全文获取类型
收费全文 | 187213篇 |
免费 | 20083篇 |
国内免费 | 12836篇 |
学科分类
工业技术 | 220132篇 |
出版年
2024年 | 686篇 |
2023年 | 2652篇 |
2022年 | 5971篇 |
2021年 | 8136篇 |
2020年 | 5912篇 |
2019年 | 4462篇 |
2018年 | 4840篇 |
2017年 | 5401篇 |
2016年 | 5076篇 |
2015年 | 7891篇 |
2014年 | 10000篇 |
2013年 | 11743篇 |
2012年 | 14496篇 |
2011年 | 15486篇 |
2010年 | 14655篇 |
2009年 | 13736篇 |
2008年 | 13913篇 |
2007年 | 13466篇 |
2006年 | 12092篇 |
2005年 | 9502篇 |
2004年 | 7035篇 |
2003年 | 5283篇 |
2002年 | 4951篇 |
2001年 | 4346篇 |
2000年 | 3477篇 |
1999年 | 2209篇 |
1998年 | 3600篇 |
1997年 | 2308篇 |
1996年 | 1614篇 |
1995年 | 1088篇 |
1994年 | 874篇 |
1993年 | 837篇 |
1992年 | 311篇 |
1991年 | 274篇 |
1990年 | 237篇 |
1989年 | 223篇 |
1988年 | 156篇 |
1987年 | 135篇 |
1986年 | 127篇 |
1985年 | 72篇 |
1984年 | 25篇 |
1983年 | 42篇 |
1982年 | 56篇 |
1981年 | 60篇 |
1980年 | 86篇 |
1979年 | 25篇 |
1977年 | 166篇 |
1976年 | 286篇 |
1959年 | 48篇 |
1951年 | 23篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
自动化实体描述生成有助于进一步提升知识图谱的应用价值,而流畅度高是实体描述文本的重要质量指标之一。该文提出使用知识库上多跳的事实来进行实体描述生成,从而贴近人工编撰的实体描述的行文风格,提升实体描述的流畅度。该文使用编码器—解码器框架,提出了一个端到端的神经网络模型,可以编码多跳的事实,并在解码器中使用关注机制对多跳事实进行表示。该文的实验结果表明,与基线模型相比,引入多跳事实后模型的BLEU-2和ROUGE-L等自动化指标分别提升约8.9个百分点和7.3个百分点。 相似文献
72.
Wang Hay Kan Chenxi Wei Dongchang Chen Tao Bo Bao‐Tian Wang Yan Zhang Yangchao Tian Jun‐Sik Lee Yijin Liu Guoying Chen 《Advanced functional materials》2019,29(17)
Lithium‐rich disordered rock‐salt oxides have attracted great interest owing to their promising performance as Li‐ion battery cathodes. While experimental and theoretical efforts are critical in advancing this class of materials, a fundamental understanding of key property changes upon Li extraction is largely missing. In the present study, single‐crystal synthesis of a new disordered rock‐salt cathode material, Li1.3Ta0.3Mn0.4O2 (LTMO), and its use as a model compound to investigate Li concentration–driven evolution of local cationic ordering, charge compensation, and chemical distribution are reported. Through the combined use of 2D and 3D X‐ray nanotomography, it is shown that Li removal accompanied by oxygen oxidation is correlated with the development of morphological defects such as particle cracking. Chemical heterogeneity, quantified by subparticle level distribution of Mn valence state, is minimal during Mn redox, which drastically increases upon the formation of cracks during oxygen redox. Density functional theory and bond valence sum mismatch calculations reveal the presence of local short‐range ordering in the pristine oxide, which gradually disappears along with the extraction of Li. The study suggests that with cycling the transformation into true cation–disordered state can be expected, which likely impacts the voltage profile and obtainable energy density of the oxide cathodes. 相似文献
73.
Biyun Fang Chuanfeng Zhang Zeliang Qi Chunyan Li Jun Ni Xiuyun Wang Jianxin Lin Chak-Tong Au Bingyu Lin Lilong Jiang 《American Institute of Chemical Engineers》2022,68(11):e17849
The design of an efficient non-noble metal catalyst is of burgeoning interest for ammonia synthesis. Herein, we report a Mo2C/CeO2 catalyst that is superior in ammonia synthesis activity. In this catalyst, molybdenum carbide coexisted with the ceria overlayers which is from the ceria support as the strong metal–support interaction. There is a high proportion of low-valent Mo species, as well as high concentration of Ce3+ and surface oxygen species. The presence of Mo2C and CeO2 overlayers not only leads to enhancement of hydrogen and nitrogen adsorption, but also facilitates the desorption and exchange of adsorbed species with the gaseous reagents. Compared with the Mo/CeO2 catalyst prepared without carbonization, the Mo2C/CeO2 catalyst is more than sevenfold higher in ammonia synthesis rate. This work not only presents an explicit example of designing Mo-based catalyst that is highly efficient for ammonia synthesis by tuning the adsorption and desorption properties of the reactant gases, but opens a perspective for other elements in ammonia synthesis. 相似文献
74.
麻锐敏 《计算技术与自动化》2019,38(2):19-22
针对水质污染情况的严重性和水质主要污染源之一的氨氮缺乏实时检测的情况,设计了一套基于Freescale单片机芯片的水质氨氮检测系统,可以实时和快速地计算出水质中氨氮的含量。检测系统的硬件部分设计主要包括微处理器模块、温度控制模块、存储模块、信号采集模块以及通信模块的电路设计,软件部分对不同的模块进行程序设计以及上位机软件平台的开发。最后对整个系统进行实验测试,实验结果表明检测系统可以满足氨氮检测的精度要求。 相似文献
75.
76.
Zhang Huawei Yang Zhi Wu Zhaoyu Hong Xiaoyu Li Zhong Xu Yulai Li Jun Ni Gaojin Xiao Xueshan 《Oxidation of Metals》2019,92(1-2):49-65
Oxidation of Metals - The isothermal oxidation behavior and oxide-scale evolution on a newly developed Ni–Fe-based superalloy were investigated. Three oxidation stages were generally... 相似文献
77.
Jialin Sun Jun Zhao Xiuying Ni Feng Gong Zuoli Li 《Journal of the European Ceramic Society》2018,38(9):3096-3103
This work investigates the critical roles of two-step sintering (TSS) and laminated structure on the sintering behavior and mechanical properties of functionally graded WC-TiC-Al2O3 nanostructured composite materials doped with Cr3C2/VC. Results show that excellent mechanical properties are achieved for tailored TSS conditions with a hardness of 27.91?±?2.3?GPa and a flexural strength of 1423.3?±?23.5?MPa. The desirable mechanical properties are attributed to the suppressed grain growth without densification deterioration. TSS is more effective in facilitating the favorable dispersion of secondary phase toughening nano-particulates in a WC matrix than conventional sintering (CS). Cr3C2/VC dopant plays an important role in maximizing and shifting the temperature range of the kinetic window for WC-Al2O3 composites. Al2O3 crack deflection, transgranular Al2O3, microcracking, WC crack bridging and plate-like WC crack deflection are the major toughening mechanisms. Residual surface compressive stress induced by the graded structure is also an appreciated contribution to the improvement of mechanical properties. 相似文献
78.
79.
Zhuo Shi Ningning Dong Dingfeng Zhang Xiaofang Jiang Guanxin Du Shichao Lv Jiejie Chen Jun Wang Shifeng Zhou 《Journal of the American Ceramic Society》2019,102(7):3965-3971
The construction of nonlinear optical materials featuring asymmetric transmission of light is of great technological importance for various applications, including optical switching and optical power limiting. A significant challenge is the scalable fabrication of material candidates with good photochemical stability, high optical transmittance, and excellent optical limiting performance. Here, we present a nanocrystallization avenue for constructing hybrid optical limiting materials that exhibit ultrafast and robust optical limiting performance. The experimental results show that the controllable relaxation of a niobate glass may lead to the clustering of Nb-O units and contracting of the bandgap. It results in the notable improvement in nonlinear optical properties, including the enhanced saturation irradiance (380 GW/cm2), doubly increased nonlinear coefficient, and decreased limiting threshold (200 GW/cm2). Our results suggest a promising material that exhibits promising applications for protecting eyes and sensitive components from laser-induced damage. 相似文献
80.
Qun Ren Haijun Su Jun Zhang Haifang Liu Weidan Ma Guangrao Fan Di Zhao Min Guo Lin Liu Hengzhi Fu 《Ceramics International》2019,45(6):6632-6638
Directionally solidified microstructures of Al2O3-Er3Al5O12 eutectic and off-eutectic in situ composite ceramics were explored under abrupt-change pulling rate conditions. Corresponding temperature distributions and interface locations were studied. In eutectic composition, fluctuation of eutectic spacing occurred when the pulling rate increased abruptly. A gradually increase or abrupt increase in eutectic spacing was observed when the pulling rate decreased abruptly. In hypoeutectic and hypereutectic compositions, formation of the primary phases were suppressed when the pulling rate increased abruptly from 10?µm/s to 100?µm/s, while primary phases precipitated when the pulling rate decreased abruptly from 100?µm/s to 10?µm/s. The interface altitude decreased after the pulling rate increased abruptly, but increased after the pulling rate decreased abruptly. The liquid composition restriction (around the eutectic composition) at the eutectic interface plays an important role in the suppression of the primary dendrite and coupled eutectic oxides can be obtained in off-eutectic compositions even under higher solidification rate conditions. 相似文献