无碱玻璃纤维池窑用高致密锆英石砖的研究

采用高纯锆英石为主要原料 ,研究了几个关键工艺因素对高纯高致密锆英石砖性能的影响。结果表明 ,原料纯度、外加物种类及其加入量和烧成温度是获得优质高致密锆英石砖的关键。显微结构分析结果显示 ,这种砖晶粒间呈交错网络结构 ,直接结合程度极高 ,并具有良好的抗玻璃液的侵蚀性和渗透性。扫描电镜检验发现 ,玻璃液渗入砖内与砖反应 ,首先溶解Al2 O3、R2 O等组分 ,然后溶解锆英石 ,并析出斜锆石晶粒 ,呈岛状分布于玻璃液中 ,破坏了砖的原始直接结合结构 ,导致砖的解体。     

含MnO2和Sb2O3的SnO2基陶瓷烧结致密化和导电性能的研究

以粒度0.401μm、纯度为99.5%的SnO2,粒度0.6μm、纯度为99%的MnO2和粒度0.12μm、纯度为99%的Sb2O3为原料,配料后,放在尼龙行星球磨罐中加无水乙醇湿混4h,烘干后用50μm筛网筛分,取筛下料在20mm模具中以6MPa压力成型为2~3mm薄片,再将薄片做200MPa冷等静压处理。将处理后的生坯放入硅钼棒炉中于空气气氛下分别在1300℃、1350℃、1400℃、1420℃、1450℃、1470℃、1500℃均保温5h烧成,随炉冷却至常温。采用排水法测试试样密度,利用SEM和EDX分析微观结构和元素组成,采用四探针法测量电阻率。研究结果表明MnO2的加入对SnO2基陶瓷的相对密度有很大的提高,而Sb2O3的加入对SnO2陶瓷的致密化起到抑制的作用,但适量的Sb2O3可显著提高同时含有MnO2和Sb2O3的SnO2陶瓷的导电性能。同时添加MnO2和Sb2O3的试样的相对密度和电阻率与Mn-Sn-O和Sb-Sn-O分别形成的相关固溶体有很大的关系。对试样的相对密度和电阻率结果分析表明,对于SnO2基陶瓷,MnO2的最佳添加量为1.0%,Sb2O3的最佳添加量为0.5%;其烧结温度为1400℃时,其相对密度为95.63%,电阻率为78.37Ω·cm。     

A Sedimentation-Dispersion Model for both Non-attached and Attached Particles in Three-Phase Batchwise Fluidized Beds

The axial concentration distribution of both particles with better wetting (forming non-attached system) and poorer wetting (forming attached system) was investigated in a vertical gas-liquid-solid fluidized bed of 4.2 cm in diameter and 130 cm in height with the solids holdup less than 0.05. The one-dimensional sedimentation-dispersion model could be used satisfactorily to describe the axial distribution of solids holdup by modifying only a model parameter, i.e. by means of the terminal settling velocity minus a certain value, which is a function of gas velocity and considers the effect of an additional drag force resulted from attached rising bubbles. The axial profiles of solid concentration predicted are in good agreement with experimental results. This model also explains reasonably the different axial distributions of solid concentration, i.e. the solids holdup decreases as the axial height increases in non-attached system, but increases with the axial height in attached system at a given gas veloc     

白腐菌Panus conchatus降解稻草木素机理研究──(一)低分子木素降解产物各组分的分离及特征

经白腐菌Panusconchatuss发酵15天的稻草用乙酸乙酯进行抽提可有效分离出生物作用后的低分子量木煮降解产物。利用这些低分子降解产物在酸碱度不同的介质以及不同的有机溶剂中的溶解度不同进一步分离、分级和提纯，获得酚类（LP），芳香酸类（LA1—4）以及中性物质三个组份。我们发现LP与LA是降解产物中的主要组份，它们的得率分别为51．1％和34．4％。如此高的LP得率是白腐菌P．conchatus降解稻草木素的重要特征。本文还利用红外光谱和核磁共振技术对LP和LA中最多的一个组份LA—1的可能化学结构特征进行剖析。     

仿瓷胶粘剂的研究

本文介绍一种仿瓷环氧胶粘剂,该胶耐酸耐碱,可室温固化,在室温下粘接不锈钢试样,其剪切强度可达30.7MPa;而在130℃时其剪切强度为1.7MPa。可用于修复搪瓷,粘接金属和陶瓷等。     

国内外聚碳酸酯市场及需求分析

聚碳酸酯(PC)综合性能好,其消费与生产增长举世瞩目,在世界五大通用工程塑料中占有重要地位。国内PC生产及消费量虽不大,但潜在市场不可忽视,发展与开拓工程塑料,特别是PC的应用与生产的开发,是我国化学和石化工业发展需要之一。     

1991年我国工程塑料进展

根据国内有关工程塑料的文献,报道1991年国内热塑性树脂及塑料、热固性树脂及塑料、成型加工技术的进展,以及工程塑料在国民经济各个领域中的研究开发和应用。     

Numerical simulations of failure behavior around a circular opening in a non-persistently jointed rock mass under biaxial compression

Pre-existing discontinuities change the mechanical properties of rock masses,and further influence failure behavior around an underground opening.In present study,the failure behavior in both Inner and Outer zones around a circular opening in a non-persistently jointed rock mass under biaxial compression was investigated through numerical simulations.First,the micro parameters of the PFC^3D model were carefully calibrated using the macro mechanical properties determined in physical experiments implemented on jointed rock models.Then,a parametrical study was undertaken of the effect of stress condition,joint dip angle and joint persistency.Under low initial stress,the confining stress improves the mechanical behavior of the surrounding rock masses;while under high initial stress,the surrounding rock mass failed immediately following excavation.At small dip angles the cracks around the circular opening developed generally outwards in a step-path failure pattern;whereas,at high dip angles the surrounding rock mass failed in an instantaneous intact rock failure pattern.Moreover,the stability of the rock mass around the circular opening deteriorated significantly with increasing joint persistency.     

基于遗传算法的双区型仓库人工拣货路径优化

为获取捡货作业的最优路径,本文以某配送中心双区型仓库中人工拣货作业为研究对象,探讨了订单批量处理和拣货路径优化问题,建立了拣货车容量受限的TSP模型,并基于遗传算法,设计一种启发式算法对拣货路径进行优化处理,同时,应用Visual 6.0C++程序进行仿真实验,以快速获得任意订单中所有待拣货物的拣取顺序,计算出最短路程。仿真结果表明,将考虑拣货车容量限制的情况下求得的最优路径与未考虑拣货车容量限制的情况下求得的最优路径进行对比,结果拣货的先后次序完全不同,说明考虑运载量是有效的,且更符合实际情况。该研究不但提高拣货效率,而且节约各项成本,对现实仓库的拣货作业具有实际应用价值。