基于移动互联的继电保护移动作业平台设计

文章利用移动互联技术,通过搭建"移动终端-主站"软硬件平台,将传统继电保护作业中涉及的文本编辑、业务流转、作业审核、安全监督、资料整理等作业环节进行数字化改造,通过开发作业文本管理模块、安措票管理模块、设备检修缺陷管理模块,实现移动作业终端与现场作业的无缝衔接.继电保护从业人员可通过主站联动方式,提升继电保护作业的工作效率和智能化水平.     

终轧温度和卷取温度对51CrV4热轧板组织性能的影响研究

利用光学显微镜、扫描电镜、Z150电子拉伸试验机分析了不同终轧温度、卷取温度下51CrV4热轧板的显微组织和力学性能。     

动态网络安全模型信息安全风险分析

通过动态网络模型信息安全风险分析实验,在LazyLBR和VFI的ROC曲线进行统计和F-度量,采用10倍交叉验证方法.针对网络的脆弱性、外界的威胁和资产价值几种数据,对比四种动态网络模型信息安全风险的数字学习曲线.     

疲劳裂纹扩展行为的研究现状及钛合金的疲劳裂纹扩展特征

疲劳裂纹扩展行为是现代材料研究中重要的内容之一。论述了组织结构、环境温度、腐蚀条件以及载荷应力比、频率变化对材料疲劳裂纹扩展行为的影响。总结出疲劳裂纹扩展研究的常用方法和理论模型,并讨论了"塑性钝化模型"和"裂纹闭合效应"与实际观察结果存在的矛盾。最后,对钛合金疲劳裂纹扩展研究的内容和研究结果进行了概述。     

基于ITS rDNA分析辣椒幼苗根际真菌群落结构差异

[目的]比较云南地方两个主要辣椒栽培种(Capsicum annuum L.和Capsicum frutescens L.)幼苗根际真菌群落结构相似性与差异性,为探索根际特有微生物群功能挖掘、调控机制及应用提供参考.[方法]运用ITS rDNA高通量测序技术对其根际土壤真菌群落组成进行测定并分析其多样性.[结果]一年生辣椒中子囊菌门Ascomycota为优势群落,而在灌木状辣椒中则是担子菌门Basidiomycota为优势菌群,表明不同辣椒可根据生长环境选择性"招募"不同的有益真菌群类来分解环境中不同有机体为自身提供养分以促进生长.在仅多样性分析中灌木辣椒根际真菌群落的丰度和多样性显著高于一年生辣椒、对照.[结论]辣椒根际真菌群落结构多样性受不同基因型辣椒品种的影响,灌木辣椒种相较于一年生辣椒种根际真菌群落结构表现出显著的差异性和丰富的多样性.     

Functionalized metal–organic frameworks with strong acidity and hydrophobicity as an efficient catalyst for the production of 5-hydroxymethylfurfural

In the dehydration of fructose to 5-hydroxymethyl furfural(HMF), in situ produced water weakens the acid strength of the catalyst and causes the rehydration of HMF, causing unsatisfactory catalytic activity and selectivity. In this work, a class of benzenesulfonic acid-grafted metal–organic frameworks with strong acidity and hydrophobicity is obtained by the direct sulfonation method using 4-chlorobenzenesulfonic acid as sulfonating agent. The resultant MOFs have a specific surface area of greater than 250 m~2·g~(-1), acid density above 1.0 mmol·g~(-1), and water contact angle up to 129°. The hydrophobic MOF-Ph SO_3 H exhibits both higher catalytic activity and selectivity than MOF-SO_3 H in the HMF synthesis due to its better hydrophobicity and olephilicity. Moreover, the catalyst has a high recycled stability. At last, fructose is completely converted, and 98.0% yield of HMF is obtained under 120 °C in a DMSO solvent system. The successful preparation of the hydrophobic acidic MOF provides a novel hydrophobic catalyst for the synthesis of HMF.     

生物基异山梨醇改性磺酸盐水性聚氨酯的制备及性能

以异佛尔酮二异氰酸酯(IPDI)、聚碳酸酯二元醇(PCDL)、季戊四醇三丙烯酸酯(PETA)为主要原料,以自制的含磺酸基的低聚物聚酯二元醇(SO3-2OH)为亲水单体,二羟甲基丁酸(DMPA)作为亲水扩链剂,合成了含磺酸基的聚氨酯预聚物,再采用生物基二元醇──异山梨醇(IS)对其进行改性,制备了可紫外光固化的异山梨醇改性磺酸盐水性聚氨酯(UV-SIWPU)乳液.通过傅里叶变换红外光谱仪(FT-IR)、紫外可见近红外分光光度计(UV-VIS-NIR)、凝胶渗透色谱(GPC)、光学接触角测量仪(OCA)等仪器对该乳液及其涂膜的结构、形貌和性能进行了分析.结果表明:当SO3-2OH含量为20％,IS含量为75％时,所制备的UV-SIWPU涂膜的综合性能优异:水接触角为23.2°,吸水率为11.6％,在水中浸泡7 d后不泛白、不脱落,耐水性较好,拉伸强度为6.5 MPa,断裂伸长率为253％,铅笔硬度达到2H,在550 nm处的透光率达到96.0％,热稳定性和防雾性能良好.     

具有直流故障穿越能力的模块化多电平换流拓扑推演与对比

直流故障具有影响范围广、故障电流大的特征,已成为制约直流系统发展的重要因素之一。模块化多电平换流器可通过配置双极性子模块实现直流故障穿越,但相比于基于半桥子模块的拓扑,其建造成本与运行损耗均大幅增加。为寻求兼顾硬件成本、运行效率与直流故障穿越能力的模块化多电平换流拓扑,首先通过拓扑抽象定义与模块配置约束,遍历并推导出4大类共13种模块化多电平换流拓扑;进而优选出T型桥臂交替多电平换流器,并提出桥臂移相导通调制,实现其高效功率变换与直流故障穿越的兼顾;最后,计及硬件成本、运行损耗、可靠性与可实现性等维度,对各类具有直流故障穿越能力的拓扑进行了系统性对比,为具有故障穿越能力需求的交直流变换场景提供模块化多电平换流拓扑的选择依据。     

Preparation of ceramic coatings on inner surface of steel tubes using a combined technique of hot-dipping and plasma electrolytic oxidation

A new method for inner surface modification of steel tubes, named a combined technique of hot-dipping and plasma electrolytic oxidation (PEO) was proposed and demonstrated in this paper. In this work, metallurgically bonded ceramic coatings on inner surface of steel tubes were obtained using this method. In the combined process, aluminum coatings on steel were firstly prepared by the hot-dip process and then metallurgically bonded ceramic coatings were obtained on the aluminum coatings by PEO. The element distribution, phase composition and morphology of the aluminide layer and the ceramic coatings were characterized by SEM/EDX and XRD. The corrosion resistance of the ceramic coatings were also studied. The results show that, after hot-dip treatment, the coating layers consist of two layers, where Al, Fe_xAl _(1−x) were detected from external topcoat to the aluminide/steel substrate. Then after PEO process, uniform Al₂O₃ ceramic coatings have been deposited on inner surface of steel tubes. The ceramic coatings are mainly composed of -Al₂O₃ and γ-Al₂O₃ phase. The compound coatings show favorable corrosion resistance property. The investigations indicate that the combination of hot-dipping and plasma electrolytic oxidation proves a promising technique for inner surface modification of steel tubes for protective purposes.