中找到了最优的勘探方法,为以后从事此类工程的物探工作者提供一些借鉴。     

黄麦岭磷矿矿石工艺矿相学研究

经红外光谱测试及单矿物化学分析，确定了磷灰石的种类；通过显微镜观察，系统地研究了不同自然类型磷矿石中磷灰石的嵌布嵌镶关系；利用线测法测定了磷灰石的嵌布粒度；采用一粗一精一扫浮选流程，按原来的浮选条件和药剂制度所得精矿，研究了其单体解离度及选矿回收率；提出了改进选矿工艺流程的可能途径和方法。     

Single Radar Measurement Method for Antiaircraft Projectile Miss Distance

To measure miss distance for antiaircraft projectile,a radial velocity identification and positioning method with a single radar is proposed.By analyzing the spatial resolution of multi-frequency ranging radar,the discrimination and testing model of this radar for multi-targets (projectile and target) is established to analyze the systematic error of antiaircraft miss distance.Then through the aerial target flight test and contrast test with optical test equipment,the validity of the measurement method is verified.This new method has the potential to be used in the measurement of antiaircraft projectile miss distance.     

Effect of wafer size on the film internal stress measurement by wafer curvature method

Wafer curvature method has been applied to determine the internal stress in the films using Stoney’s equation. During the film deposition, the wafer fixation on the sample holder will restrict the deformation of the rectangle-shaped wafer, which may result in the stress datum difference along length and width direction. In this paper, the effect of wafer size and the wafer fixation on the TiN film internal stress measured by wafer curvature method was discussed. The rectangle-shaped wafers with different length/width ratios (L/W=1:1, 2:1, 3:1 and 4:1) were fixed as a cantilever beam. After the TiN films deposition, the profiles of the film/wafer were measured using a stylus profilometer and then the internal stress was calculated using the Stoney equation in the film. The results showed that the fixed end of the wafers limited to some degree the curvature of the wafers along the width direction. For film internal stress measured by wafer curvature method, the wafer profile should be scanned along the length direction and the scan distance should be greater than or equal to half of wafer length. When the length/width ratio of the wafer reached 3:1, the wafer curvature and the calculated stress were basically the same at different positions along the length direction. For film internal stress measured by wafer curvature method, it was recommended that the length/width ratio of wafer should be considered to be greater than or equal to 3:1, and the deformed profile was scanned along the length direction.     

Characterization and methanol adsorption of walnut-shell activated carbon prepared by KOH activation

Walnut-shellactivated carbons(WSACs)were prepared by the KOH chemicalactivation.The effects of carbonization temperature,activation temperature,and ratio of KOH to chars on the pore development of WSACs were investigated.Fourier transform infrared spectroscopy(FTIR),X-ray powder diffraction(XRD),and scanning electron microscopy(SEM)were employed to characterize the microstructure and morphology of WSACs.Methanoladsorption performance onto the optimalWSAC and the coal-based AC were also investigated.The results show that the optimalpreparation conditions are a carbonization temperature of 700 ℃,an activation temperature of 700 ℃,and a mass ratio of 3.The BET surface area,the micropore volume,and the micropore volume percentage of the optimalWASC are 1636 m~2/g,0.641 cm~3/g and 81.97%,respectively.There are a lot of micropores and a certain amount of meso-and macropores.The characteristics of the amorphous state are identified.The results show that the optimalWSAC is favorable for methanoladsorption.The equilibrium adsorption capacity of the optimalWSAC is 248.02mg/g.It is shown that the equilibrium adsorption capacity of the optimalWSAC is almost equivalent to that of the common activated carbon.Therefore the optimalWSAC could be a potentialadsorbent for the solar energy adsorption refrigeration cycle.     

用于频率综合的电荷泵锁相环电路设计

在阐述了锁相环频率综合的工作原理、分析和设计方法的基础上,结合环路稳定性和相位噪声两方面因素对锁相环电路进行了建模及分析。采用安捷伦公司的ADS软件对锁相环进行了系统设计及仿真,并采用Cadence公司的Spectre-RF系列软件进行了锁相环具体电路设计和仿真。采用该方案设计的锁相环输出频率范围18.15 23 GHz,相位噪声-90 dBc/Hz,锁定时间小于5μs。     

基于 Stateflow 的电动汽车再生制动控制策略

针对东风EJ02电动汽车进行了再生制动控制策略研究,通过对制动动力学与制动法规的研究,结合电池充电特性与电机输出特性,提出了在保证制动稳定性和电池安全性的前提下,最大限度回收制动能量的再生制动控制策略,并在ADVISOR仿真平台上结合Matlab Stateflow对该策略进行了建模与仿真分析,进行了3种工况的台架试验,得到不同工况的续驶里程。结果表明,该控制策略在保证电池安全性的前提下充分利用了电机的制动转矩,大幅提高了制动能量的回收,增加了电动汽车的续驶里程。     

A (4-fluorophenyl)(phenyl)phosphine oxide-modified epoxy resin with improved flame-retardancy,hydrophobicity, and dielectric properties

The compound (4-fluorophenyl)(phenyl) phosphine oxide (4-FPO) was designed, synthesized, and used in the modification of epoxy resin (EP). The 4-FPO-modified EP was prepared by curing the reaction mixture of diglycidyl ether of bisphenol A (DGEBA) and 4-FPO in the presence of 4,4′-diaminodiphenylsulfone (DDS). Compared with the unmodified EP, the limiting oxygen index value of the EP/4-FPO-0.6 (4-FPO-modified EP with 0.6 wt% of phosphorus) increased to 31.6%, and the sample achieved UL-94 V-0 rating. The peak of the heat release rate, average of the heat release rate, and total heat release of EP/4-FPO-0.6 were reduced by 39, 24, and 19%, respectively. Mechanism study showed that the quenching effect in the gas and barrier effect in the condensed phase were responsible for the enhanced flame-retardant properties of the 4-FPO-modified EP. The results showed that hydrophobicity and dielectric properties of the modified EP were clearly improved.     

残余应力及其分布的X射线二维衍射分析与计算

根据在X射线二维衍射几何关系下建立的应力应变基本方程，提出了一种基于X射线多晶面探测器衍射系统的残余应力及其分布测量方法，即通过分析X射线衍射圆锥的变形程度确定应变张量，进而计算应力张量。该方法有效地利用X射线面探测器的“虚拟摆动”功能，在一定程度上解决了传统X射线衍射法较难处理的粗晶材料和有织构材料的残余应力测量问题。对304不锈钢的残余应力及其分布进行了分析与计算，结果表明，该合金呈表面残余压应力，并且应力分布比较均匀。